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Synthesis of high strength aluminum alloys in the Al–Ni–La system

Published online by Cambridge University Press:  11 March 2014

Juan Mu*
Affiliation:
Key Laboratory for Anisotropy and Texture of Materials (MOE), Northeastern University, Shenyang 110004, China; and Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Pengfeng Sha
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Zhengwang Zhu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Yandong Wang
Affiliation:
Key Laboratory for Anisotropy and Texture of Materials (MOE), Northeastern University, Shenyang 110004, China
Haifeng Zhang*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Zhuangqi Hu
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
*
a)Address all correspondence to this author. e-mail: hfzhang@imr.ac.cn
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Abstract

High strength aluminum (Al) alloys were prepared by rapid solidification method in the Al–Ni–La system. Microstructural characterizations show that all the investigated Al–Ni–La alloys are comprised of Al, rod-like Al3Ni, and blocky Al11La3 phases, of which the size and volume fraction are composition-dependent. The Al85.5Ni9.5La5 (at.%) alloy shows the finest microstructure, which contributes to the highest strength along with considerable plasticity. The experimental analysis and finite element simulation (FES) show that the distribution of the intermetallic phases greatly affects the mechanical properties of the alloys. The rod-like Al3Ni phase precipitated with the locally uniform direction prevents the propagation of cracks and benefits the plastic deformation, whereas the blocky Al11La3 phase exhibits the nature of brittleness and acts as the origin of the microcrack initiation. These findings suggest a new method to design high strength Al alloys.

