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Solvothermal synthesis of manganese sulfides and control of their phase and morphology

Published online by Cambridge University Press:  12 November 2018

Jianchao Zhang ,
Rongrong Shi Open the ORCID record for Rongrong Shi [Opens in a new window] ,
Chen Zhang ,
Lingyun Li ,
Jiaming Mei  and
Shengqing Liu
Jianchao Zhang
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Rongrong Shi*
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Chen Zhang
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Lingyun Li
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Jiaming Mei
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Shengqing Liu
Affiliation:
Institute of Materials Science and Engineering, School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, State and Local Joint Engineering Laboratory of Light-conversion Materials and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: shirr@lzu.edu.cn
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Abstract

Manganese sulfides (MnS) with a diversity of well-defined morphologies and phases have been successfully synthesized by the solvothermal approach. The phase structure and morphology of MnS could readily be tuned by adjusting the sulfur sources and solvents. Hollow γ-MnS spheres were obtained by treating L-cysteine and manganese source in ethylene glycol (EG) at 200 °C for 2 h, whereas a replacement of the mixture solvent by EG and deionized water yields the hierarchical flower-like γ-MnS. γ-MnS tubes were also produced under the same condition by using diethylene glycol and deionized water as solvents. When thioacetamide used as the sulfur source and oleylamine used as the solvent, monodisperse α-MnS nanoparticles with the mean diameter of 17 nm could be synthesized successfully. The phase structures, sizes, and morphologies of samples were investigated in detail by powder X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The UV-vis absorption peak and the width of band gap with different morphologies of the as-prepared MnS were measured. The samples described in this paper are promising to be utilized in solar cells, biomedicine, short wavelength electronic devices, photocatalysis, and other fields.

Keywords

band gaphollow structuremonodisperseMnSsolution polarity
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 24 , 28 December 2018 , pp. 4224 - 4232
Copyright
Copyright © Materials Research Society 2018 

