Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-14T18:15:18.700Z Has data issue: false hasContentIssue false
  • English
  • Français

Shape-controlled synthesis for silver: Triangular/hexagonal nanoplates, chain-like nanoplate assemblies, and nanobelts

Published online by Cambridge University Press:  31 January 2011

Xin He ,
Xiujian Zhao ,
Yuanzhi Li  and
Xiaotao Sui
Xin He*
Affiliation:
Key Laboratory of Silicate Materials Science and Engineering, Wuhan University of Technology, Ministry of Education, Hongshan District, Wuhan, Hubei 430070, People’s Republic of China; and Functional Materials Institute, Wuyi University, Jiangmen, Guangdong 529020, People’s Republic of China
Xiujian Zhao*
Affiliation:
Key Laboratory of Silicate Materials Science and Engineering, Wuhan University of Technology, Ministry of Education, Hongshan District, Wuhan, Hubei 430070, People’s Republic of China; and Functional Materials Institute, Wuyi University, Jiangmen, Guangdong 529020, People’s Republic of China
Xiaotao Sui
Affiliation:
Key Laboratory of Silicate Materials Science and Engineering, Wuhan University of Technology, Ministry of Education, Hongshan District, Wuhan, Hubei 430070, People’s Republic of China
*
a) e-mail: hexin1981@126.com
b) e-mail: zhaoxj@public.wh.hb.cn
Get access

Abstract

Individual triangular/hexagonal nanoplates, chain-like nanoplate assemblies, and nanobelts in the case of silver were selectively synthesized using N,N-dimethylformamide (DMF) in the presence of poly (vinyl pyrrolidone) (PVP). The molar ratio of AgNO3/PVP, concentration of AgNO3, temperature, and process time were crucial factors in determining the morphologies of the final products. Based on the experimental results, it was concluded that the products were favorable to form individual nanoplates because of the strong interaction between PVP and Ag+, and the outline of the nanoplates was controlled by the ratio of AgNO3 and PVP. The formation of novel chain-like nanoplate assemblies could be explained by the secondary growth of the nanocrystals. If the reaction continuously lasted for another 7 h, the chain-like assemblies could transform into nanobelts with width of 40∼100 nm and the length of several micrometers.

