Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-27T13:39:17.634Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and characterization of highly organized crystalline rutile nanoparticles by low-temperature dissolution-reprecipitation process

Published online by Cambridge University Press:  08 June 2015

Mohammad Rezaul Karim ,
Mohammad Tauhidul Islam Bhuiyan ,
Mushtaq Ahmad Dar ,
Asiful Hossain Seikh ,
Muhammad Ali Shar ,
Mohammed Badruz Zaman ,
Chul Jae Lee ,
Hee Jin Kim  and
Mu Sang Lee
Mohammad Rezaul Karim*
Affiliation:
Center of Excellence for Research in Engineering Materials, Advanced Manufacturing Institutes, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Mohammad Tauhidul Islam Bhuiyan
Affiliation:
Faculty of Engineering, Particle Technology Research Centre, University of Western Ontario, London, Ontario N6A5B8, Canada
Mushtaq Ahmad Dar
Affiliation:
Center of Excellence for Research in Engineering Materials, Advanced Manufacturing Institutes, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Asiful Hossain Seikh
Affiliation:
Center of Excellence for Research in Engineering Materials, Advanced Manufacturing Institutes, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Muhammad Ali Shar
Affiliation:
Center of Excellence for Research in Engineering Materials, Advanced Manufacturing Institutes, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Mohammed Badruz Zaman
Affiliation:
AB-Biotech Inc., National Research Council of Canada, Ottawa, Ontario K1A 0R6, Canada; and Center of Excellence for Research in Engineering Materials, Advanced Manufacturing Institutes, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Chul Jae Lee
Affiliation:
School of Chemical Industry, Yeungnam College of Science and Technology, 170 Hyeonchung-ro, Nam-gu, Daegu 705-703, Republic of Korea
Hee Jin Kim
Affiliation:
Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang, Gyungbuk 790-784, Republic of Korea
Mu Sang Lee
Affiliation:
Department of Chemistry, Kyungpook National University, Daegu 702-701, Republic of Korea
*
a)Address all correspondence to this author. e-mail: mkarim@ksu.edu.sa
Get access

Abstract

Rutile nanoparticles have been synthesized by acid hydrolysis of titanium isopropoxide by low-temperature dissolution-reprecipitation process. High-resolution transmission electron micrographs of the rutile colloidal solution show needle-shaped rutile nanoparticles with the dimensions of 10–30 nm in diameter and 100–150 nm in length. X-ray diffraction (XRD) data show the existence of only the rutile polymorph in TiO2 powder with a crystallite size of 11.3 nm. The dielectric constant of rutile nanoparticles has been found to be 57 at 10 MHz AC frequency and DC conductance as 2.3 × 10−6 S/cm. Transmission electron micrographs and XRD data analysis imply that the rutile crystallites are self-organized in a regular fashion to produce multilayer three-dimensional linear clusters. The clusters have been found to be microporous (average porosity 1.4 nm) with high specific surface area (132.2 m2/g). At higher concentration, the clusters aggregate to produce interconnected network of star- or flower-like structures. This organized crystalline microporous metal-oxide semiconductor might find various practical applications.

