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Preparation of Epitaxial BaTiO3 Thin Films by the Dipping-pyrolysis Process

Published online by Cambridge University Press:  31 January 2011

S. Kim ,
T. Manabe ,
I. Yamaguchi ,
T. Kumagai  and
S. Mizuta
S. Kim
Affiliation:
Department of Chemical Engineering, Yosu Fisheries University, Yosu 550–749, Korea
T. Manabe
Affiliation:
National Institute of Materials and Chemical Research, Tsukuba, Ibaraki 305, Japan
I. Yamaguchi
Affiliation:
National Institute of Materials and Chemical Research, Tsukuba, Ibaraki 305, Japan
T. Kumagai
Affiliation:
National Institute of Materials and Chemical Research, Tsukuba, Ibaraki 305, Japan
S. Mizuta
Affiliation:
National Institute of Materials and Chemical Research, Tsukuba, Ibaraki 305, Japan
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Abstract

Epitaxial BaTiO3 thin films were prepared on SrTiO3 (100) substrates by the dipping-pyrolysis process using metal naphthenates as starting materials. Highly oriented BaTiO3 thin films were crystallized by heat treatment at 800 °C and higher, from amorphous precursor films pyrolyzed at 470 °C. XRD pole-figure and reciprocal-space mapping analyses showed that the films were epitaxially grown on SrTiO3substrates and were pseudocubic phase with an a║/aτ ratio of 1.003, smaller than the c0/a0 ratio (=1.011) of bulk tetragonal BaTiO3.

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Type
Articles
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Journal of Materials Research , Volume 12 , Issue 4 , April 1997 , pp. 1141 - 1144
Copyright
Copyright © Materials Research Society 1997

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