Keywords

AgCrystal growthMorphology
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 7 , July 2009 , pp. 2200 - 2209
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1Esumi, K., Hosoyo, T., Suzuki, A., and Torigoe, K.: Spontaneous formation of gold nanoparticles in aqueous solution of sugarpersubstituted poly(amidoamine)dendrimers. Langmuir 16, 2978 (2000).CrossRefGoogle Scholar
2El-Sayed, M.A.: Some interesting properties of metals confined in time and nanometer space of different shapes. Acc. Chem. Res. 34, 257 (2001).CrossRefGoogle ScholarPubMed
3Eychmuller, A.: Structure and photophysics of semiconductor nanocrystals. J. Phys. Chem. B 104, 6514 (2001).CrossRefGoogle Scholar
4Wu, H.P., Liu, J.F., Wu, X.J., Ge, M.Y., Wang, Y.W., Zhang, G.Q., and Jiang, J.Z.: High conductivity of isotropic conductive adhesives filled with silver nanowires. Int. J. Adhes. Adhes. 26, 617 (2006).CrossRefGoogle Scholar
5Lyu, S.C., Zhang, Y., Lee, C.J., Ruh, H., and Lee, H.J.: Low-temperature growth of ZnO nanowire array by a simple physical vapor-deposition method. Chem. Mater. 15, 3294 (2003).CrossRefGoogle Scholar
6Kong, X.Y., Ding, Y., and Wang, Z.L.: Metal-semiconductor Zn-ZnO core-shell nanobelts and nanotubes. J. Phys. Chem. B 108, 570 (2004).CrossRefGoogle Scholar
7Murphy, C.J., Gole, A.M., Hunyadi, S.E., and Orendorff, C.J.: Onedimensional colloidal gold and silver nanostructures. Inorg. Chem. 45, 7544 (2006).Google Scholar
8Lu, Q.Y., Gao, F., and Komarneni, S.: Cellulose-directed growth of selenium nanobelts in solution. Chem. Mater. 18, 159 (2006).CrossRefGoogle Scholar
9Washio, I., Xiong, Y.J., Yin, Y.D., and Xia, Y.N.: Reduction by the end groups of poly(vinyl pyrrolidone): A new and versatile route to the kinetically controlled synthesis of Ag triangular nanoplates. Adv. Mater. 18, 1745 (2006).CrossRefGoogle Scholar
10Mulvaney, P.: Surface plasmon spectroscopy of nanosized metal particles. Langmuir 12, 788 (1996).CrossRefGoogle Scholar
11Callegari, A., Tonti, D., and Chergui, M.: Photochemically grown silver nanoparticles with wavelength-controlled size and shape. Nano Lett. 3, 1565 (2003).CrossRefGoogle Scholar
12Sosa, I.O., Noguez, C., and Barrera, R.G.: Optical properties of metal nanoparticles with arbitrary shapes. J. Phys. Chem. B 107, 6269 (2003).CrossRefGoogle Scholar
13Tsuji, M., Hashimoto, M., Nishizawa, Y., and Tsuji, T.: Synthesis of gold nanorods and nanowires by a microwave–polyol method. Mater. Lett. 58, 2326 (2004).CrossRefGoogle Scholar
14Lee, G.J., Shin, S.I., Kim, Y.C., and Oh, S.G.: Preparation of silver nanorods through the control of temperature and pH of reaction medium. Mater. Chem. Phys. 84, 197 (2004).CrossRefGoogle Scholar
15Burda, C., Chen, X.B., Narayanan, R., and El-Sayed, M.A.: Chemistry and properties of nanocrystals of different shapes. Chem. Rev. 105, 1025 (2005).CrossRefGoogle ScholarPubMed
16Aslan, K., Leonenko, Z., Lakowicz, J.R., and Geddes, C.D.: Fast and slow deposition of silver nanorods on planar surfaces: Application to metal-enhanced fluorescence. J. Phys. Chem. B 109, 3157 (2005).CrossRefGoogle ScholarPubMed
17Yang, Y., Matsubara, S., Xiong, L.M., Hayakawa, T., and Nogami, M.: Solvothermal synthesis of multiple shapes of silver nanoparticles and their SERS properties. J. Phys. Chem. C 111, 9095 (2007).Google Scholar
18Zhang, Y. and Dai, H.J.: Formation of metal nanowires on suspended single-walled carbon nanotubes. Appl. Phys. Lett. 77, 3015 (2000).CrossRefGoogle Scholar
19Hong, B.H., Bae, S.C., Lee, C.W., Jeong, S., and Kim, K.S.: Ultrathin single-crystalline silver nanowire arrays formed in an ambient solution phase. Science 294, 348 (2001).CrossRefGoogle Scholar
20Mbindyo, J.K.N., Mallouk, T.E., Mattzela, J.B., Kratochvilova, I., Razavi, B., Jackson, T.N., and Mayer, T.S.: Template synthesis of metal nanowires containing monolayer molecular junctions. J. Am. Chem. Soc. 124, 4020 (2002).Google Scholar
