Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-14T19:29:07.042Z Has data issue: false hasContentIssue false
  • English
  • Français

Palladium and gold nanoparticles on carbon supports as highly efficient catalysts for effective removal of trichloroethylene

Published online by Cambridge University Press:  17 July 2018

Kavita Meduri Open the ORCID record for Kavita Meduri [Opens in a new window] ,
Candice Stauffer ,
Wen Qian ,
Otto Zietz ,
Andrew Barnum ,
Graham O’Brien Johnson ,
Dimin Fan ,
Weixiao Ji ,
Changwen Zhang  and
Paul Tratnyek
...Show all authors
Kavita Meduri
Affiliation:
Department of Mechanical and Materials Engineering, Portland State University, Portland, Oregon 97201, USA
Candice Stauffer
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Wen Qian
Affiliation:
Department of Mechanical & Materials Engineering, University of Nebraska-Lincoln, Lincoln, Nebraska 68588, USA
Otto Zietz
Affiliation:
Department of Mechanical and Materials Engineering, Portland State University, Portland, Oregon 97201, USA
Andrew Barnum
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Graham O’Brien Johnson
Affiliation:
School of Public Health, Oregon Health and Science University, Portland, Oregon 97239, USA
Dimin Fan
Affiliation:
School of Public Health, Oregon Health and Science University, Portland, Oregon 97239, USA
Weixiao Ji*
Affiliation:
School of Physics and Technology, University of Jinan, Jinan 250022, China
Changwen Zhang
Affiliation:
School of Physics and Technology, University of Jinan, Jinan 250022, China
Paul Tratnyek
Affiliation:
School of Public Health, Oregon Health and Science University, Portland, Oregon 97239, USA
Jun Jiao*
Affiliation:
Department of Mechanical and Materials Engineering, Portland State University, Portland, Oregon 97201, USA; and Department of Physics, Portland State University, Portland, Oregon 97201, USA
*
a)Address all correspondence to this author. e-mail: jiaoj@pdx.edu
Get access

Abstract

Palladium (Pd) and gold (Au) nanoparticles (NPs) hybridized on two types of carbon supports, graphene and granular activated carbon (GAC), were shown to be promising catalysts for the sustainable hydrodehalogenation of aqueous trichloroethylene (TCE). These catalysts are capable of degrading TCE more rapidly than commercial Pd-on-GAC catalysts. The catalysts were synthesized at room temperature without the use of any environmentally unfriendly chemicals. Pd was chosen for its catalytic potency to break down TCE, while Au acts as a strong promoter of the catalytic activity of Pd. The results indicate that both graphene and GAC are favorable supports for the NPs due to high surface-to-volume ratios, unique surface properties, and the prevention of NP aggregation. The properties of NP catalysts were characterized using electron microscopy and spectroscopy techniques. The TCE degradation results indicate that the GAC-supported catalysts have a higher rate of TCE removal than the commercial Pd-on-GAC catalyst, and the degradation rate is greatly increased when using graphene-supported samples.

Keywords

catalyticpalladiumgold
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 16 , 28 August 2018 , pp. 2404 - 2413
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

b)

Present address: Oak Ridge Institute for Science and Education Fellow, Office of Superfund Remediation and Technology Innovation, U.S. Environmental Protection Agency, Arlington, Virginia 22201, USA.