Keywords

nanostructureschemical synthesisdielectric propertiessemiconductorshighly organized rutile TiO2
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 12 , 28 June 2015 , pp. 1887 - 1893
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Senna, M., Myers, N., Aimable, A., Laporte, V., Pulgarin, C., Baghriche, O., and Bowen, P.: Modification of titania nanoparticles for photocatalytic antibacterial activity via a colloidal route with glycine and subsequent annealing. J. Mater. Res. 28, 354 (2013).Google Scholar
Wu, J.M.: Tin-doped rutile titanium dioxide nanowires: Luminescence, gas sensor, and field emission properties. J. Nanosci. Nanotechnol. 12, 1434 (2012).Google Scholar
Karim, M.R., Yeum, J.H., Lee, M.S., and Lim, K.T.: Preparation of conducting polyaniline/TiO2 composite submicron-rods by the γ-radiolysis oxidative polymerization method. React. Funct. Polym. 68, 1371 (2008).CrossRefGoogle Scholar
Xu, J., Jia, C., Cao, B., and Zhang, W.F.: Electrochemical properties of anatase TiO2 nanotubes as an anode material for lithium-ion batteries. Electrochim. Acta 52, 8044 (2007).Google Scholar
Baudrin, E., Cassaignon, S., Koelsch, M., Jolivet, J.P., Dupont, L., and Tarascon, J.M.: Structural evolution during the reaction of Li with nano-sized rutile type TiO2 at room temperature. Electrochem. Commun. 9, 337 (2007).Google Scholar
Kim, S.L., Jang, S.R., Vittal, R., Lee, J., and Kim, K.J.: Rutile TiO2-modified multi-wall carbon nanotubes in TiO2 film electrodes for dye-sensitized solar cells. J. Appl. Electrochem. 36, 1433 (2006).Google Scholar
Byun, H.Y., Vittal, R., Kim, D.Y., and Kim, K.J.: Beneficial role of cetyltrimethylammonium bromide in the enhancement of photovoltaic properties of dye-sensitized rutile TiO2 solar cells. Langmuir 20, 6853 (2004).Google Scholar
Karim, M.R., Lim, K.T., Lee, M.S., Kim, K., and Yeum, J.H.: Sulfonated polyaniline–titanium dioxide nanocomposites synthesized by one-pot UV-curable polymerization method. Synth. Met. 159, 209 (2009).Google Scholar
Karim, M.R., Lee, H.W., Cheong, I.W., Park, S.M., Oh, W., and Yeum, J.H.: Conducting polyaniline‐titanium dioxide nanocomposites prepared by inverted emulsion polymerization. Polym. Compos. 31, 83 (2010).Google Scholar
Kadoshima, M., Hiratani, M., Shimamoto, Y., Torii, K., Miki, H., Kimura, S., and Nabatame, T.: Rutile-type TiO2 thin film for high-k gate. Thin Solid Films 424, 224 (2003).Google Scholar
Abazovic, N.D., Comor, M.I., Dramicanin, M.D., Jovanovic, D.J., Ahrenkiel, S.P., and Nedeljkovic, J.M.: Photoluminescence of anatase and rutile TiO2 particles. J. Phys. Chem. B 110, 25366 (2006).Google Scholar
Wu, J.M., Shih, H.C., and Wu, W.T.: Formation and photoluminescence of single-crystalline rutile TiO2 nanowires synthesized by thermal evaporation. Nanotechnology 17, 105 (2006).Google Scholar
Zhu, Y., Shi, J., Zhang, Z., Zhang, C., and Zhang, X.: Development of a gas sensor utilizing chemiluminescence on nanosized titanium dioxide. Anal. Chem. 74, 120 (2001).Google Scholar
Corrales, T.P., Allen, N.S., Edge, M., Sandoval, G., and Catalina, F.: A chemiluminescence study of micron and nanoparticle titanium dioxide: Effect on the thermal stability of metallocene polyethylene. J. Photochem. Photobiol., A 156, 151 (2003).Google Scholar
Yin, S., Li, R., He, Q., and Sato, T.: Low temperature synthesis of nanosize rutile titania crystal in liquid media. Mater. Chem. Phys. 75, 76 (2002).CrossRefGoogle Scholar
Wang, L., Yuan, Z., and Egerton, T.A.: The effects of different acids on the preparation of TiO2 nanostructure in liquid media at low temperature. Mater. Chem. Phys. 133, 304 (2012).CrossRefGoogle Scholar
Park, S.D., Cho, Y.H., Kim, W.W., and Kim, S-J.: Understanding of homogeneous spontaneous precipitation for monodispersed TiO2 ultrafine powders with rutile phase around room temperature. J. Solid State Chem. 146, 230 (1999).CrossRefGoogle Scholar
Ovenstone, J.: Preparation of novel titania photocatalysts with high activity. J. Mater. Sci. 36, 1325 (2001).Google Scholar
Navrotsky, A. and Kleppa, O.J.: Enthalpy of the anatase-rutile transformation. J. Am. Ceram. Soc. 50, 626 (1967).Google Scholar
JCPDS—International Centre for Diffraction Data, 2003, PCPDFWIN v. 2.4.Google Scholar
Klug, H.P. and Alexander, L.E.: X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials (Wiley, New York, 1954); 491 pp.Google Scholar
Danilchenko, S.N., Kukharenko, O.G., Moseke, C., Protsenko, I.Y., Sukhodub, L.F., and Sulkio-Cleff, B.: Determination of the bone mineral crystallite size and lattice strain from diffraction line broadening. Cryst. Res. Technol. 37, 1234 (2002).Google Scholar
Watson, S., Beydoun, D., Scott, J., and Amal, R.: Preparation of nanosized crystalline TiO2 particles at low temperature for photocatalysis. J. Nanopart. Res. 6, 193 (2004).Google Scholar
Porto, S.P.S., Fleury, P.A., and Damen, T.C.: Raman spectra of TiO2, MgF2, ZnF2, FeF2, and MnF2 . Phys. Rev. 154, 522 (1967).Google Scholar
Hanaor, D.A.H. and Sorrell, C.C.: Review of the anatase to rutile phase transformation. J. Mater. Sci. 46, 855 (2011).CrossRefGoogle Scholar