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Published online by Cambridge University Press: 03 March 2011
The refining of lead blast furnace bullion involves the transfer and handling of hot impure lead bullion. Fugitive emissions of lead-containing fumes create a plant hygiene problem. The cause of the emissions is the high vapor pressure of lead and its compounds when lead blast furnace bullion is transferred in an open ladle at ∼1000 °C from the blast furnace and poured into the drossing kettle, and later during the manual skimming of powdery dross. A laboratory study was conducted on a new concept for lead refining that eliminates contact between hot lead and the cnvironment, and thus abates fugitive lead emissions. The new process takes place in two steps: controlled solidification of bullion as it flows from the blast furnace, followed by remelting in a closed centrifuge to separate lead and dross. Refined lead was produced with <0.05% copper and <0.01% of all other impurities. Suggestions are outlined for implementing the process.