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Role of Ru on the microstructure and property of novel Co–Ti–V Superalloy

Published online by Cambridge University Press:  10 September 2020

Pengjie Zhou*
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang212003, China
Xinkang Gao
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang212003, China
Dehang Song
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang212003, China
Qilong Liu
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang212003, China
Yinbing Liu
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang212003, China
Jun Cheng
Affiliation:
Northwest Institute for Nonferrous Metal Research, Shanxi Key Laboratory of Biomedical Metal Materials, Xi'an 710016, China State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China
*
a)Address all correspondence to this author. e-mail: zhoupengjie@just.edu.cn
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Abstract

In the present paper, the authors investigated the microstructures and mechanical properties of dual-phase Co–Ti–V-based superalloys with different additions of Ru. The results showed that with the increase of Ru contents, the size of γ′ precipitates of the alloy gradually raised, the volume fraction of γ′ phase slightly, and the lattice misfit between γ/γ′ phases increased. Ru was enriched in the γ′ phase, and the elemental partition coefficients (KX = Cγ/Cγ) of Ti and V increased with the increment of Ru. The Ru contents have no remarkable influence on the solvus temperatures of γ′ in the Co–Ti–V alloys. The yield strength at 1000 °C of the Co–10Ti–11V–0.5Ru alloy was the highest, while the yield strength of the 1Ru alloy was the smallest. Transmission electron microscopy and scanning electron microscopy observations showed that the γ′ shape in the compressed specimen containing 0.5Ru remain integrated, while the γ′ in other alloys were cut into several parts.

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Article
Copyright
Copyright © The Author(s), 2020. Published by Cambridge University Press on behalf of Materials Research Society

