Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-26T20:31:22.189Z Has data issue: false hasContentIssue false
  • English
  • Français

Spectroscopic properties of Sm3+-doped phosphate glasses

Published online by Cambridge University Press:  07 June 2012

Liaolin Zhang ,
Mingying Peng ,
Guoping Dong  and
Jianrong Qiu
Liaolin Zhang
Affiliation:
State Key Laboratory of Luminescent Materials and Devices and Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510640, China
Mingying Peng
Affiliation:
State Key Laboratory of Luminescent Materials and Devices and Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510640, China
Guoping Dong
Affiliation:
State Key Laboratory of Luminescent Materials and Devices and Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510640, China
Jianrong Qiu*
Affiliation:
State Key Laboratory of Luminescent Materials and Devices and Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510640, China
*
a)Address all correspondence to this author. e-mail: qjr@scut.edu.cn
Get access

Abstract

We report on the absorption, static, and transient luminescence spectra of Sm3+-doped glasses. The dependences between absorption and emission cross sections as well as between luminescence quantum efficiencies and Sm3+ doping concentration are examined. The large stimulated absorption cross section and emission cross section combined with the long fluorescent lifetime make phosphate glasses doped with Sm3+ promising material for visible fiber lasers. Moreover, ΔT(Tx − Tg) of these glasses is about 290 °C, which guarantees their thermal stability against crystallization during the fiber drawing process.

Keywords

phosphate glassluminescenceSm3+ ions
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 16 , 28 August 2012 , pp. 2111 - 2115
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Okamoto, H., Kasuga, K., Hara, I., and Kubota, Y.: Visible-NIR tunable Pr3+-doped fiber laser pumped by a GaN laser diode. Opt. Express 17, 20227 (2009).CrossRefGoogle ScholarPubMed
2.Fujimoto, Y., Ishii, O., and Yamazaki, M.: Multi-colour laser oscillation in Pr3+-doped fluoro-aluminate glass fibre pumped by 442.6 nm GaN-semiconductor laser. Electron. Lett. 45, 1301 (2009).CrossRefGoogle Scholar
3.Fujimoto, Y., Ishii, O., and Yamazaki, M.: Yellow laser oscillation in Dy3+-doped waterproof fluoro-aluminate glass fibre pumped by 398.8 nm GaN laser diodes. Electron. Lett. 46, 1285 (2010).CrossRefGoogle Scholar
4.Yamashita, T. and Ohisi, Y.: Amplification and lasing characteristics of Tb3+-doped fluoride fiber in the 0.54 μm band. Jpn. J. Appl. Phys. 46, L991 (2007).CrossRefGoogle Scholar
5.Farries, M., Morkel, P., and Townsend, J.: Spectroscopic and lasing characteristics of samarium doped glass fibre. Electron. Lett. 24, 709 (1988).CrossRefGoogle Scholar
6.Seshadri, M., Rao, K., Rao, J., and Ratnakaram, Y.: Spectroscopic and laser properties of Sm3+ doped different phosphate glasses. J. Alloys Compd. 476, 263 (2009).CrossRefGoogle Scholar
7.Campbell, H. and Suratwala, I.: Nd-doped phosphate glasses for high-energy/high-peak-power lasers. J. Non-Cryst. Solids 263 and 264 , 318 (2000).CrossRefGoogle Scholar
8.Lin, H., Pun, E., Wang, X., and Liu, X.: Optical absorption and photoluminescence in Sm3+- and Eu3+-doped rare-earth borate glasses. J. Alloys Compd. 390, 197 (2005).CrossRefGoogle Scholar
9.Elisa, M., Vasiliu, I., Grigorescu, C., Grigoras, B., Niciu, H., Niciu, D., Meghea, A., Lfitimie, N., Giurginca, M., Trodahl, H., and Dalley, M.: Optical and structural investigation on rare-earth-doped aluminophosphate glasses. Opt. Mater. 28, 621 (2006).CrossRefGoogle Scholar
10.Pascuta, P., Borodi, G., Junate, N., Vida-Simmiti, I., Viorel, D., and Culea, E.: The structural role of manganese ions in some zinc phosphate glasses and glass ceramics. J. Alloys Compd. 504, 479 (2010).CrossRefGoogle Scholar
11.Czaja, M., Bodyl, S., Gabrys-Pisaarska, J., and Mazurak, Z.: Applications of Judd-Ofelt theory to praseodymium and samarium ions in phosphate glass. Opt. Mater. 31, 1898 (2009).CrossRefGoogle Scholar
12.Auzel, F.: Upconversion and anti-stokes processes with f and d ions in solids. Chem. Rev. 104, 139 (2004).CrossRefGoogle Scholar
13.Righini, G. and Ferrari, M.: Photoluminescence of rare-earth-doped glasses. La Rivista del Nuovo Cimento. 28, 1 (2005).Google Scholar
14.Ferrari, M.: in Handbook of Sole Gel Science and Technology, edited by Sakka, S. (Kluwer Academic Publishers, 2, Boston, MA, 2005) pp. 359–388.Google Scholar
15.McCumber, D.: Theory of phonon-terminated optical masers. Phys. Rev. 134, A299 (1964).CrossRefGoogle Scholar
16.Berneschi, S., Bettinelli, M., Brenci, M., Nunzi Conti, G., Pelli, S., Sebastiani, S., Siligardi, C., Speghini, A., and Righini, G.C.: Aluminum co-doping of soda-lime silicate glasses: Effect on optical and spectroscopic properties. J. Non-Cryst. Solids 351, 1747 (2005).CrossRefGoogle Scholar
17.Saissy, A., Azami, N., Jones, J., and Maze, G.: Properties of Sm3+ ions in fluorozirconate fiber. Appl. Opt. 36, 5931 (1997).CrossRefGoogle ScholarPubMed
18.de Mello, J., Wittmann, H., and Friend, R.: An improved experimental determination of external photoluminescence quantum efficiency. Adv. Mater. 9, 230 (1997).CrossRefGoogle Scholar
19.Liu, W., Chiu, Y., Tung, C., Jang, S., and Chen, T.: A study on the luminescence properties of CaAlBO4:RE3+(RE = Ce, Tb, and Eu) phosphors. J. Electrochem. Soc. 155, J252 (2008).CrossRefGoogle Scholar