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Preparation, microstructure, and compressive strength of carbon foams derived from sucrose and kaolinite

Published online by Cambridge University Press:  14 March 2014

Haipeng Ji ,
Zhaohui Huang ,
Xiaowen Wu ,
Juntong Huang ,
Kai Chen ,
Minghao Fang  and
Yan’gai Liu
Haipeng Ji
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Zhaohui Huang*
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Xiaowen Wu
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Juntong Huang*
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Kai Chen
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Minghao Fang
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Yan’gai Liu
Affiliation:
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
*
a)Address all correspondence to this author. e-mail: huang118@cugb.edu.cn
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Abstract

Carbon foams were successfully fabricated from sucrose and kaolinite clay by thermo-foaming method using aluminum nitrate as the blowing agent. The phases, pore structure, and compressive strength were characterized by x-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, and mechanical test, respectively. The foams had porous structure with spherical open cells of size in the range of 400–1000 μm, dense struts, and interconnected voids of size in the range of 100–600 μm. Both smooth and coarse types of voids are observed. Mullite and cristobalite, products of the clay mineral, are concentrated more on the strut and cell walls. The ultimate compressive strength evolution is found to be in correlation with the amount of voids and the microcracking in the carbon foams.

Keywords

carbonizationfoammicrostructure
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 8 , 28 April 2014 , pp. 1018 - 1025
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Ford, W.D.: Cellular refractory thermal insulating material. U.S. Patent No. 3 121 050, 1964.Google Scholar
Googin, J., Napier, J., and Scrivner, M.: Method for making manufacturing foam carbon products. U.S. Patent No. 3 345 440, 1967.Google Scholar
Gallego, N.C. and Klett, J.W.: Carbon foams for thermal management. Carbon 41, 1461 (2003).Google Scholar
Amini, N., Aguey-Zinsou, K.F., and Guo, Z.X.: Processing of strong and highly conductive carbon foams as electrode. Carbon 49, 3857 (2011).Google Scholar
Mehtaa, R., Andersonb, D.P., and Hagerc, J.W.: Graphitic open-celled carbon foams: processing and characterization. Carbon 41, 2174 (2003).CrossRefGoogle Scholar
Mukai, S.R., Tamitsuji, C., Nishihara, H., and Tamon, H.: Preparation of mesoporous carbon gels from an inexpensive combination of phenol and formaldehyde. Carbon 43, 2628 (2005).Google Scholar
Nishihara, H., Mukai, S.R., and Tamon, H.: Preparation of resorcinol-formaldehyde carbon cryogel microhoneycombs. Carbon 42, 899 (2004).CrossRefGoogle Scholar
Yamashita, J., Ojima, T., Shioya, M., Hatori, H., and Yamada, Y.: Organic and carbon aerogels derived from poly (vinyl chloride). Carbon 41, 285 (2003).Google Scholar
Inagaki, M., Morishita, T., Kuno, A., Kito, T., Hirano, M., Suwa, T., and Kusakawa, K.: Carbon foams prepared from polyimide using urethane foam template. Carbon 42, 497 (2004).Google Scholar
Klett, J.W., Mcmillan, A.D., Gallego, N.C., and Walls, C.A.: The role of structure on the thermal properties of graphitic foams. J. Mater. Sci. 39, 3659 (2004).Google Scholar
Li, T.Q., Wang, C.Y., An, B.X., and Wang, H.: Preparation of graphitic carbon foam using size-restriction method under atmospheric pressure. Carbon 43, 2030 (2005).CrossRefGoogle Scholar