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References

REFERENCES

Joshi, H.M., Lin, Y.P., Aslam, M., Prasad, P.V., Schultz-Sikma, E.A., Edelman, R., Meade, T., and Dravid, V.P.: Effects of shape and size of cobalt ferrite nanostructures on their MRI contrast and thermal activation. J. Phys. Chem. C 113, 17761 (2009).CrossRefGoogle ScholarPubMed
Xu, D., Shi, W., Xu, C., Yang, S., Bai, H., Song, C., and Chen, B.: Hydrothermal synthesis of 3D Ba5Ta4O15 flower-like microsphere photocatalyst with high photocatalytic properties. J. Mater. Res. 31, 2640 (2016).CrossRefGoogle Scholar
Shen, Z., Zhao, Z., Qian, J., Peng, Z., and Fu, X.: Synthesis of WO3−x nanomaterials with controlled morphology and composition for highly efficient photocatalysis. J. Mater. Res. 31, 1065 (2016).CrossRefGoogle Scholar
Algra, R.E., Hocevar, M., Verheijen, M.A., Zardo, I., Immink, G.G., van Enckevort, W.J., Abstreiter, G., Kouwenhoven, L.P., Vlieg, E., and Bakkers, E.P.: Crystal structure transfer in core/shell nanowires. Nano Lett. 11, 1690 (2011).CrossRefGoogle ScholarPubMed
Li, Y. and Shi, J.: Hollow-structured mesoporous materials: Chemical synthesis, functionalization and applications. Adv. Mater. 26, 3176 (2014).CrossRefGoogle ScholarPubMed
Liu, L. and Chen, X.: Titanium dioxide nanomaterials: Self-structural modifications. Chem. Rev. 114, 9890 (2014).CrossRefGoogle ScholarPubMed
Zhang, Q., Wang, W., Goebl, J., and Yin, Y.: Self-templated synthesis of hollow nanostructures. Nano Today 4, 494 (2009).CrossRefGoogle Scholar
Li, X., Yu, J., and Jaroniec, M.: Hierarchical photocatalysts. Chem. Soc. Rev. 45, 2603 (2016).CrossRefGoogle ScholarPubMed
Gao, M.R., Jiang, J., and Yu, S.H.: Solution-based synthesis and design of late transition metal chalcogenide materials for oxygen reduction reaction (ORR). Small 8, 13 (2012).CrossRefGoogle Scholar
Ma, S., Deng, Y., Xie, J., and He, K.: Noble-metal-free Ni3C cocatalysts decorated CdS nanosheets for high-efficiency visible-light-driven photocatalytic H2 evolution. Appl. Catal., B 227, 218 (2018).CrossRefGoogle Scholar
Qian, J., Zhao, Z., Shen, Z., Zhang, G., and Peng, Z.: A large scale of CuS nano-networks: Catalyst-free morphologically controllable growth and their application as efficient photocatalysts. J. Mater. Res. 30, 3746 (2015).CrossRefGoogle Scholar
Lai, C.H., Lu, M.Y., and Chen, L.J.: Metal sulfide nanostructures: Synthesis, properties and applications in energy conversion and storage. J. Mater. Chem. 22, 19 (2012).CrossRefGoogle Scholar
Antunez, P.D., Buckley, J.J., and Brutchey, R.L.: Tin and germanium monochalcogenide IV–VI semiconductor nanocrystals for use in solar cells. Nanoscale 3, 2399 (2011).CrossRefGoogle ScholarPubMed
Yuan, M. and Mitzi, D.B.: Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films. Dalton Trans. 31, 6078 (2009).CrossRefGoogle Scholar
Chen, M., Ye, C., Zhou, S., and Wu, L.: Recent advances in applications and performance of inorganic hollow spheres in devices. Adv. Mater. 25, 5343 (2013).CrossRefGoogle ScholarPubMed
Mi, L., Chen, Y., Zheng, Z., Hou, H., Chen, W., and Cui, S.: Beneficial metal ion insertion into dandelion-like MnS with enhanced catalytic performance and genetic morphology. RSC Adv. 4, 19257 (2014).CrossRefGoogle Scholar
Ren, Y., Gao, L., Sun, J., Liu, Y., and Xie, X.: Facile synthesis of γ-MnS hierarchical nanostructures with high photoluminescence. Ceram. Int. 38, 875 (2012).CrossRefGoogle Scholar
Puglisi, A., Mondini, S., Cenedese, S., Ferretti, A.M., Santo, N., and Ponti, A.: Monodisperse octahedral α-MnS and MnO nanoparticles by the decomposition of manganese oleate in the presence of sulfur. Chem. Mater. 22, 2804 (2010).CrossRefGoogle Scholar
Chen, C.C., heerhold, A.B., Johnson, C.S., and Alivisatos, A.P.: Size dependence of structural metastability in semiconductor nanocrystals. Science 276, 398 (1997).CrossRefGoogle ScholarPubMed
Lei, S., Tang, K., Yang, Q., and Zheng, H.: Solvothermal synthesis of metastable γ-MnS hollow spheres and control of their phase. Eur. J. Inorg. Chem. 20, 4124 (2005).CrossRefGoogle Scholar
Yang, X., Wang, Y., Wang, K., Sui, Y., Zhang, M., Li, B., Ma, Y., Liu, B., Zou, G., and Zou, B.: Polymorphism and formation mechanism of nanobipods in manganese sulfide nanocrystals induced by temperature or pressure. J. Phys. Chem. C 116, 3292 (2012).CrossRefGoogle Scholar
Li, F., Han, T., Wang, H., and Zheng, X.: Morphology evolution and visible light driven photocatalysis study of Ti3+ self-doped TiO2−x nanocrystals. J. Mater. Res. 32, 1563 (2017).CrossRefGoogle Scholar
Zhang, J., Sun, L., Yin, J., Su, H., Liao, C., and Yan, C.: Control of ZnO morphology via a simple solution route. Chem. Mater. 14, 4172 (2002).CrossRefGoogle Scholar
Ao, Y., Gao, Y., Wang, P., Wang, C., Hou, J., and Qian, J.: Solvent-controlled preparation and photocatalytic properties of nanostructured TiO2 thin films with different morphologies. Mater. Res. Bull. 49, 223 (2014).CrossRefGoogle Scholar
Yang, H.G. and Zeng, H.C.: Preparation of hollow anatase TiO2 nanospheres via qstwald ripening. J. Phys. Chem. B 108, 3492 (2004).CrossRefGoogle Scholar
Shi, W., Song, S., and Zhang, H.: Hydrothermal synthetic strategies of inorganic semiconducting nanostructures. Chem. Soc. Rev. 42, 5714 (2013).CrossRefGoogle ScholarPubMed
Jiang, L. and Zhu, Y.J.: Cu2S nanostructures prepared by Cu-cysteine precursor templated route. Mater. Lett. 63, 1935 (2009).CrossRefGoogle Scholar
Chen, Z.X., Shen, Y.H., Xie, A.J., Zhu, J.M., Wu, Z.F., and Huang, F.Z.: L-Cysteine-assisted controlled synthesis of selenium nanospheres and nanorods. Cryst. Growth Des. 9, 1327 (2008).CrossRefGoogle Scholar
Zhang, X., Chen, Y., Jia, C., Zhou, Q., Su, Y., Peng, B., Yin, S., and Xin, M.: Two-step solvothermal synthesis of α-MnS spheres: Growth mechanism and characterization. Mater. Lett. 62, 125 (2008).CrossRefGoogle Scholar
Huang, F., Zhang, H.Z., and Banfield, J.F.: Two-stage crystal-growth kinetics observed during hydrothermal coarsening of nanocrystalline ZnS. Nano Lett. 3, 373 (2003).CrossRefGoogle Scholar
Shi, Y., Xue, F., Li, C., Zhao, Q., and Qu, Z.: Preparation and hydrothermal annealing of pure metastable β-MnS thin films by chemical bath deposition (CBD). Mater. Res. Bull. 46, 483 (2011).CrossRefGoogle Scholar
Zheng, Y.H., Cheng, Y., Wang, Y.S., Zhou, L.H., Bao, F., and Jia, C.: Metastable γ-MnS hierarchical architectures: Synthesis, characterization, and growth mechanism. J. Phys. Chem. 110, 8284 (2006).CrossRefGoogle ScholarPubMed
Mu, J., Gu, Z., Wang, L., Zhang, Z., Sun, H., and Kang, S.Z.: Phase and shape controlling of MnS nanocrystals in the solvothermal process. J. Nanopart. Res. 10, 197 (2007).CrossRefGoogle Scholar
Liu, M., Shan, N., Chen, L., Li, X., and Li, B.: A mild l-cystine-assisted hydrothermal route to metastable γ-MnS multipods. Appl. Surf. Sci. 258, 7922 (2012).CrossRefGoogle Scholar