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Sr(Zn1/3Nb2/3)O3-induced R3c to P4bm transition and large field-induced strain in 0.80(Bi0.5Na0.5)TiO3–0.20SrTiO3 ceramics

Published online by Cambridge University Press:  15 April 2019

Qiumei Wei ,
Mankang Zhu ,
Mupeng Zheng  and
Yudong Hou
Qiumei Wei
Affiliation:
Key Laboratory of Advanced Functional Materials, Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Mankang Zhu*
Affiliation:
Key Laboratory of Advanced Functional Materials, Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Mupeng Zheng
Affiliation:
Key Laboratory of Advanced Functional Materials, Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Yudong Hou*
Affiliation:
Key Laboratory of Advanced Functional Materials, Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
*
a)Address all correspondence to these authors. e-mail: zhumk@bjut.edu.cn
b)e-mail: ydhou@bjut.edu.cn
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Abstract

Bi0.5Na0.5TiO3 (BNT)-based lead-free materials are important for piezoelectric actuator, and several researchers have studied the effect of B-site complex ion doping on strain in (Bi0.5Na0.5)TiO3–SrTiO3. In this work, a paraelectric perovskite Sr(Zn1/3Nb2/3)O3 (SZN) with B-site complex structure was introduced into 0.80(Bi0.5Na0.5)TiO3–0.20SrTiO3 (BNTST) to investigate the phase structure and electrical properties as well as the field-induced strain behavior. The results showed that SZN substitution decreases the rhombohedrality 90-γ and induces the transition from dominant ferroelectric to nonergodic relaxor by shifting its TF-R to lower temperatures. Moreover, the field-induced ferroelectric domains cannot remain stable at room temperature when SZN substitution is large than 1.0 mol%. These behaviors induced the transition between nonergodic relaxor and ergodic relaxor, which contributed to its large strain and related properties. In this work, this material gave the largest bipolar strain of 0.43% and large normalized unipolar strain of 505 pm/V at the SZN content of 2 mol% under 8 kV/mm, and showed good temperature stability up to 100 °C. The above encouraging results may be helpful for further investigation of BNTST-based ternary systems in search of a potential Pb-free piezoelectric material.

Keywords

ferroelectricity/ferroelectric materialselectroceramicselectrical propertiesdomains
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 7: Focus Section: Interconnects and Interfaces in Energy Conversion Materials , 15 April 2019 , pp. 1210 - 1218
Copyright
Copyright © Materials Research Society 2019 

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