Published online by Cambridge University Press: 31 January 2011
Thin films of aluminum oxide and titanium dioxide have been deposited onto gallium arsenide at low temperatures (<200 °C). A high-pressure xenon–mercury are lamp (1 kW) and a frequency doubled argon ion laser (100 mW at 257 nm) have been used as illumination sources Suitable volatile metallo-organic precursors have been synthesized with strong absorptions at the wavelengths of the light sources. The Al2O3 or TiO2 layers grown at 200 °C or less are amorphous although the anatase phase of TiO2 is deposited at temperatures over 350 °C. Ellipsometry has been used to measure the thickness and refractive index of the films. Films have been deposited onto gold on silicon in order to make simple electrical measurements. Resistivity, dielectric constant, loss factor, and breakdown voltage have been measured. The results shows values in good agreement with the results published on films grown by other CVD techniques using much higher temperatures.