Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-29T12:30:39.814Z Has data issue: false hasContentIssue false
  • English
  • Français

Role of submicron residual fillers in improving optical reflectance of barrier rib glasses for plasma display panels

Published online by Cambridge University Press:  01 July 2006

Hyunho Shin ,
Sang-Gon Kim ,
Jong-Sung Park ,
Hyun Suk Jung ,
Kug Sun Hong  and
Hyungsun Kim
Hyunho Shin
Affiliation:
Department of Ceramic Engineering, Kangnung National University, Kangnung 210-702, Republic of Korea
Sang-Gon Kim
Affiliation:
School of Materials Science and Engineering, Seoul National University, Seoul 151-744, Republic of Korea
Jong-Sung Park
Affiliation:
School of Materials Science and Engineering, Seoul National University, Seoul 151-744, Republic of Korea
Hyun Suk Jung
Affiliation:
School of Materials Science and Engineering, Seoul National University, Seoul 151-744, Republic of Korea
Kug Sun Hong*
Affiliation:
School of Materials Science and Engineering, Seoul National University, Seoul 151-744, Republic of Korea
Hyungsun Kim
Affiliation:
School of Materials Engineering, Inha University, Incheon 402-751, Republic of Korea
*
a) Address all correspondence to this author. e-mail: kshongss@plaza.snu.ac.kr
Get access

Abstract

The improvement of optical reflectance of BaO–ZnO–B2O3–SiO2 (BZBS) glass by the addition of various types of micron-scale crystalline fillers (TiO2, SiO2, ZrO2, Al2O3, MgO, and cordierite) was investigated for application of the materials to barrier ribs of plasma display panels. The fillers were partially dissolved during sintering, yielding an increased local volume of the fillers in the submicron range, filler rearrangement along boundaries of sintered glass frits, and rather irregular and rugged filler shapes differing from the original morphologies. The measured optical reflectance of the various filler added specimens was within the 30–70% range, which was much higher than the predicted values (less than 10%) based on the rule of mixture of the refractive index. Here we report that the high reflectance of the barrier rib glass for plasma display panels is explained by light scattering by the increased submicron portion of the partially dissolved residual fillers, the size of which is similar to the visual spectrum range (0.4–0.7 μm). The order of reflectance improvement among different types of filler-embedded specimens was consistent with that of the degree of dispersion of the residual fillers in the glass matrix.

Keywords

Grain boundariesOptical propertiesSi
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 7 , July 2006 , pp. 1753 - 1758
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Hwang, G.H., Jeon, H.J., Kim, Y.S.: Physical properties of barrier ribs of plasma display panels: I. Formation of pores during sintering of lead borosilicate glass frits. J. Am. Ceram. Soc. 85, 2961 (2002).CrossRefGoogle Scholar
2.Fukushima, N., Oshita, H., and Mito, T.: Dielectric composition useful for light transparent layer in PDP. U.S. Patent No. 6 417 123 B1 (2002).Google Scholar
3.Mattox, D.M., Robinson, J.H.: Chemical durability of lead-oxide-based, thick-film binder glasses. J. Am. Ceram. Soc. 80, 1189 (1997).CrossRefGoogle Scholar
4.Jean, J-H., Lin, S-C., Yang, S-L.: Effect of alumina on crystallization of low-dielectric lead borosilicate glass. Jpn. J. Appl. Phys. 34, L422 (1995).CrossRefGoogle Scholar
5.Hwang, G-H., Kim, W-Y., Jeon, H-J., Kim, Y-S.: Physical properties of barrier ribs of plasma display panels: II. Effects of fillers. J. Am. Ceram. Soc. 85, 2961 (2002).CrossRefGoogle Scholar
6.Mito, T., Oshita, H., Ouji, M., and Hadano, K.: Composition containing lead-oxide free glass powder of low softening point useful for barrier rib in PDP. U.S. Patent No. 6 589 894 B1 (2003).Google Scholar
7.Kim, D-N., Lee, J-Y., Huh, J-S., Kim, H-S.: Thermal and electrical properties of BaO–B2O3–ZnO glasses. J. Non-Cryst. Solids 306, 70 (2002).CrossRefGoogle Scholar
8.Kim, S-G., Shin, H., Park, J-S., Hong, K.S., Kim, H.: Effect of SiO2 addition to BaO–ZnO–B2O3 glass on dielectric and thermal properties for application to barrier ribs of plasma display panels. J. Electroceram. 15, 129 (2005).CrossRefGoogle Scholar
9.Cullity, B.D.Elements of X-ray Diffraction, 2nd ed. (Addison-Wiley, New York, 1978), p. 407.Google Scholar
10.Scholze, H., Lakin, M.: Glass: Nature, Structure, and Properties (Springer, New York, 1991), p. 214.CrossRefGoogle Scholar
11.Kingery, W.D., Bowen, H.K., Uhlmann, D.R.: Introduction to Ceramics (John-Wiley and Sons, New York, 1976), p. 670.Google Scholar