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Synthesis and dielectric properties of tungsten-based complex perovskites

Published online by Cambridge University Press:  31 January 2011

D.D. Khalyavin ,
Jiaping Han ,
A.M.R Senos  and
P.Q. Mantas
D.D. Khalyavin
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal
Jiaping Han
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal
A.M.R Senos
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal
P.Q. Mantas*
Affiliation:
Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal
*
bAddress all correspondence to this author. e-mail: pmantas@cv.ua.pt
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Abstract

Ba2MeWO6 (Me=Mg, Ni, Zn) double perovskites were prepared by the conventional solid-state reaction in a wide temperature range. Single-phase ceramics were obtained only at low temperatures approximately 1200°C, whereas a small amount of second phases existed in the samples sintered at higher temperatures. All the compounds are characterized by the cubic perovskite structure (space group Fm3m) with a complete NaCl type ordering between B-site ions. Anomalous temperature variation of the dielectric loss tangent found in the Ba2NiWO6 perovskite is supposed to be connected with a dielectric relaxation due to electronic hopping within thermally activated Ni3+-6W(6-1/6)+/W5+-6Ni(2+1/6)+ clusters. Dielectric measurements showed that the other two perovskites—Ba2ZnWO6 and Ba2MgWO6—exhibit a positive value of the temperature coefficient of permittivity. Such temperature variation is assumed to be caused by a considerable influence of the second polar mode involving B-site ion vibrations on the low-frequency dielectric properties.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 11 , November 2003 , pp. 2600 - 2607
Copyright
Copyright © Materials Research Society 2003

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References

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