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Preparation of Polymer-Covered Metal Nanorods and Metal Microcrystals by Intrinsic Two-Dimensional Crystalline Lattice Templating

Published online by Cambridge University Press:  03 March 2011

Alexandru C. Pavel ,
Dwight K. Romanovicz ,
Miguel J. Yacaman  and
John T. McDevitt
Alexandru C. Pavel
Affiliation:
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0165
Dwight K. Romanovicz
Affiliation:
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0165
Miguel J. Yacaman
Affiliation:
Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712-0231; and Texas Materials Institute, University of Texas at Austin, Austin, Texas 78712-1063
John T. McDevitt
Affiliation:
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0165; Center for Nano- and Molecular Science and Technology, University of Texas at Austin, Austin, Texas 78712-1063; and Texas Materials Institute, University of Texas at Austin, Austin, Texas 78712-1063
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Abstract

Two-dimensional layered ceramics, highly anisotropic materials in terms of structure and properties, were used to produce polymer-covered metal nanorods and metal microcrystals. The procedure took advantage of the intrinsic planar, layered ordering of the metal cations suitable to be reduced and could be further used to engineer one-dimensional metal alloy nanostructures by appropriate doping of the initial layered ceramic lattice with suitable cationic species. The procedure involved the formation in an intermediate step of a polymer-intercalated ceramic nanocomposite, highly porous to the diffusion of the polymerizable reducing agent, pyrrole. Two structurally similar layered bismuthates, Bi2Sr2CaCu2O8+δ and Bi6Sr2CaO12 and a partially Rh-substituted ceramic, Bi4Rh2Sr2CaO12 were used as the precursor layered ceramics and the reducible metal cations were Cu2+, Bi3+, and Rh3+, respectively. The formation of the polymer-covered metal nanorods and metal microcrystals took place at relatively high temperatures of reaction (325 °C) and long reaction times (10–12 days).

Keywords

CeramicLayeredSuperconductor
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 11 , November 2005 , pp. 3034 - 3046
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1Schoellhorn, R. Materials and models: Faces of intercalation chemistry, in Progress in Intercalation Research , edited by Mueller-Warmuth, W. and Schoellhorn, R. (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994), p. 1.Google Scholar
2Clearfield, A. Intercalation chemistry of selected layered oxides and phosphates, in Progress in Intercalation Research , edited by Mueller-Warmuth, W. and Schoellhorn, R. (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994), p. 223.CrossRefGoogle Scholar
3Behrens, P., Panz, C., Kuehn, C., Pillep, B. and Schneider, A. Guest functionalized crystalline organic–inorganic nanohybrid materials, in Host–Guest Systems Based on Nanoporous Crystals , edited by Laeri, F., Schueth, F., Simon, U., and Wark, M. (Wiley-VCH, Weinheim, Germany, 2003), p. 7.CrossRefGoogle Scholar
4Horiuchi, S. and Takayama-Muromachi, E. Crystal structure, in Bismuth-Based High-Temperature Superconductors , edited by Maeda, H. and Togano, K. (Marcel Dekker, Inc., New York, 1996), p. 7.Google Scholar
5Conflant, P., Boivin, J-C. and Thomas, D.: Etude structurale du conducteur anionique Bi0,765Sr0,235O1,383. J. Solid State Chem. 35, 192 (1980).CrossRefGoogle Scholar
6Xiang, X.-D., McKernan, S., Vareka, W.A., Zettl, A., Corkill, J.L., III, T.W. Barbee and Cohen, M.L.: Iodine intercalation of a high-temperature superconducting oxide. Nature 348, 145 (1990).CrossRefGoogle Scholar
7Xiang, X.-D., Vareka, W.A., Zettl, A., Corkill, J.L., III, T.W. Barbee, Cohen, M.L., Kijima, N. and Gronsky, R.: Tuning high-Tc superconductors via multistage intercalation. Science 254, 1487 (1991).CrossRefGoogle ScholarPubMed
8Xiang, X.-D., Vareka, W.A., Zettl, A., Corkill, J.L., III, T.W. Barbee and Cohen, M.L.: Epitaxial intercalation of the Bi–Sr–Ca–Cu–O superconductor series. Phys. Rev. B 43(13), 11496 (1991).CrossRefGoogle ScholarPubMed
9Kijima, N., Gronsky, R., Xiang, X.-D., Vareka, W.A., Zettl, A., Corkill, J.L., III, T.W. Barbee and Cohen, M.L.: Crystal structure of stage-1 iodine-intercalated superconducting IBi2Sr2CaCu2Ox Physica C 181, 18 (1991).CrossRefGoogle Scholar
10Scarfe, D.P., Bhavaraju, S. and Jacobson, A.J.: Iodine intercalation in the oxide-ion conductor BaBi8O13. Chem. Commun. 3, 313 (1997).CrossRefGoogle Scholar
11Scarfe, D.P. and Jacobson, A.J.: Iodine intercalation in the ionic conductor SrxBi9−xO(27−x)/2. Chem. Mater. 9, 3107 (1997).CrossRefGoogle Scholar
12Liang, W., Lei, J. and Martin, C.R.: Effect of synthesis temperature on the structure, doping level and charge-transport properties of polypyrrole. Synth. Met. 52, 227 (1992).CrossRefGoogle Scholar
13Lei, J., Liang, W. and Martin, C.R.: Infrared investigations of pristine, doped and partially doped polypyrrole. Synth. Met. 48, 301 (1992).CrossRefGoogle Scholar
14Lei, J., Cai, Z. and Martin, C.R.: Effect of reagent concentrations used to synthesize polypyrrole on the chemical characteristics and optical and electronic properties of the resulting polymer. Synth. Met. 46, 53 (1992).CrossRefGoogle Scholar
15Vernitskaya, T.V. and Efimov, O.N.: Polypyrrole: A conducting polymer: Its synthesis, properties and applications. Russ. Chem. Bull. 66, 443 (1997).CrossRefGoogle Scholar
16Kim, J., Sohn, D., Sung, Y. and Kim, E-R.: Fabrication and characterization of conductive polypyrrole thin film prepared by in situ vapor-phase polymerization. Synth. Met. 132, 309 (2003).CrossRefGoogle Scholar
17Kanatzidis, M.G., Tonge, L.M., Marks, T.J., Marcy, H.O. and Kannewurf, C.R.: In situ intercalative polymerization of pyrrole in FeOCl: A new class of layered, conducting polymer–inorganic hybrid materials. J. Am. Chem. Soc. 109, 3797 (1987).CrossRefGoogle Scholar
18Wang, L., Schindler, J., Thomas, J.A., Kannewurf, C.R. and Kanatzidis, M.G.: Entrapment of polypyrrole chains between MoS2 layers via an in-situ oxidative polymerization encapsulation reaction. Chem. Mater. 7, 1753 (1995).CrossRefGoogle Scholar
19Schweinfest, R., Paxton, A.T. and Finnis, M.W.: Bismuth embrittlement of copper is an atomic size effect. Nature 432, 1008 (2004).CrossRefGoogle Scholar
20 CRC Handbook of Chemistry and Physics, edited by Lide, D.R. (CRC Press, Boca Raton, FL, 1995), pp. 4–45.Google Scholar
21 CRC Handbook of Chemistry and Physics, edited by Lide, D.R. (CRC Press, Boca Raton, FL, 1995), pp. 12–14.Google Scholar