Published online by Cambridge University Press: 31 January 2011
Reaction of Ni–Al alloys within the β-NiAl phase with CrB2 was studied at 1473 K as a function of Al concentration in the alloy. Reaction of 49–50 at. % Al alloys with CrB2 occurred by interdiffusion of Ni into CrB2 and Cr into the alloy without forming a new product phase. On the other hand, a new product phase, rich in Ni and B, formed by the reaction of alloys having Al concentrations 48 at. % or lower with CrB2. The reaction product was observed both at the CrB2/alloy interface and along the alloy grain boundaries.