21Sauer, G., Brehm, G., Schneider, S., Nielsch, K., Wehrspohn, R.B., Choi, J., Hofrneister, H., and Gösele, U.: Highly ordered monocrystalline silver nanowire arrays. J. Appl. Phys. 91, 3243 (2002).CrossRefGoogle Scholar
22Wei, G., Zhou, H.L., Liu, Z.G., Song, Y.H., Wang, L., Sun, L.L., and Li, Z.: One-step synthesis of silver nanoparticles, nanorods, and nanowires on the surface of DNA network. J. Phys. Chem. B 109, 8738 (2005).Google Scholar
23Sun, Y.G. and Xia, Y.N.: Large-scale synthesis of uniform silver nanowires through a soft, self-seeding, polyol process. Adv. Mater. 14, 833 (2002).3.0.CO;2-K>CrossRefGoogle Scholar
24He, X., Zhao, X.J., Chen, Y.X., Feng, J.Y., and Sun, Z.Y.: Synthesis and characterization of silver nanowires with zigzag morphology in N,N-dimethylformamide. J. Solid State Chem. 180, 2262 (2007).CrossRefGoogle Scholar
25Wei, G.D., Nan, C.W., and Yu, D.P.: Large-scale self-assembled Ag nanotubes. Tsinghua Sci. Technol. 10, 736 (2005).CrossRefGoogle Scholar
26Wiley, B.J., Sun, Y.G., Mayers, B., and Xia, Y.N.: Shape-controlled synthesis of metal nanostructures: The case of silver. Chem. Eur. J. 11, 454 (2005).Google Scholar
27Chen, J.Y., Wiley, B.J., and Xia, Y.N.: One-dimensional nanostructures of metals: Large-scale synthesis and some potential applications. Langmuir 23, 4120 (2007).Google Scholar
28Chen, S.H., Fan, Z.Y., and Carroll, D.L.: Silver nanodisks: Synthesis, characterization, and self-assembly. J. Phys. Chem. B 106, 10777 (2002).CrossRefGoogle Scholar
29Maillard, M., Giorgio, S., and Pileni, M.P.: Silver nanodisks. Adv. Mater. 14, 1084 (2002).3.0.CO;2-L>CrossRefGoogle Scholar
30Gao, Y., Jiang, P., Song, L., Wang, J.X., Liu, L.F., Liu, D.F., Xiang, Y.J., Zhang, Z.X., Zhao, X.W., Dou, X.Y., Luo, S.D., Zhou, W.Y., and Xie, S.S.: Studies on silver nanodecahedrons synthesized by PVP-assisted N,N-dimethylformamide (DMF) reduction. J. Cryst. Growth 289, 376 (2006).CrossRefGoogle Scholar
31Du, J.M., Han, B.X., Liu, Z.M., Liu, Y.Q., and Kang, D.J.: Control synthesis of silver nanosheets, chainlike sheets, and microwires via a simple solvent-thermal method. Cryst. Growth Des. 7, 900 (2007).CrossRefGoogle Scholar
32Yang, J.H., Lu, L.H., Wang, H.S., Shi, W.D., and Zhang, H.J.: Glycyl glycine templating synthesis of single-crystal silver nanoplates. Cryst. Growth Des. 6, 2155 (2006).CrossRefGoogle Scholar
33Jiang, X.C., Zeng, Q.H., and Yu, A.: Thiol-frozen shape evolution of triangular silver nanoplates. Langmuir 23, 2218 (2007).Google Scholar
34Germain, V., Li, J., Ingert, D., Wang, Z.L., and Pileni, M.P.: Stacking faults in formation of silver nanodisks. J. Phys. Chem. B 107, 8717 (2003).CrossRefGoogle Scholar
35Sun, Y.G., Yin, Y.D., Mayers, B.T., Herricks, T., and Xia, Y.N.: Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone). Chem. Mater. 14, 4736 (2002).Google Scholar
36Zou, K., Zhang, X.H., Duan, X.F., Meng, X.M., and Wu, S.K.: Seedmediated synthesis of silver nanostructures and polymer/silver nanocables by UV irradiation. J. Cryst. Growth 273, 285 (2004).Google Scholar
37Sun, Y.G., Gates, B., Mayers, B., and Xia, Y.N.: Crystalline silver nanowires by soft solution processing. Nano Lett. 2, 165 (2002).Google Scholar
38Wiley, B.J., Im, S.H., Li, Z.Y., Mclellan, J., Siekkinen, A., and Xia, Y.N.: Maneuvering the surface plasmon resonance of silver nanostructures through shape-controlled synthesis. J. Phys. Chem. B 110, 15666 (2006).Google Scholar
39Jiang, P., Li, S.Y., Xie, S.S., Gao, Y., and Song, L.: Machinable long PVP-stabilized silver nanowires. Chem. Eur. J. 10, 4817 (2004).CrossRefGoogle ScholarPubMed
40Zhao, Q.T., Qiu, J.R., Zhao, C.J., Hou, L.S., and Zhu, C.S.: Synthesis and formation mechanism of silver nanowires by a templateless and seedless method. Chem. Lett. (Jpn.) 34, 30 (2005).Google Scholar
41Pan, Z.W., Dai, Z.R., and Wang, Z.L.: Nanobelts of semiconducting oxides. Science 291, 1947 (2001).CrossRefGoogle ScholarPubMed