References

REFERENCES

Chaplin, B.P., Reinhard, M., Schneider, W.F., Schüth, C., Shapley, J.R., Strathmann, T.J., and Werth, C.J.: Critical review of Pd-based catalytic treatment of priority contaminants in water. Environ. Sci. Technol. 46, 3655 (2012).CrossRefGoogle ScholarPubMed
Heck, K.N., Nutt, M.O., Alvarez, P., and Wong, M.S.: Deactivation resistance of Pd/Au nanoparticle catalysts for water-phase hydrodechlorination. J. Catal. 267, 97 (2009).CrossRefGoogle Scholar
Munakata, N. and Reinhard, M.: Palladium-catalyzed aqueous hydrodehalogenation in column reactors: Modeling of deactivation kinetics with sulfide and comparison of regenerants. Appl. Catal., B 75, 1 (2007).CrossRefGoogle Scholar
Park, S.J., Bhargava, S., Bender, E.T., Chase, G.G., and Ramsier, R.D.: Palladium nanoparticles supported by alumina nanofibers synthesized by electrospinning. J. Mater. Res. 23, 1193 (2008).CrossRefGoogle Scholar
Li, Y., Lu, D., Zhou, L., Ye, M., Xiong, X., Yang, K., Pan, Y., Chen, M., Wu, P., Li, T., Chen, Y., Wang, Z., and Xia, Q.: Bi-modified Pd-based/carbon-doped TiO2 hollow spheres catalytic for ethylene glycol electrooxidation in alkaline medium. J. Mater. Res. 31, 3712 (2016).CrossRefGoogle Scholar
Lyu, Z., Liu, B., Wang, R., and Tian, L.: Synergy of palladium species and hydrogenation for enhanced photocatalytic activity of {001} facets dominant TiO2 nanosheets. J. Mater. Res. 32, 2781 (2017).CrossRefGoogle Scholar
Salomé, O., Soares, G.P., Órfão, J.J.M., and Pereira, M.F.R.: Nitrate reduction with hydrogen in the presence of physical mixtures with mono and bimetallic catalysts and ions in solution. Appl. Catal., B 102, 424 (2011).Google Scholar
Batista, J., Pintar, A., Gomilšek, J.P., Kodre, A., and Bornette, F.: On the structural characteristics of γ-supported Pd–Cu bimetallic catalysts. Appl. Catal., A 217, 55 (2001).CrossRefGoogle Scholar
Pintar, A., Batista, J., and Muševič, I.: Palladium-copper and palladium-tin catalysts in the liquid phase nitrate hydrogenation in a batch-recycle reactor. Appl. Catal., B 52, 49 (2004).CrossRefGoogle Scholar
Engelmann, M.D., Hutcheson, R., Henschied, K., Neal, R., and Cheng, I.F.: Simultaneous determination of total polychlorinated biphenyl and dichlorodiphenyltrichloroethane (DDT) by dechlorination with Fe/Pd and Mg/Pd bimetallic particles and flame ionization detection gas chromatography. Microchem. J. 74, 19 (2003).CrossRefGoogle Scholar
Nutt, M.O., Hughes, J.B., and Wong, M.S.: Designing Pd-on-Au bimetallic nanoparticle catalysts for trichloroethene hydrodechlorination. Environ. Sci. Technol. 39, 1346 (2005).CrossRefGoogle ScholarPubMed
Calvino-Casilda, V., López-Peinado, A.J., Durán-Valle, C.J., and Martín-Aranda, R.M.: Last decade of research on activated carbons as catalytic support in chemical processes. Catal. Rev. 52, 325 (2010).CrossRefGoogle Scholar
Qiu, X.F., Xu, J.Z., Zhu, J.M., Zhu, J.J., Xu, S., and Chen, H.Y.: Controllable synthesis of palladium nanoparticles via a simple sonoelectrochemical method. J. Mater. Res. 18, 1399 (2003).CrossRefGoogle Scholar
Gertrude, G.: Hydrogenation of mono-and disaccharides to polyols. U.S. Patent No. 2868847A, 1959.Google Scholar
Díaz, E., Ordóñez, S., Bueres, R.F., Asedegbega-Nieto, E., and Sastre, H.: High-surface area graphites as supports for hydrodechlorination catalysts: Tuning support surface chemistry for an optimal performance. Appl. Catal., B 99, 181 (2010).CrossRefGoogle Scholar
Ordóñez, S., Díaz, E., Bueres, R.F., Asedegbega-Nieto, E., and Sastre, H.: Carbon nanofibre-supported palladium catalysts as model hydrodechlorination catalysts. J. Catal. 272, 158 (2010).CrossRefGoogle Scholar
Zhang, M., Bacik, D.B., Roberts, C.B., and Zhao, D.: Catalytic hydrodechlorination of trichloroethylene in water with supported CMC-stabilized palladium nanoparticles. Water Res. 47, 3706 (2013).CrossRefGoogle ScholarPubMed
Schrage, A.: Preparation of carbon supported palladium catalysts. U.S. Patent No. 3736266A, 1973.Google Scholar
Keith, C.D. and Bair, D.L.: Process for producing palladium on carbon catalysts. U.S. Patent No. 3138560A, 1964.Google Scholar
