Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-28T15:53:37.307Z Has data issue: false hasContentIssue false

Sol-gel coatings to improve processing of aluminium matrix SiC reinforced composite materials

Published online by Cambridge University Press:  03 March 2011

J. Rams
Affiliation:
Department Tecnología Química, Ambiental y de los Materiales, ESCET, Universidad Rey Juan Carlos, C/ Tulipán s/n, Móstoles 28933 Madrid, Spain
M. Campo
Affiliation:
Department Tecnología Química, Ambiental y de los Materiales, ESCET, Universidad Rey Juan Carlos, C/ Tulipán s/n, Móstoles 28933 Madrid, Spain
A. Ureña
Affiliation:
Department Tecnología Química, Ambiental y de los Materiales, ESCET, Universidad Rey Juan Carlos, C/ Tulipán s/n, Móstoles 28933 Madrid, Spain
Get access

Abstract

This paper analyses the influence of the inner structure of a SiO2 coating deposited on SiC particles by a sol-gel route on reactivity and wettability between SiC particles and molten aluminium during composite manufacturing. Different heat treatments were applied to the sol-gel coatings to change the porous structure of the amorphous silica. The coatings subjected to the mildest heat treatment were more reactive with molten aluminium, enriching the Si content of the matrix composite, and hence inhibiting direct reaction of the SiC particles and the formation of aluminium carbide. Thermal analysis showed that Si enrichment altered the solidification behavior of the aluminium matrix and its resultant microstructure, influencing the manufacturing conditions and final properties of the fabricated composites.

Type
Articles
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Viala, J.C., Fortier, P. and Bouix, J.Stable and metastable phase equilibria in the chemical interaction between aluminium and silicon carbide. J. Mater. Sci. 25, 1842 (1990).CrossRefGoogle Scholar
2.Rajan, T.P.D., Pillai, R.M. and Pai, B.C.Review Reinforcement coatings and interfaces in aluminium metal matrix composites. J. Mater. Sci. 33, 3491 (1998).CrossRefGoogle Scholar
3.Suéry, M., L’Espérance, G., Hong, B.D., Thanh, L. Nguyen and Bordeaux, F.Development of particulate treatments and coatings to reduce SiC degradation by liquid aluminium. J. Mater. Eng. Perf. 2, 365 (1993).CrossRefGoogle Scholar
4.Kindl, B., Teng, Y.H. and Liu, Y.L.Protective coatings for commercial particulates. Composites 25, 671 (1994).CrossRefGoogle Scholar
5.Shi, J.M. Zhongliang, Yang, J.C., Lee, D.Z., Lee, H.I. and Wu, R.: The interfacial characterization of oxidized SiCp/2014 Al composites. Mater. Sci. Eng. A 303, 46 (2001).CrossRefGoogle Scholar
6.Ureña, A., Rodrigo, P., Gil, L., Escalera, M.D. and Baldonedo, J.L.Interfacial reaction in an Al–Cu–Mg 2009/SiCw composite during liquid processing. Part I. Casting. J. Mater. Sci. 36, 419 (2001).CrossRefGoogle Scholar
7.Ureña, A., Escalera, M.D., Rodrigo, P., Baldonedo, J.L. and Gil, L.Active coatings for SiC particles to reduce the degradation by liquid aluminium during processing of aluminium matrix composites: Study of interfacial reactions. J. Microsc. 201, 1 (2001).CrossRefGoogle ScholarPubMed
8.Rams, J., Campo, M. and Ureña, A. Sol-Gel Coatings as active barriers to protect ceramic reinforcement in aluminium matrix composites. Adv. Eng. Mater. 6, 57 (2004).CrossRefGoogle Scholar
9.Massalski, T.B. and Murray, J.L.: Binary Alloy Phase Diagrams, edited by Bennett, L.H. and Baker, H. (American Society for Metals Park, Metals Park, Ohio, 1986), p. 165.Google Scholar
10.Hughes, A.E., Hedges, M.M. and Sexton, B.A.Reactions at the Al/SiO2/SiC layered interface. J. Mater. Sci. 25, 4856 (1990).CrossRefGoogle Scholar
11.Luo, Z.P., Song, Y.G. and Zhang, S.Q.A TEM study of the microstructure of SiCp/Al composite prepared by pressureless infiltration method. Scripta Mater. 45, 1183 (2001).CrossRefGoogle Scholar
12.Laurent, V., Chatain, D. and Eustathopoulous, N.Wettability of SiO2 and oxidized SiC by aluminium. Mater. Sci. Eng. A 135, 89 (1987).CrossRefGoogle Scholar
13.Aksay, I., Hoye, C. and Pask, J.Wetting under chemical-equilibrium and nonequilibrium conditions. J. Phys. Chem. 78, 1178 (1974).CrossRefGoogle Scholar
14.Isaikin, A.S., Chubarov, V.M., Tretilov, B.F., Silaer, V.A. and Goselor, Y.A.Compatibility of carbon filaments with a carbide coating and an aluminium matrix. Mater. Sci. Heat Treat. 22, 815 (1980).CrossRefGoogle Scholar
15.Ureña, A., Escalera, M.D. and Gil, L.Oxidation barriers on SiC particles for use in aluminium matrix composites manufactured by casting route: Mechanisms of interfacial protection. J. Mater. Sci. 37, 4633 (2002).CrossRefGoogle Scholar