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Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Inoue, A. and Nishiyama, N.: New bulk metallic glasses for applications as magnetic-sensing, chemical, and structural materials. MRS Bull. 32, 651 (2007).CrossRefGoogle Scholar
Johnson, W.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).CrossRefGoogle Scholar
Yavari, A., Lewandowski, J., and Eckert, J.: Mechanical properties of bulk metallic glasses. MRS Bull. 32, 635 (2007).CrossRefGoogle Scholar
Kim, J., Inoue, A., and Masumoto, T.: Ultrahigh tensile strengths of Al88Y2Ni9Mn1 or Al88Y2Ni9Fe1 amorphous alloys containing finely dispersed fcc Al particles. Mater. Trans. JIM 31, 747 (1990).CrossRefGoogle Scholar
Mu, J., Fu, H., Zhu, Z., Wang, A., Li, H., Hu, Z., and Zhang, H.: Synthesis and properties of Al-Ni-La bulk metallic glass. Adv. Eng. Mater. 11, 530 (2009).CrossRefGoogle Scholar
Scudino, S., Surreddi, K.B., Nguyen, H.V., Liu, G., Gemming, T., Sakaliyska, M., Kim, J.S., Vierke, J., Wollgarten, M., and Eckert, J.: High-strength Al87Ni8La5 bulk alloy produced by spark plasma sintering of gas atomized powders. J. Mater. Res. 24, 2909 (2009).CrossRefGoogle Scholar
Kawamura, Y., Mano, H., and Inoue, A.: Nanocrystalline aluminum bulk alloys with a high strength of 1420 MPa produced by the consolidation of amorphous powders. Scr. Mater. 44, 1599 (2001).CrossRefGoogle Scholar
Ohtera, K., Terabayashi, T., Nagahama, H., Inoue, A., and Masumoto, T.: Mechanical properties of an Al88.5Ni8Mm3.5(Mm: Misch Metal) alloy produced by extrusion of atomized amorphous plus fcc-aluminum phase powders. Mater. Trans. JIM 33, 775 (1992).CrossRefGoogle Scholar
Sasaki, T., Hono, K., Vierke, J., Wollgarten, M., and Banhart, J.: Bulk nanocrystalline Al85Ni10La5 alloy fabricated by spark plasma sintering of atomized amorphous powders. Mater. Sci. Eng. A 490, 343 (2008).CrossRefGoogle Scholar
Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
Hays, C., Kim, C., and Johnson, W.: Large supercooled liquid region and phase separation in the Zr-Ti-Ni-Cu-Be bulk metallic glasses. Appl. Phys. Lett. 75, 1089 (1999).CrossRefGoogle Scholar
Li, H.: Influence of intermediate-range order on glass formation. J. Phys. Chem. B 108, 5438 (2004).Google Scholar
Penfold, I.T. and Salmon, P.S.: Structure of covalently bonded glass-forming melts: A full partial-structure-factor analysis of liquid GeSe2 . Phys. Rev. Lett. 67, 97 (1991).CrossRefGoogle ScholarPubMed
Liddicoat, P.V., Liao, X.Z., Zhao, Y., Zhu, Y., Murashkin, M.Y., Lavernia, E.J., Valiev, R.Z., and Ringer, S.P.: Nanostructural hierarchy increases the strength of aluminium alloys. Nat. Commun. 1, 63 (2010).CrossRefGoogle ScholarPubMed
Zhang, S., Hu, W., Berghammer, R., and Gottstein, G.: Microstructure evolution and deformation behavior of ultrafine-grained Al-Zn-Mg alloys with fine η′ precipitates. Acta. Mater. 58, 6695 (2010).CrossRefGoogle Scholar
Zhao, Y., Liao, X., Jin, Z., Valiev, R., and Zhu, Y.: Microstructures and mechanical properties of ultrafine grained 7075 Al alloy processed by ECAP and their evolutions during annealing. Acta Mater. 52, 4589 (2004).CrossRefGoogle Scholar
Ralston, K.D., Birbilis, N., Weyland, M., and Hutchinson, C.R.: The effect of precipitate size on the yield strength-pitting corrosion correlation in Al-Cu-Mg alloys. Acta Mater. 58, 5941 (2010).CrossRefGoogle Scholar
Feng, Z.Q., Yang, Y.Q., Huang, B., Luo, X., Li, M.H., Han, M., and Fu, M.S.: Variant selection and the strengthening effect of S precipitates at dislocations in Al-Cu-Mg alloy. Acta Mater. 59, 2412 (2011).CrossRefGoogle Scholar
Fu, H., Mu, J., Wang, A., Li, H., Hu, Z., and Zhang, H.: Synthesis and compressive properties of Al–Ni–Y bulk metallic glass. Philos. Mag. Lett. 89, 711 (2009).CrossRefGoogle Scholar
Inoue, A., Matsumoto, N., and Masumoto, T.: Al-Ni-Y-Co amorphous alloys with high mechanical strengths, wide supercooled liquid region and large glass-forming capacity. Mater. Trans. JIM 31, 493 (1990).CrossRefGoogle Scholar
Sahoo, K.L., Wollgarten, M., Haug, J., and Banhart, J.: Effect of La on the crystallization behaviour of amorphous Al94-xNi6Lax (x=4-7) alloys. Acta Mater. 53, 3861 (2005).CrossRefGoogle Scholar
Wang, S.H. and Bian, X.F.: Crystallization of Al-Mg-Ce and Al-Mg-Ni-Ce amorphous alloys. J. Alloys Compd. 441, 135 (2007).CrossRefGoogle Scholar
Massalski, T.B., Murray, J.L., Bennett, L.H., and Baker, H.: Binary Alloy Phase Diagram (Am. Soc. Metals, Metals Park, OH, 1986).Google Scholar
Mu, J., Fu, H., Zhu, Z., Wang, A., Li, H., Hu, Z., and Zhang, H.: The effect of melt treatment on glass forming ability and thermal stability of Al-based amorphous alloy. Adv. Eng. Mater. 12, 1127 (2010).CrossRefGoogle Scholar
Furukawa, M., Horita, Z., Nemoto, M., Valiev, R., and Langdon, T.: Microhardness measurements and the Hall-Petch relationship in an Al-Mg alloy with submicrometer grain size. Acta Mater. 44, 4619 (1996).CrossRefGoogle Scholar
Hughes, G., Smith, S., Pande, C., Johnson, H., and Armstrong, R.: Hall-Petch strengthening for the microhardness of twelve nanometer grain diameter electrodeposited nickel. Scr. Metall. 20, 93 (1986).CrossRefGoogle Scholar
Qin, X., Wu, X., and Zhang, L.: The microhardness of nanocrystalline silver. Nanostruct. Mater. 5, 101 (1995).CrossRefGoogle Scholar
Inoue, A., Zhang, T., and Masumoto, T.: Zr–Al–Ni amorphous alloys with high glass transition temperature and significant supercooled liquid region. Mater. Trans. JIM 31, 177 (1990).CrossRefGoogle Scholar
Ashby, M. and Jones, D.R.H.: Engineering Materials, Part 1 and 2 (Pergamon Press, Oxford, 1980).Google Scholar
Bauer, D.W.: Fiber reinforced composite product. U.S. Patent No. 3 991 248, Nov 9, 1976.Google Scholar
Dew-Hughes, D. and Robertson, W.: Dispersed particle hardening of aluminum-copper alloy single crystals. Acta Metall. 8, 147 (1960).CrossRefGoogle Scholar
Ibrahim, I., Mohamed, F., and Lavernia, E.: Particulate reinforced metal matrix composites—a review. J. Mater. Sci. 26, 1137 (1991).CrossRefGoogle Scholar
Zhu, Z.W., Zhang, H.F., Hu, Z.Q., Zhang, W., and Inoue, A.: Ta-particulate reinforced Zr-based bulk metallic glass matrix composite with tensile plasticity. Scr. Mater. 62, 278 (2010).CrossRefGoogle Scholar
Hansen, N.: Dispersion strengthening of aluminium-aluminium-oxide products. Acta Metall. 18, 137 (1970).CrossRefGoogle Scholar
Shi, D.: First-principles studies of Ni-Al and Ca-x(x=Si, Ge, Sn, Pb, Zn) intermetallic compounds. Ph.D. Thesis, Dalian University of Technology, 2009.Google Scholar