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Rare-earth transition-metal intermetallic compounds produced via self-propagating, high-temperature synthesis

Published online by Cambridge University Press:  31 January 2011

Joel P. McDonald ,
Mark A. Rodriguez ,
Eric D. Jones Jr.  and
David P. Adams
David P. Adams
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185
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Abstract

Several binary intermetallic compounds—each containing a rare-earth (RE) element paired with a transition metal (TM)—were prepared by self-propagating, high-temperature synthesis (SHS). Thin multilayers, composed of alternating Sc or Y (RE element) and Ag, Cu, or Au (TM), were first deposited by direct current magnetron sputtering. Once the initially distinct layers were stimulated and caused to mix, exothermic reactions propagated to completion. X-ray diffraction revealed that Sc/Au, Sc/Cu, Y/Au, and Y/Cu multilayers react in vacuum to form single-phase, cubic B2 structures. Multilayers containing Ag and a RE metal formed cubic B2 (RE)Ag and a minority (RE)Ag2 phase. The influence of an oxygen-containing environment on the reaction dynamics and the formation of phase were investigated, providing evidence for the participation of secondary combustion reactions during metal-metal SHS. High-speed photography demonstrated reaction propagation speeds that ranged from 0.1–40.0 m/s (dependent on material system and foil design). Both steady and spin-like reaction modes were observed.

Keywords

Combustion synthesis (SHS)Physical vapor deposition (PVD)X-ray diffraction (XRD)
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 4 , April 2010 , pp. 718 - 727
Copyright
Copyright © Materials Research Society 2010

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