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Preparation and photocatalytic performance of Ag/AgCl-modified cubic ZHS hollow particles

Published online by Cambridge University Press:  28 May 2014

Wenyan Wang
Affiliation:
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
Yiming He
Affiliation:
Department of Materials Physics, Zhejiang Normal University, Jinhua 321004, China
Tinghua Wu*
Affiliation:
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
Ying Wu*
Affiliation:
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
*
a)Address all correspondence to these authors. e-mail: thwu@zjnu.cn
b)e-mail: yingwu@zjnu.cn
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Abstract

SnZn(OH)6 (ZHS) hollow cubes were synthesized by a facile self-templated method at room temperature, and Ag/AgCl/ZHS particles were prepared by a photodepositing method. The crystalline structure and morphology of the prepared particles were characterized by x-ray diffraction, UV-vis diffuse reflectance spectroscopy, scanning electron microscopy, and N2 adsorption. The results indicated that the particles had almost uniform monoclinic geometry and size. The photocatalytic oxidation of Rhodamine B was used to evaluate the photocatalytic activity of the synthesized photocatalysts. It is found that the hollow Ag/AgCl/ZHS showed the highest catalytic performance under visible or UV light, which can be attributed to the synergetic effect of Ag, AgCl, and ZHS.

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Articles
Copyright
Copyright © Materials Research Society 2014 

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