Ryoo, R., Joo, S.H., Kruk, M., and Jaroniec, M.: Ordered mesoporous carbons. Adv. Mater. 13, 677 (2001).Google Scholar
Bakandritsos, A., Steriotis, T., and Petridis, D.: High surface area montmorillonite-carbon composites and derived carbon. Chem. Mater. 16, 1551 (2004).Google Scholar
Scherdel, C. and Reichenauer, G.: Microstructure and morphology of porous carbons derived from sucrose. Carbon 47, 1102 (2009).Google Scholar
Cao, Y., Cao, J., Zheng, M., Liu, J., and Ji, G.: Synthesis, characterization, and electrochemical properties of ordered mesoporous carbons containing nickel oxide nanoparticles using sucrose and nickel acetate in a silica template. J. Solid State Chem. 180, 792 (2007).Google Scholar
Armandi, M., Bonelli, B., Geobaldo, F., and Garrone, E.: Nanoporous carbon materials obtained by sucrose carbonization in the presence of KOH. Microporous Mesoporous Mater. 132, 414 (2010).Google Scholar
Böhme, K., Einicke, W.D., and Klepel, O.: Templated synthesis of mesoporous carbon from sucrose-the way from the silica pore filling to the carbon material. Carbon 43, 1918 (2005).CrossRefGoogle Scholar
Prabhakaran, K., Singh, P.K., Gokhale, N.M., and Sharma, S.C.: Processing of sucrose to low density carbon foams. J. Mater. Sci. 42, 3894 (2007).Google Scholar
Narasimman, R. and Prabhakaran, K.: Preparation of carbon foams by thermo-foaming of activated carbon powder dispersions in an aqueous sucrose resin. Carbon 50, 5583 (2012).Google Scholar
Narasimman, R. and Prabhakaran, K.: Preparation of low density carbon foams by foaming molten sucrose using an aluminium nitrate blowing agent. Carbon 50, 1999 (2012).CrossRefGoogle Scholar
Wang, X.Y., Zhong, J.M., Wang, Y.M., and Yu, M.F.: A study of the properties of carbon foam reinforced by clay. Carbon 44, 1560 (2006).Google Scholar
Wu, X.W., Liu, Y.G., Fang, M.H., Mei, L.F., and Luo, B.C.: Preparation and characterization of carbon foams derived from aluminosilicate and phenolic resin. Carbon 49, 1782 (2011).Google Scholar
Wu, X.W., Fang, M.H., Mei, L.F., and Luo, B.C.: Effect of final pyrolysis temperature on the mechanical and thermal properties of carbon foams reinforced by aluminosilicate. Mater. Sci. Eng., A 558, 446 (2012).Google Scholar
Sanz, J., Madani, A., and Serratosa, J.M.: Aluminum-27 and silicon-29 magic-angle-spinning nuclear magnetic resonance study of the kaolinite-mullite transformation. J. Am. Ceram. Soc. 71, 418 (1988).Google Scholar
Klett, J., Hardy, R., Romine, E., Walls, C., and Burchell, T.: High-thermal-conductivity, mesophase-pitch-derived carbon foams: effect of precursor on structure and properties. Carbon 38, 953 (2000).Google Scholar
Wang, S.B., Luo, R.Y., and Ni, Y.F.: Preparation and characterization of resin-derived carbon foams reinforced by hollow ceramic microspheres. Mater. Sci. Eng., A 527, 3392 (2010).Google Scholar
He, X., Tang, Z.H., Zhu, Y.F., and Yang, J.H.: Fabrication of carbon foams with low thermal conductivity using the protein foaming method. Mater. Lett. 94, 55 (2013).Google Scholar
Shen, H.B. and Nutt, S.: Mechanical characterization of short fiber reinforced phenolic foam. Compos. Part A 34, 899 (2003).CrossRefGoogle Scholar
Voigt, C., Storm, J., Abendroth, M., Aneziris, C.G., Kuna, M., and Hubaálková, J.: The influence of the measurement parameters on the crushing strength of reticulated ceramic foams. J. Mater. Res. 28, 2288 (2013).CrossRefGoogle Scholar
Seeber, B.S.M., Gonzenbach, U.T., and Gauckler, L.J.: Mechanical properties of highly porous alumina foams. J. Mater. Res. 28, 2281 (2013).Google Scholar