Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-13T06:07:44.311Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Eu3+ doped Al5BO9 red phosphor by a facile thermal conversion method and its enhanced luminescent property

Published online by Cambridge University Press:  15 April 2016

Yu-Yan Liang  and
Zhi-Hong Liu
Yu-Yan Liang
Affiliation:
Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, People's Republic of China
Zhi-Hong Liu*
Affiliation:
Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, People's Republic of China
*
a)Address all correspondence to this author. e-mail: liuzh@snnu.edu.cn
Get access

Abstract

A new red-emitting phosphor, Eu3+ doped Al5BO9, was prepared for the first time by calcining the precursor of K2[Al(B5O10)]·4H2O:Eu3+ which was synthesized by a facile hydrothermal route. The obtained samples were characterized by energy dispersive x-ray spectrometer, x-ray powder diffraction, IR, scanning electron microscopy, photoluminescence, and photoluminescence excitation spectrum (PLE). Moreover, the influences of Eu3+ doping concentration, calcination temperature, and calcination time on the luminescence properties of Al5BO9:Eu3+ phosphor were also investigated. The phosphor with optimal luminescent intensity and the higher red/orange ratio was obtained by sintering the precursor at 1300 °C for 5.5 h, with 5% doping concentration, in which its luminescent decay lifetime and quantum efficiency were also measured. It is also found that the phosphor prepared by conventional solid-state reaction method exhibits the dominant transition at 591 nm (orange) with the lower color purity, while the phosphor prepared by the present precursor method exhibits the dominant transition at 615 nm (red) with the higher color purity, which indicates that this is a good method for preparing Al5BO9:Eu3+ red phosphor.

Keywords

optical propertiesluminescencephase transformation
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 10 , 28 May 2016 , pp. 1433 - 1439
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Liu, J., Wang, X.D., Wu, Z.C., and Kuang, S.P.: Preparation, characterization and photoluminescence properties of BaB2O4:Eu3+ red phosphor. Spectrochim. Acta, Part A 79, 1520 (2011).Google Scholar
Cavalcante, L.S., Sczancoski, J.C., Albarici, V.C., Matos, J.M.E., Varela, J.A., and Longo, E.: Synthesis, characterization, structural refinement and optical absorption behavior of PbWO4 powders. Mater. Sci. Eng., B 150, 18 (2008).Google Scholar
Elssfah, E. and Tang, C.: From Al4B2O9 nanowires to Al18B4O33:Eu nanowires. J. Phys. Chem. C 111, 8176 (2007).Google Scholar
Pekgözlü, I., Taşcıālu, S., and Menger, A.: Luminescence of Pb2+ in MAl2B2O7 (M = Ca, Sr). Inorg. Mater. 44, 1151 (2008).Google Scholar
Sun, H.T., Shimaoka, F., Fujii, M., Nitta, N., Mizuhata, M., Yasuda, H., Dekiand, S., and Hayashi, S.: Controlled synthesis and luminescent properties of erbium silicate nanostructures. Nanotechnology 9, 6277 (2009).Google Scholar
Jia, L.Y., Shao, Z.B., Lüd, Q., Tian, Y.W., and Han, J.F.: Optimum europium doped aluminoborates phosphors and their photoluminescence properties under VUV and UV excitation. Opt. Laser Technol. 54, 79 (2013).Google Scholar
Liao, J. S., Huang, H.Z., You, H.Y., Qiu, X., Li, Y., Qiu, B., and Wen, H.R.: Photoluminescence properties of NaGd(MoO4)2:Eu3+ nanophosphors prepared by sol–gel method. Mater. Res. Bull. 45, 1145 (2010).Google Scholar
Rong, C., Yu, Z.W., Wang, Q., Zheng, S.T., Pan, C.Y., Deng, F., and Yang, G.Y.: Aluminoborates with open frameworks: Syntheses, structures, and properties. Inorg. Chem. 48, 3650 (2009).Google Scholar
Fisch, M., Armbruster, T., Rentsch, D., Libowitzky, E., and Pettke, T.: Crystal-chemistry of mullite-type aluminoborates Al18B4O33 and Al5BO9: A stoichiometry puzzle. J. Solid State Chem. 184, 70 (2011).Google Scholar
Kumar, R.S. and Ponnusamy, V.: Phase formation and photoluminescence properties of Sm3+ doped Al5BO9 phosphor. Optik 126, 1224 (2015).Google Scholar
Jung, K.Y., Lee, C.H., and Kang, Y.C.: Effect of surface area and crystallite size on luminescent intensity of Y2O3:Eu phosphor prepared by spray pyrolysis. Mater. Lett. 59, 2451 (2005).Google Scholar
Lian, J.B., Liu, F., Wang, X.J., and Sun, X.D.: Hydrothermal synthesis and photoluminescence properties of Gd2O2SO4:Eu3+ spherical phosphor. Powder Technol. 253, 187 (2014).Google Scholar
Parchura, K. and Ningthoujam, R.S.: Behaviour of electric and magnetic dipole transitions of Eu3+, 5D0–7F0 and Eu–O charge transfer band in Li+ co-doped YPO4:Eu3+. RSC. Adv. 2, 10859 (2012).Google Scholar
Yu, M., Lin, J., Wang, Z., Fu, J., Wang, S., Zhang, H.J., and Han, Y.C.: Fabrication, patterning, and optical properties of nanocrystalline YVO4:A (A = Eu3+, Dy3+, Sm3+, Er3+) phosphor films via sol–gel soft lithography. Chem. Mater. 14, 2224 (2002).Google Scholar
Li, G.F., Cao, Q.X., Li, Z.M., and Huang, Y.X.: Luminescence properties of YAl3(BO3)4 phosphors doped with Eu3+ ions. J. Rare Earths 26, 792 (2008).Google Scholar
Kim, K.B., Kim, Y.I., Chun, H.G., Cho, T.Y., Jung, J.S., and Kang, J.G.: Structural and optical properties of BaMgAl10O17:Eu2+ phosphor. Chem. Mater. 14, 5045 (2002).Google Scholar
Liu, X.M., Lin, C.K., and Lin, J.: Thermally stable luminescence of KSrPO4:Eu2+ phosphor for white light UV light-emitting diodes. Appl. Phys. Lett. 90, 151108 (2007).Google Scholar
Lei, F., Yan, B., Chen, H.H., and Zhao, J.T.: Surfactant-assisted hydrothermal synthesis of Eu3+-doped white light hydroxyl sodium yttrium tungstate microspheres and their conversion to NaY(WO4)2. Inorg. Chem. 48, 7576 (2009).Google Scholar
Wang, X., Liang, P., Huang, H.S., and Liu, Z.H.: Preparation of LaB3O6:Eu3+ phosphors by a facile precursor method and their luminescent properties. Mater. Res. Bull. 52, 112 (2014).Google Scholar
Gatta, G.D., Rotiroti, N., Fisch, M., and Armbruster, T.: Stability at high pressure, elastic behavior and pressure-induced structural evolution of “Al5BO9”, a mullite-type ceramic material. Phys. Chem. Miner. 37, 227 (2010).Google Scholar