Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-13T09:33:29.308Z Has data issue: false hasContentIssue false
  • English
  • Français

Oxidation of carbon on nickel-based metallic substrates: Implications for high-temperature superconductor coated conductors

Published online by Cambridge University Press:  01 March 2005

F.A. List ,
L. Heatherly ,
D.F. Lee ,
K.J. Leonard  and
A. Goyal
F.A. List*
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6116
L. Heatherly
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6116
D.F. Lee
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6116
K.J. Leonard
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6116
A. Goyal
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6116
*
a)Address all correspondence to this author. e-mail: fal@ornl.gov
Get access

Abstract

Adhesion of thin films of epitaxial oxides to nickel-based metallic substrates is important for the successful development of high-temperature superconductor coated conductors. Detachment of epitaxial oxide buffer layers at the oxide/metal interface during either oxide growth or subsequent processing renders the conductor useless. In this study, thermal desorption spectroscopy (TDS) has been used to identify and understand one of the causes of buffer layer detachment, oxidation of carbon at the oxide–metal interface to form carbon monoxide. Results of TDS indicate that on the surface of a bare nickel-based alloy substrate, the rate of carbon oxidation depends on both the supply of carbon from the substrate and the supply of oxygen from the vapor. Sulfur at the surface of the alloy substrate reduces the rate of carbon oxidation. The effectiveness of various treatments of the bare substrate to eliminate CO formation and epitaxial oxide detachment has been demonstrated. TDS provides both a means to evaluate the kinetics of the oxidation reaction and a tool to assess the need and effectiveness of a substrate oxidation treatment.

Keywords

AdhesionOxidation/annealingSuperconductor
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 3 , March 2005 , pp. 765 - 773
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Paranthaman, M.P. and Izumi, T.: High-performance YBCO-coated superconductor wire. MRS Bull. 29(8), 533 (2004).CrossRefGoogle Scholar
2.Arendt, P.N. and Foltyn, S.R.: Biaxially textured IBAD-MgO templates for YBCO-coated conductors. MRS Bull. 29(8), 543 (2004).CrossRefGoogle Scholar
3.Goyal, A., Paranthaman, M.P. and Schoop, U.: The RABiTS approach: Using rolling-assisted biaxially textured substrates for high performance YBCO superconductors. MRS Bull. 29(8), 552 (2004).CrossRefGoogle Scholar
4.Iijima, Y., Kakimoto, K., Yamada, Y., Izuma, T., Saitoh, T. and Shiohara, Y.: Research and development of biaxially textured IBAD-GZO templates for coated superconductors. MRS Bull. 29(8), 564 (2004).CrossRefGoogle Scholar
5.Becker, J.A., Becker, E.J. and Brandes, R.G.: Reactions of oxygen with pure tungsten and tungsten containing carbon. J. Appl. Phys. 32, 411 (1961).CrossRefGoogle Scholar
6.Sancho, M.P. Lopez and Sancho, J.M. Lopez: ESD study of the interaction of oxygen with tungsten containing carbon. Appl. Surf. Sci. 6, 82 (1980).CrossRefGoogle Scholar
7.McAllister, J.W. and White, J.M.: The oxidation of carbon at the surface of nickel. J. Phys. Chem. 76, 968 (1972).CrossRefGoogle Scholar
8.Conrad, H., Ertl, G., Kuppers, J. and Latta, E.E.: Adsorption of CO on clean and oxygen covered Ni(111) surfaces. Surf. Sci. 57, 475 (1976).CrossRefGoogle Scholar
9.List, F.A. and Blakely, J.M.: Oxidation of carbon on vicinal surfaces of nickel. J. Vac. Sci. Technol. 20, 838 (1982).CrossRefGoogle Scholar
10.List, F.A. and Blakely, J.M.: Kinetics of CO formation on singular and stepped nickel surfaces. Surf. Sci. 152–153, 463 (1985).CrossRefGoogle Scholar
11.Smith, W.F.: Structural Properties of Engineering Alloys (McGraw-Hill Publishing, New York, 1981).Google Scholar
12.Gruzin, P.L., Polickarpov, Y.A. and Federov, G.B.: Determining carbon diffusion in nickel and its alloys by means of carbon-14. Fiz. Metal. Metalloved. 4, 94 (1957).Google Scholar
13.Reif, F.: Fundamentals of Statistical and Thermal Physics (McGraw-Hill, New York, 1965), pp. 269–273.Google Scholar
14.Cantoni, C., Christen, D.K., Heatherly, L., Kowalewski, M.M., List, F.A., Goyal, A., Ownby, G.W., Zehner, D.M., Kang, B.W. and Kroeger, D.M.: Quantification and control of the sulfur c(2 × 2) superstructure on {100}(100) Ni for optimization of YSZ, CeO2, and SrTiO3 seed layer texture. J. Mater. Res. 17, 2549 (2002).CrossRefGoogle Scholar
15. Thermo-Calc TCC Software, ver. 8.12 (Thermo-Calc Software, Stockholm, Sweden, 2004).Google Scholar
16.Specht, E.D., List, F.A., Lee, D.F., More, K.L., Goyal, A., Robbins, W.B. and O’Neill, D.: Uniform texture in meter-long YBa2Cu3O7 tape. Physica C 382, 342 (2002).CrossRefGoogle Scholar
17.Hofmann, S. and Frech, R.: Application of Auger electron spectroscopy to trace analysis: Determination of less than 10 ppm sulfur in copper. Anal. Chem. 57, 716 (1985).CrossRefGoogle Scholar
18.Diamond, S. and Wert, C.: Diffusion of carbon in nickel above and below the Curie temperature. Trans. Met. Soc. AIME 239, 705 (1967).Google Scholar
19.Crank, J.: The Mathematics of Diffusion, 2nd ed. (Oxford University Press, London, U.K., 1975).Google Scholar
20.Carslaw, H.S. and Jaeger, J.C.: Conduction of Heat in Solids, 2nd ed. (Oxford University Press, London, U.K., 1959).Google Scholar
21.Iserles, A.: A First Course in the Numerical Analysis of Differential Equations (Cambridge University Press, Cambridge, U.K., 1996).Google Scholar