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Portable solid rapid quantitative detection for Cu2+ ions: Tuning the detection range limits of fluorescent conducting polymer dots

Published online by Cambridge University Press:  27 March 2017

Shizhen Zhao ,
Siwei Yang ,
Xun Song ,
Gang Wang ,
Yucheng Yang ,
Fang Liao  and
Guqiao Ding
Shizhen Zhao
Affiliation:
Chemical Synthesis and Pollution Control, Key Laboratory of Sichuan Province, School of Chemistry and Chemical Industry, China West Normal University, Nanchong 637002, China
Siwei Yang
Affiliation:
State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai 20050, China
Xun Song
Affiliation:
Chemical Synthesis and Pollution Control, Key Laboratory of Sichuan Province, School of Chemistry and Chemical Industry, China West Normal University, Nanchong 637002, China
Gang Wang
Affiliation:
Department of Microelectronic Science and Engineering, Faculty of Science, Ningbo University, Ningbo, Zhejiang 315211, China
Yucheng Yang
Affiliation:
State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai 20050, China
Fang Liao*
Affiliation:
Chemical Synthesis and Pollution Control, Key Laboratory of Sichuan Province, School of Chemistry and Chemical Industry, China West Normal University, Nanchong 637002, China
Guqiao Ding
Affiliation:
State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai 20050, China
*
a) Address all correspondence to this author. e-mail: liaofang407@163.com
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Abstract

In this work, o-phenylenediamine-m-phenylenediamine copolymer dots (omCPs) with designed surface groups are synthesized and characterized. Here, we explored a simple, rapid semiquantitative detection system for Cu2+ with a wide detection range (5–7 orders of magnitude) based on the fluorescence in the solid state of omCPs and their tunable detection limits. The construction and application of the rapid semiquantitative detection system for Cu2+ are developed and demonstrated for the practical applications. What’s more, the detection limit can be modulated easily by adjusting the surface groups of these dots through the monomer dose control before the co-polymerization. Moreover, we demonstrated that this new technological approach is suitable for the semiquantitative determination of other ions pollutants (i.e., Na+, K+, Cu2+, Pb2+, Hg2+, and NO2 −) in environmental water.

Keywords

chemical compositionenvironmentally protectivenanostructure
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 8 , 28 April 2017 , pp. 1582 - 1593
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

b)

These authors contributed equally to this work.

Contributing Editor: Tao Xie

References

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