Mozingo, R.: Palladium catalysts. Org. Synth. 26, 77 (1946).Google ScholarPubMed
Cookson, J.: The preparation of palladium nanoparticles. Platinum Met. Rev. 56, 83 (2012).CrossRefGoogle Scholar
US EPA: Wastewater technology fact sheet: Granular activated carbon adsorption and regeneration (2000). Available at: https://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=P1001QTK.txt.Google Scholar
US EPA and EPA: Work breakdown structure-based cost models for drinking water treatment technologies. EPA 832-F-00–017, EPA 815, 2014.Google Scholar
Mcallister, M.J., Li, J., Adamson, D.H., Schniepp, H.C., Abdala, A.A., Liu, J., Herrera-Alonso, M., Milius, D.L., Car, R., Prud’homme, R.K., and Aksay, I.A.: Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem. Mater. 19, 4396 (2007).CrossRefGoogle Scholar
Zhang, Y., Tan, Y., Stormer, H.L., and Kim, P.: Experimental observation of the quantum Hall effect and Berry’s phase in graphene. Nature 438, 201 (2005).CrossRefGoogle ScholarPubMed
Scarpa, F., Adhikari, S., and Srikantha Phani, A.: Effective elastic mechanical properties of single layer graphene sheets. Nanotechnology 20, 1 (2009).CrossRefGoogle ScholarPubMed
Qian, W., Hao, R., Zhou, J., Eastman, M., Manhat, B.A., Sun, Q., Goforth, A.M., and Jiao, J.: Exfoliated graphene-supported Pt and Pt-based alloys as electrocatalysts for direct methanol fuel cells. Carbon 52, 595 (2013).CrossRefGoogle Scholar
Qian, W., Cottingham, S., and Jiao, J.: Hybridization of conductive few-layer graphene with well-dispersed Pd nanocrystals. Appl. Surf. Sci. 275, 342 (2013).CrossRefGoogle Scholar
Edwards, J.K., Thomas, A., Carley, A.F., Herzing, A.A., Kiely, C.J., and Hutchings, G.J.: Au–Pd supported nanocrystals as catalysts for the direct synthesis of hydrogen peroxide from H2 and O2. Green Chem. 10, 388 (2008).CrossRefGoogle Scholar
Qian, W., Chen, Z., Cottingham, S., Merrill, W.A., Swartz, N.A., Goforth, A.M., Clare, T.L., and Jiao, J.: Surfactant-free hybridization of transition metal oxide nanoparticles with conductive graphene for high-performance supercapacitor. Green Chem. 14, 371 (2012).CrossRefGoogle Scholar
Nutt, M.O., Heck, K.N., Alvarez, P., and Wong, M.S.: Improved Pd-on-Au bimetallic nanoparticle catalysts for aqueous-phase trichloroethene hydrodechlorination. Appl. Catal., B 69, 115 (2006).CrossRefGoogle Scholar
Ji, W., Zhang, C., Li, F., Li, P., Wang, P., Ren, M., and Yuan, M.: First-principles study of small Pd–Au alloy clusters on graphene. RSC Adv. 4, 55781 (2014).CrossRefGoogle Scholar
Meduri, K., Barnum, A., Johnson, G.O.B., Tratnyek, P.G., and Jiao, J.: Characterization of palladium and gold nanoparticles on granular activated carbon as an efficient catalyst for hydrodechlorination of trichloroethylene. Microsc. Microanal. 22, 332 (2016).CrossRefGoogle Scholar
Edwards, J., Landon, P., Carley, A.F., Herzing, A.A., Watanabe, M., Kiely, C.J., and Hutchings, G.J.: Nanocrystalline gold and gold-palladium as effective catalysts for selective oxidation. J. Mater. Res. 22, 831 (2007).CrossRefGoogle Scholar
Lowry, G.V. and Reinhard, M.: Hydrodehalogenation of 1- to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas. Environ. Sci. Technol. 33, 1905 (1999).CrossRefGoogle Scholar
Li, S., Fang, Y.L., Romanczuk, C.D., Jin, Z., Li, T., and Wong, M.S.: Establishing the trichloroethene dechlorination rates of palladium-based catalysts and iron-based reductants. Appl. Catal., B 125, 95 (2012).CrossRefGoogle Scholar
Tierney, H.L., Baber, A.E., Kitchin, J.R., and Sykes, E.C.H.: Hydrogen dissociation and spillover on individual isolated palladium atoms. Phys. Rev. Lett. 103, 246102 (2009).CrossRefGoogle ScholarPubMed
Baber, A.E., Tierney, H.L., and Sykes, E.C.H.: Atomic-scale geometry and electronic structure of catalytically important Pd/Au alloys. ACS Nano 4, 1637 (2010).CrossRefGoogle ScholarPubMed
Li, J., Pu, M., Ma, C., Tian, Y., He, J., and Evans, D.G.: The effect of palladium clusters (Pdn, n = 2–8) on mechanisms of acetylene hydrogenation: A DFT study. J. Mol. Catal. A: Chem. 359, 14 (2012).CrossRefGoogle Scholar