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References

Pollock, T.M. and Tin, S.: Nickel-based superalloys for advanced turbine engines: Chemistry, microstructure and properties. J. Propuls. Power 361, 22 (2006).Google Scholar
Pollock, T.M., Dibbern, J., Tsunekane, M., Zhu, J., and Suzuki, A.: New Co-based γ/γ′ high-temperature alloys. JOM 58, 62 (2010).Google Scholar
Lin, W.J., Duan, J.F., and Wang, C.L.: Study on precipitation enhancement of Ni-based superalloys. Foundry Technol. 607, 29 (2008).Google Scholar
Li, X.H., Gan, B., and Feng, Q.: Co-Al-W ternary alloy heat treatment organization. J. Sci. Eng. 1369, 30 (2008) (in Chinese).Google Scholar
Davis, J.R.: Nickel, Cobalt, and Their Alloys (ASM International, Materials Park, OH, USA, 2000).Google Scholar
Chinen, H., Sato, J., Omori, T., Oikawa, K., Ohnuma, I., Kainuma, R., and Ishida, K.: New ternary compound Co3(Ge, W) with L12 structure. Scr. Mater. 141, 56 (2007).Google Scholar
Davydov, A.V., Kattner, U.R., Jossel, D., Blendell, J.E., Waterstrat, R.M., Shaprio, A.J., and Boettinger, W.J.: Determination of the Co-Ti congruent Melting point and thermodynamic reassessment of the Co-Ti system. Metall. Mater. Trans. A 2175, 32 (2001).Google Scholar
Shinagawa, K., Chinen, H., Omori, T., Oikawa, K., Ohnuma, I., and Kainuma, R.: Phase equilibria and thermodynamic calculation of the Co-Ta binary system. Intermetallics 87, 49 (2014).Google Scholar
Zhu, L., Wei, C., Qi, H., Jiang, L., Jin, Z., and Zhao, J.C.: Experimental investigation of phase equilibria in the Co-rich part of the Co-Al-X (X = W, Mo, Nb, Ni, Ta) ternary systems using diffusion multiples. J. Alloy Compd. 110, 691 (2017).Google Scholar
Suzuki, A., Inui, H., and Pollock, T.M.: L12-strengthened cobalt-base superalloys. Annu. Rev. Mater. Res. 345, 45 (2015).Google Scholar
Tanake, K., Ohashi, T., and Kishida, K.: Single-crystal elastic constants of Co(Al,W) with the L12 structure. App. Phys. Lett. 307, 91 (2007).Google Scholar
Ooshima, M., Tanaka, K., Okamoto, N.L., Kishida, K., and Inui, H.: Effects of quaternary alloying elements on the γ′ solvus temperature of Co-Al-W based alloys with fcc/L12 two-phase microstructures. J. Alloy Compd. 71, 508 (2010).Google Scholar
Akanes, S. and Pollock, T.M.: High-temperature strength and deformation of γ/γ′ two-phase Co-Al-W-base alloys. Scr. Mater. 1288, 56 (2008).Google Scholar
Sato, J., Tomori, T., and Oikawa, K.: Cobalt-base high-temperature alloys. Science 90, 312 (2006).Google Scholar
Suzuki, A., DeNolf, G.C., and Pollock, T.M.: Flow stress anomalies in γ/γ′ two-phase Co-Al-W-base alloys. Scr. Mater. 385, 56 (2007).Google Scholar
Bauer, A., Neumeier, S., Pyczak, F., and Göken, M.: Microstructure and creep strength of different γ/γ′-strengthened Co-base superalloy variants. Scr. Mater. 1197, 63 (2010).Google Scholar
Omori, T., Oikawa, K., Sato, J., Ohnuma, I., Kattner, U.R., Kainuma, R., and Ishida, K.: Partition behavior of alloying elements and phase transformation temperatures in Co-Al-W-base quaternary systems. Intermetallics 274, 32 (2013).Google Scholar
Shinagawa, K., Omori, T., Oikawa, K., Kainuma, R., and Ishida, K.: Ductility enhancement by boron addition in Co-Al-W high-temperature alloys. Scr. Mater. 612, 61 (2009).Google Scholar
Shinagawa, K., Omori, T., Sato, J., Oikawa, K., Ohnuma, I., Kainuma, R., and Ishida, K.: Phase equilibria and microstructure on γ′ phase in Co-Ni-Al-W system. Mater. Trans. 1474, 49 (2008).Google Scholar
Tsukamoto, Y., Kobayashi, S., and Takasugi, T.: The stability of γ′-Co3(Al, W) phase in Co-Al-W ternary system. Mater. Sci. Forum 448, 654656 (2010).Google Scholar
Kobayashi, S., Tsukamoto, Y., Takasugi, T., Chinen, H., Omori, T., Ishida, K., and Zaefferer, S.: Determination of phase equilibria in the Co-rich Co-Al-W ternary system with a diffusion-couple technique. Intermetallics 1085, 17 (2009).Google Scholar
Kobayashi, S., Tsukamoto, Y., and Takasugi, T.: The effects of alloying elements (Ta, Hf) on the thermodynamic stability of γ′-Co3 (Al, W) phase. Intermetallics 94, 31 (2012).Google Scholar
Neumeier, S., Rehman, H.U., Neuner, J., Zenk, C.H., Michel, S., Schuwalow, S., Rogal, J., Drautz, R., and Goken, M.: Diffusion of solutes in fcc cobalt investigated by diffusion couples and first principles kinetic Monte Carlo. Acta Mater. 304, 106 (2016).Google Scholar
Bocchini, P.J., Sudbrack, C.K., Noebe, R.D., Dunand, D.C., and Seidman, D.N.: Microstructural and creep properties of boron- and zirconium-containing cobalt-based superalloys. Mater. Sci. Eng. A 260, 682 (2017).Google Scholar
Bocchini, P.J., Sudbrack, C.K., Noebe, R.D., Dunand, D.C., and Seidman, D.N.: Effects of titanium substitutions for aluminum and tungsten in Co-10Ni-9Al-9W (at.%) superalloys. Mater. Sci. Eng. A 122, 705 (2017).Google Scholar
