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Synthesis and electrochemical properties of benzoxazine-based heteroatom-doped carbon materials

Published online by Cambridge University Press:  15 April 2019

Xiaoli Gao ,
Xiaobo Sun ,
Li Xu ,
Haihan Zhang  and
Guoji Liu
Xiaoli Gao
Affiliation:
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China
Xiaobo Sun
Affiliation:
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China
Li Xu*
Affiliation:
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China
Haihan Zhang
Affiliation:
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China
Guoji Liu
Affiliation:
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: xuli@zzu.edu.cn
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Abstract

In this work, the nitrogen-doped carbon materials (NCM) and nitrogen/sulfur codoped carbon materials (NSCM) were prepared using conventional benzoxazine (BOZ) and sulfur-containing benzoxazine as precursor and SBA-15 as template. The morphology, structure, and electrochemical performance of carbon materials were characterized by scanning electron microscopy, transmission electron microscopy, the X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption–desorption, cyclic voltammetry, and galvanostatic charge–discharge. The results show that the as-prepared carbon materials have ordered mesoporous structure, large specific surface area, and excellent electrochemical properties. The NSCM treated at 800 °C exhibit an extremely high specific capacitance of 550 F/g at the current density of 0.5 A/g in 0.5 mol H2SO4 electrolyte, which shows great improvement compared with NCM. The nitrogen/sulfur codoping is suggested to be a very effective method to improve the performance of carbon materials, and the NSCM should be a promising candidate as electrode materials for supercapacitors.

Keywords

chemical synthesisenergy storagenanostructure
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 7: Focus Section: Interconnects and Interfaces in Energy Conversion Materials , 15 April 2019 , pp. 1219 - 1228
Copyright
Copyright © Materials Research Society 2019 

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