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Preparation and characterization of conducting nylon 6 fibers

Published online by Cambridge University Press:  31 January 2011

Sunil K. Narayanankutty*
Affiliation:
Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Cochin 682 022, Kerala, India
*
a) Address all correspondence to this author. e-mail: sunil@cusat.ac.in
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Abstract

Conducting nylon 6 fibers were prepared by in situ polymerization of aniline on to the fiber surface, after providing a chemical etching treatment to the fibers using chromic acid. The properties of the etched and polyaniline (PANI) coated fibers were evaluated using scanning electron microscopy, x-ray photoelectron spectroscopy, infrared spectroscopy, x-ray diffraction, thermogravimetry, and differential scanning calorimetry. Though the etching process caused a marginal decline in the mechanical properties of the fiber, it provided a reasonably rough surface for PANI adhesion and enhanced the conductivity of the fiber. The conductivity increased from 4.22 × 10−2 to 3.72 × 10−1 S/cm at an etching time of 4 h.

Type
Articles
Copyright
Copyright © Materials Research Society 2009

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References

1Genies, E.M., Petrescu, C., and Olmedo, L.: Conducting materials from polyaniline on glass textile. Synth. Met. 41–43, 665 (1991).CrossRefGoogle Scholar
2Gregory, R.V., Kimbrell, W.C., and Kuhn, H.H.: Conductive textiles. Synth. Met. 28, 823 (1989).CrossRefGoogle Scholar
3Forveille, J.L. and Olmedo, L.: Controlling the quality of deposits of polyaniline synthesized on glass fiber fabric. Synth. Met. 65, 5 (1994).CrossRefGoogle Scholar
4Byun, S.W. and Im, S.S.: Preparation and properties of transparent conducting nylon6- based composite films. J. Appl. Polym. Sci. 51, 1221 (1994).Google Scholar
5Park, Y.H., Choi, S.H., and Miyata, S.: Synthesis of highly conducting nylon-6 composites and their electrical properties. J. Appl. Polym. Sci. 45, 843 (1992).CrossRefGoogle Scholar
6Tzou, K. and Gregory, V.: Kinetic-study of the chemical polymerization of aniline in aqueous-solutions. Synth. Met. 47, 267 (1992).CrossRefGoogle Scholar
7Anbarasan, R., Jayaseharan, J., Sudha, M., Devi, J.L., Nirmala, P.V., and Gopalan, A.: Peroxosalts initiated graft copolymerization of aniline onto rayon fiber: A kinetic approach. Appl. Polym. Sci. 81, 468 (2001).CrossRefGoogle Scholar
8Anbarasan, R., Vasudevan, T., and Gopalan, A.: Peroxosalts initiated graft-copolymerization of aniline onto wool fiber: A comparative kinetic study. J. Mater. Sci. 35, 617 (2000).CrossRefGoogle Scholar
9Anbarasan, R., Vasudevan, T., Kalaignan, G.P., and Gopalan, A.: Chemical grafting of aniline and o-toludine onto poly(ethyleneterephthalate) fiber. J. Appl. Polym. Sci. 73, 121 (1999).3.0.CO;2-9>CrossRefGoogle Scholar
10Oh, K.W., Hong, K.H., and Kim, S.H.: Electrically conductive textiles by in situ polymerization of aniline. J. Appl. Polym. Sci. 74, 2094 (1999).3.0.CO;2-9>CrossRefGoogle Scholar
11Oh, K.W., Kim, S.H., and Kim, E.A.: Improved surface characteristics and the conductivity of polyaniline-nylon-6 fabrics by plasma treatment. J. Appl. Polym. Sci. 81, 684 (2001).CrossRefGoogle Scholar
12Wunderlich, B.: Thermal Analysis (Academic Press, 1990), p. 417.Google Scholar
13Blaine, R.L.: TN48, Polymer Heats of Fusion (TA Instruments, New Castle, DE).Google Scholar
14Chipara, M., Hui, D., Notingher, P.V., Chipara, M.D., Lau, K.T., Sankar, J., and Panaitescu, D.: On polyethylene-polyaniline composites. Composites part B 34, 637 (2001).Google Scholar
15Choda, K.I.Omastova, M. and Pionteck, J.: Relation between electrical and mechanical properties of conducting polymer composites. J. Appl. Polym. Sci. 82, 1903 (2001).CrossRefGoogle Scholar
16Hong, K.H., Oh, K.W., and Kang, T.J.: Preparation of conducting nylon-6 electrospun fiber webs by the insitu polymerization of polyaniline. J. Appl. Polym. Sci. 96, 983 (2005).CrossRefGoogle Scholar
