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Tellurium nanotubes and nanorods synthesized by physical vapor deposition

Published online by Cambridge University Press:  03 March 2011

C. Métraux
Affiliation:
University of Fribourg, Dep. of Geosciences, Mineralogy Group, 1700 Fribourg, Switzerland
B. Grobéty
Affiliation:
University of Fribourg, Dep. of Geosciences, Mineralogy Group, 1700 Fribourg, Switzerland
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Abstract

Tellurium nanotubes and nanorods were synthesized by physical vapor deposition (PVD) in an induction furnace for reaction times between 25 and 35 min. The growth morphologies depended on the reaction times and the atmosphere in the induction furnace. Nanotubes grew only under argon atmosphere (1 mbar). Under vacuum, tellurium blades and nanorods were observed. Of particular interest are the dense carpets of nanorods observed on polycrystalline aluminum. PVD experiences in a conventional high vacuum coating system did not lead to the formation of nanotubes nor nanorods. The interesting electrical properties of tellurium and tellurium compounds combined with the observed growth morphologies are promising for the fabrication of nanoscale functional devices.

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Articles
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1.Iijima, S.: Helical Microtubules of Graphite Carbon Nature 354, 56 (1991).CrossRefGoogle Scholar
2.Harris, P.J.F.: Carbon Nanotubes and Related Structures, New Materials for the Twenty-first Century (Cambridge University Press, Cambridge, U.K., 1999)CrossRefGoogle Scholar
3.Gleize, P., Schouler, M.C., Gadelle, P. and Calliet, A.: Growth of tubular BN filaments. J. Mater. Sci. 29, 1575 (1994).CrossRefGoogle Scholar
4.Chopra, N.G., Luyken, H., Crespi, V.H., Cherrey, K., Zettl, A. and Cohen, M.L.: Synthesis of BN nanotubes. Science 269, 966 (1995).CrossRefGoogle Scholar
5.Narita, I. and Oku, T.: Synthesis of boron nitride nanotubes by using NbB2, YB6 and YB6/Ni powders. Diamond Relat. Mater. 12, 1912 (2003).CrossRefGoogle Scholar
6.Goldberg, D., Rode, A., Bando, Y., Mitome, A., Gamaly, E. and Luther-Davies, B.: Boron nitride nanostructures formed by ultra-high-repetition rate laser ablation. Diamond Relat. Mater. 12, 1226 (2003).Google Scholar
7.Tenne, R., Margulis, L., Genut, A. and Hodes, G.: Polyhedral and Cylindrical Structures of WS2. Nature 360, 444 (1992).CrossRefGoogle Scholar
8.Nath, M., Govindaraj, A. and Rao, C.N.R.: Simple synthesis of MoS2 and WS2 nanotubes. Adv. Mater. 13, 283 (2001).3.0.CO;2-H>CrossRefGoogle Scholar
9.Mayers, B. and Xia, Y.: One-Dimensional Nanostructures of Trigonal Tellurium with Various Morphologies Can Be Synthesized Using a Solution-Phase Approach. ET J. 12, 1875 (2002).Google Scholar
10.Mayers, B. and Xia, Y.: Formation of Tellurium Nanotubes Through Concentration Depletion at the Surfaces of Seeds. Adv. Mater. 14, 279 (2002).3.0.CO;2-2>CrossRefGoogle Scholar
11.Wei, G., Deng, Y., Lin, Y-H. and Nan, C-W.: Solvothermal synthesis of porous tellurium nanotubes. Chem. Phys. Lett. 372, 590 (2003).CrossRefGoogle Scholar
12.Liu, X-Y., Mo, M-S., Chen, X-Y. and Qian, Y-T.: A rational redox route for the synthesis of tellurium nanotubes. Inorg. Chem. Comm. (In press)Google Scholar
13.Mayers, B., Gates, B., Yin, Y. and Xia, Y.: Large scale Synthesis of Monodisperse Nanorods of Se/Te Alloys Through a Homogeneous Nucleation and Solution Growth Process. Adv. Mater. 13, 1380 (2001).3.0.CO;2-W>CrossRefGoogle Scholar
14.Gates, B., Mayers, B., Wu, Y., Sun, Y., Cattle, B., Yang, P. and Xia, Y.: Synthesis and Characterization of Crystalline Ag2Se Nanowires through a Template-Engaged Reaction at Room Temperature. Adv. Funct. Mater. 12, 679 (2002).3.0.CO;2-#>CrossRefGoogle Scholar
15.Jiang, Z-Y., Xie, Z-X., Xie, S-Y., Zhang, X-H., Huang, R-B. and Zheng, L-S.: High purity trigonal selenium nanorods growth via laser ablation under controlled temperature. Chem. Phys. Lett. 368, 425 (2002).CrossRefGoogle Scholar
16.Stadelmann, P.: A Software Package for Electron Diffraction Analysis and HREM Image Simulation in Materials Science Ultramicroscopy 21, 131 (1987).CrossRefGoogle Scholar
17.McLaren, A.C. and Phakey, P.P.: Electron microscope study of Brazil twin boundaries in amethyst quartz. Phys. Stat. Sol. 13, 413 (1966).CrossRefGoogle Scholar
18.McLaren, A.C. and Phakey, P.P.: Di.raction contrast from Dauphiné twin boundaries in quartz Phys. Stat. Sol. 31, 723 (1969).CrossRefGoogle Scholar
19.Mauron, P., Emmeneger, C. and Zuettel, A.: Synthesis of oriented nanotube films by chemical vapor deposition. Carbon 40, 1339 (2002).CrossRefGoogle Scholar