Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-28T01:02:21.114Z Has data issue: false hasContentIssue false
  • English
  • Français

Thermodynamic coupling effect and catalyst effect for the artificial diamond growth

Published online by Cambridge University Press:  31 January 2011

Ji-Tao Wang ,
Zhong-Qiang Huang ,
Yong-Zhong Wan ,
David Wei Zhang  and
Hong-Yong Jia
Ji-Tao Wang
Affiliation:
Department of Electronic Engineering, Fudan University, 200433 Shanghai, China
Zhong-Qiang Huang
Affiliation:
Department of Applied Mathematics, Tongji University, 200092, Shanghai, China
Yong-Zhong Wan
Affiliation:
Department of Electronic Engineering, Fudan University, 200433 Shanghai, China
David Wei Zhang
Affiliation:
Department of Electronic Engineering, Fudan University, 200433 Shanghai, China
Hong-Yong Jia
Affiliation:
Department of Electronic Engineering, Fudan University, 200433 Shanghai, China
Get access

Abstract

The activated chemical vapor deposition (CVD) diamond process became one of the worldwide interesting projects in the 1980s. The basic question is why diamond can grow under activated low pressure conditions. The driving force of the transformation from graphite to diamond under low pressure is coming from a coupled reaction of the association of superequilibrium atomic hydrogen. The thermodynamic coupling effect in the activated CVD process is different from the catalyst effect in the high pressure, catalyst-assisted process for the artificial diamond growth.

Type
Articles
Information
Journal of Materials Research , Volume 12 , Issue 6 , June 1997 , pp. 1530 - 1535
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Wang, J-T. and Carlsson, J-O., Surf. Coatings Techol. 43/44, 1–9 (1990).Google Scholar
2.Wang, J-T., Cao, C-B., and Zheng, P-J., J. Electrochem. Soc. 141 (1), 278–281 (1994).CrossRefGoogle Scholar
3.Wang, J-T. and Zheng, P-J., Chinese Sci. Bull., Chinese ed., 40 (11), 1056 (1995); English ed., 40 (13), 1141–1143 (1995).Google Scholar
4.Wang, J-T., Zheng, P-J., Yang, Q-H., and Wang, H., in Proc. 4th Int. Symp. on Diamond Materials (The Electrochemical Soc., Inc., Pennington, NJ, 1995), PV95–4, pp. 13–18.Google Scholar
5.Zhang, Y-F., Zhang, F-Q., and Chen, G-H., J. Mater. Res. 9, 2845–2849 (1994).CrossRefGoogle Scholar
6.Shen, R-C. and Gu, Q-M., Textbook of Biochemistry (Higheducation Press, Beijing, 1993), pp. 55, 327.Google Scholar
7.Stryer, L., Biochemistry, 3rd ed. (W. H. Freeman and Co., New York, 1988), p. 410.Google Scholar
8.Prigogine, I., Introduction to Thermodynamics of Irreversible Processes, 3rd ed. (Interscience Pub., New York, 1967), Chap. 3.Google Scholar
9.Matsumoto, S., Sato, Y., Tsutsumi, M., and Setaka, N., J. Mater. Sci. 17, 3106 (1982).CrossRefGoogle Scholar
10.Setaka, N., Proc. 3rd Int. Symp. on Diamond Materials, Honolulu, HI, May 16–21, 1993 (The Electrochemical Society, Pennington, NJ, 1993), Vol. PV93–17, p. 1.Google Scholar
11.Moore, W. J., Physical Chemistry, 4th ed. (Longman Group Limited, London, 1976), Chap. 9, p. 408.Google Scholar
12.Zhang, G-Y., Li, Z-H., and Wu, J-Z., Physics (in Chinese) 3 (4), 241–242 (1974).Google Scholar
13.Spitsyn, B. V., in Proc. 4th Int. Symp. on Diamond Materials (The Electrochemical Soc., Inc., Pennington, NJ, 1995), PV95–4, pp. 61–72.Google Scholar
14.Zhu, W., Mewwier, R., and Badian, A. R., in Proc. 1st Int. Symp. on Diamond and Diamond-Like Films, edited by J. P. Dismukes (1989), p. 61.Google Scholar
15.Fu, X-C., Shen, W-X., and Yao, T-Y., Physical Chemistry, 4th ed. (High-education Press, Beijing, 1990), Vol. I, p. 419.Google Scholar