17Hong, K.H., Oh, K.W., and Kang, T.J.: Preparation and properties of electrically conducting textiles by in situ polymerization of poly (3,4-ethylenedioxythiophene). J. Appl. Polym. Sci. 97, 1326 (2005).CrossRefGoogle Scholar
18Muellerleile, J.T. and Freeman, J.J.: Effect of solvent precipitation on the crystallization behavior and morphology of nylon 6,6. J. Appl. Polym. Sci. 54, 135 (1994).CrossRefGoogle Scholar
19Byun, S.W. and Im, S.S.: Physical properties and doping characteristics of polyaniline-nylon 6 composite films. Polymer (Guildf.) 39, 485 (1998).Google Scholar
20Stejskal, J., Riede, A., Hlavata, D., Prokes, J., Helmstedt, M., and Holler, P.: The effect of polymerization temperature on molecular weight, crystallinity, and electrical conductivity of polyanilin. Synth. Met. 96, 55 (1998).CrossRefGoogle Scholar
21Armes, S.P., Aldissi, M., Hawley, M., Beery, J.G., and Gottesfeld, S.: Morphology and structure of conducting polymers. Langmuir 7, 1447 (1991).CrossRefGoogle Scholar
22Armes, S.P., Gottesfeld, S., Beery, J.G., Garzon, F., Mombourquette, C., Hawley, M., and Kuhn, H.H.: Characterization of conducting polymer-quartz composites. J. Mater. Chem. 1, 525 (1991).CrossRefGoogle Scholar
23Beadle, P., Armes, S.P., Gottesfeld, S., Mombourquette, C., Houlton, R., Andrews, W.D., and Agnew, S.F.: Electrically conductive polyaniline-copolymer latex composites. Macromolecules 25, 2526 (1992).CrossRefGoogle Scholar
24Lascelles, S.F. and Armes, S.P.: Synthesis and characterization of micrometre-sized, polypyrrole-coated polystyrene latexes. J. Mater. Chem. 7, 1339 (1997).CrossRefGoogle Scholar
25Oh, K.W., Park, H.J., and Kim, S.H.: Stretchable conductive fabric for electrotherapy. J. Appl. Polym. Sci. 88, 1225 (2003).CrossRefGoogle Scholar
26Pud, A.A., Tabellout, M., Kassiba, A., Korzhenko, A.A., Rogalsky, S.P., Shapoval, G.S., Houzé, F., Schneegans, O., and Emery, J.R.: The poly(ethylene terephthalate)/polyaniline composite: AFM, DRS and EPR investigations of some doping effects. J. Mater. Sci. 36, 3355 (2001).CrossRefGoogle Scholar
27Poughet, J.P., Jozefowicz, M.E., Epstein, A.J., Tang, X., and Diarmid, A.G. Mac: X-ray structure of polyaniline. Macromolecules 24, 779 (1991).CrossRefGoogle Scholar
28Ram, M.S. and Palaniappan, S.: A process for the preparation of polyaniline salt doped with acid and surfactant groups using benzoyl peroxide. J. Mater. Sci. 39, 3069 (2004).CrossRefGoogle Scholar
29Wei, Y. and Hsueh, K.F.: Thermal analysis of chemically synthesized polyaniline and effects of thermal aging on conductivity. J. Polym. Sci. Part Polym. Chem. 27, 4351 (1989).CrossRefGoogle Scholar
30Hong, K.H., Oh, K.W., and Kang, T.J.: Preparation and properties of electrically conducting textiles by in situ polymerization of poly(3,4-ethylenedioxythiophene). J. Appl. Polym. Sci. 97, 1326 (2005).CrossRefGoogle Scholar
31Chen, C.H.: Thermal studies of polyaniline doped with dodecyl benzene sulfonic acid directly prepared via aqueous dispersions. J. Polym. Res. 9, 195 (2002).CrossRefGoogle Scholar
32Wang, H.L., Toppare, L., and Fernandez, J.E.: Conducting polymer blends: Polythiophene and polypyrrole blends with polystyrene and poly(bisphenol A carbonate). Macromolecules 23, 1053 (1990).CrossRefGoogle Scholar
33Wang, H.L. and Fernandez, J.E.: Conducting polymer blends: Polypyrrole and poly (vinyl methyl ketone). Macromolecules 25, 6179 (1992).CrossRefGoogle Scholar
34Abraham, D., Bharathi, A., and Subramanyam, S.V.: Highly conducting polymer blend films of polyaniline and nylon 6 by cosolvation in an organic acid. Polymer (Guildf.) 37, 5295 (1996).CrossRefGoogle Scholar
35Byun, S.W. and Im, S.S.: Physical properties and doping characteristics of polyaniline-nylon 6 composite films. Polymer (Guildf.) 39, 485 (1998).Google Scholar
36Pud, A., Ogurtsov, N., Korzhenko, A., and Shapoval, G.: Some aspects of preparation methods and properties of polyaniline blends and composites with organic polymers. Prog. Polym. Sci. 28, 1701 (2003).CrossRefGoogle Scholar