Bocchini, P.J., Sudbrack, C.K., Sauza, D.J., Noebe, R.D., Seidman, D.N., and Dunand, D.C.: Effect of tungsten concentration on microstructures of Co-10Ni-6Al-(0, 2, 4, 6) W-6Ti (at.%) cobalt-based superalloys. Mater. Sci. Eng. A 481, 700 (2017).Google Scholar
Makineni, S.K., Nithin, B., and Chattopadhyay, K.: A new tungsten-free γ-γ′ Co-Al-Mo-Nb-based superalloy. Scr. Mater. 36, 98 (2015).Google Scholar
Ruan, J.J., Wang, C.P., and Zhao, C.C.: Experimental investigation of phase equilibria and microstructure in the Co-Ti-V ternary system. Intermetallics 121, 49 (2014).Google Scholar
Zenk, C.H., Povstugar, I., Li, R., Rinaldi, F., Neumeier, S., Raabe, D., and Göken, M.: A novel type of Co-Ti-Cr-based γ/γ′ superalloys with low mass density. Acta Mater. 244, 135 (2017).Google Scholar
Ruan, J.J., Liu, X.J., and Yang, S.Y.: Novel Co-Ti-V-base superalloys reinforced by L12-ordered γ′ phase. Intermetallics 126, 92 (2018).Google Scholar
Carroll, L.J., Feng, Q., Mansfield, J.F., and Pollock, T.M.: High refractory, low misfit Ru-containing single-crystal superalloys. Metall. Mater. Trans. A 2927, 37 (2006).Google Scholar
Carroll, L.J., Feng, Q., Mansfield, J.F., and Pollock, T.M.: Elemental partitioning in Ru-containing nickel-base single crystal superalloys. Mater. Sci. Eng. A 292, 457 (2007).Google Scholar
Tin, S., Yeh, A.C., Ofori, A.P., Reed, R.C., Babu, S.S., and Miller, M.K.: Atomic partitioning of Ruthenium in Ni-based superalloys. In Superalloys 2004, K.A. Green, T.M. Pollock, H. Harada, T.E. Howson, R.C. Reed, J.J. Schirra, and S. Walston eds. (Proceedings of the Tenth International Symposium on Superalloys, Champion, PA, 2004); p. 735.CrossRefGoogle Scholar
Zhou, Y., Mao, Z.G., Morrison, C.B., and Seidman, D.N.: The partitioning and site preference of rhenium or ruthenium in model nickel-based superalloys: An atom-probe tomographic and first-principles study. Appl. Phys. Lett. 171905, 93 (2008).Google Scholar
Sauza, D.J., Bocchini, P.J., Dunand, D.C., and Seidman, D.N.: Influence of ruthenium on microstructural evolution in a model Co-Al-W superalloy. Acta Mater. 135, 117 (2016).Google Scholar
Chen, M. and Wang, C-Y.: First-principles study of the partitioning and site preference of Re or Ru in Co-based superalloys with interface. Phys. Lett. A 3238, 374 (2010).Google Scholar
Mughrabi, H.: The importance of sign and magnitude of γ/γ′ lattice misfit in superalloys — With special reference to the new γ′-hardened cobalt-base superalloys. Acta Mater. 21, 81 (2014).Google Scholar
Chen, M. and Wang, C-Y.: First-principles investigation of the site preference and alloying effect of Mo, Ta and platinum group metals in γ′ -Co3(Al,W). Scr. Mater. 659, 60 (2009).Google Scholar
Du, Y.L., Niu, J.P., Wang, G.X., Liu, J.L., Liu, J.D., Zhou, Y.Z., Jin, T., and Sun, X.F.: Effect of Ru on the microstructure of Ni-based single-crystal superalloys. Rare Metal Mater. Eng. 1248, 47 (2018) (in Chinese).Google Scholar
Zhang, J.X., Harada, H., Koizumi, Y., and Kobayashi, T.: Dislocation motion in the early stages of high-temperature low-stress creep in a single-crystal superalloy with a small lattice misfit. J. Mater. Sci. 523, 45 (2010).Google Scholar
Chen, J.Y., Zhao, B., Feng, Q., Cao, L.M., and Sun, Z.Q.: Effect of Ru and Cr on γ/γ′ microstructural evolution of Ni-based single-crystal superalloys during heat treatment. Acta Metall. Sin. 897, 46 (2010).Google Scholar
Wang, M.G., Tian, S.G., and Yu, X.F.: Effects of Re and temperature on lattice constants and misfit of single crystal nickel-based alloys. Rare Metal Mater. Eng. 268, 39 (2010).Google Scholar
Mughrabi, H.: The importance of sign and magnitude of γ/γ′ lattice misfit in superalloys-with special reference to the new γ′-hardened cobalt-base superalloys. Acta Mater. 21, 81 (2014).Google Scholar
Viatour, P., Drapier, J.M., and Coutsouradis, D.: Stability of the gamma prime Co3Ti compound in simple and complex Co alloys. Cobalt 3, 67 (1973).Google Scholar
Titus, M., Suzuki, A., and Pollock, T.: Creep and directional coarsening in single crystals of new γ/γ′ cobalt-base alloys. Scr. Mater. 574, 66 (2012).Google Scholar
Rogister, C., Coutsouradis, D., and Habraken, L.: Improvement of heat-resisting cobalt-base alloys by precipitation hardening. Cobalt 3, 34 (1967).Google Scholar
Yeh, A.C.: Effects of Ru and Re additions on the high temperature flow stresses of Ni-base single crystal superalloys. Scr. Mater. 519, 52 (2005).Google Scholar
Jahangiri, M.R., Boutorabi, S.M.A., and Arabi, H.: Study on incipient melting in cast Ni base IN939 superalloy during solution annealing and its effect on hot workability. Mater. Sci. Technol. 1402, 28 (2012).Google Scholar