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Preparation of large single grains of the quasicrystalline icosahedral Al–Cu–Fe ψ phase

Published online by Cambridge University Press:  31 January 2011

T.A. Lograsso
Affiliation:
Metallurgy and Ceramics Program, Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011
D.W. Delaney
Affiliation:
Metallurgy and Ceramics Program, Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011
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Abstract

A cyclic heat-treatment process was used to prepare single grains of the quasicrystalline icosahedral phase, ψ–Al65Cu23Fe12. Alloys of appropriate composition are melted and chill cast into copper molds. Multiple cyclic heat treatments at successively higher temperatures below 860 °C, the peritectic decomposition temperature of the quasicrystal phase, are used to enhance the growth of the ψ phase. Single grains up to 10 mm × 5 mm × 5 mm have been prepared.

Type
Articles
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1.Bradley, A. J. and Goldschmidt, H. J., J. Inst. Met. 65, 403 (1939).Google Scholar
2.Gayle, F. W., Shapiro, A. J., Biancaniello, F. S., and Boet-tinger, W. J., Metall. Trans. 23A, 2409 (1992).CrossRefGoogle Scholar
3.Gratias, D., Calvayrac, Y., Devaud-Rzepski, J., Faudot, F., Harmelin, M., Quivy, A., and Bancel, P.A., J. Non-Cryst. Solids 153 & 154, 482 (1993).CrossRefGoogle Scholar
4.Lograsso, T. A. and Haines, S. A., J. Non-Cryst. Solids (in press).Google Scholar
5.Shields, J. E., Hoppe, C., McCallum, R.W., Goldman, A. I., Kelton, K.F., and Gibbons, P.C., Phys. Rev. B 45, 2063 (1992).CrossRefGoogle Scholar
6.Goldman, A. I. and Kelton, K. F., Rev. Mod Phys. 65, 213 (1993).CrossRefGoogle Scholar
7.Tsai, A. P., Inoue, A., and Masumoto, T., Jpn. J. Appl. Phys. 26, L1505 (1987).CrossRefGoogle Scholar
8.Bancel, P. A., Phys. Rev. Lett. 63, 2741 (1989).CrossRefGoogle Scholar
9.Calvayrac, Y., Quivy, A., Bessiere, M., Lefebvre, S., Cornier-Quiquandon, M., and Gratias, D., J. Phys. Paris 51, 417 (1990).Google Scholar
10.Ishimasa, T. and Mori, M., Philos. Mag. Lett. 62, 357 (1990).CrossRefGoogle Scholar
11.Kronberg, M.L. and Wilson, F.H., Trans. AIME 185, 501 (1949).Google Scholar
12.Lacombe, J. P., Ambrosis de Libamait, N., and Calais, D., Compt. Rend. (Paris) 249, 2769 (1959).Google Scholar