Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2025-01-02T20:44:43.811Z Has data issue: false hasContentIssue false
  • English
  • Français

Topotactic synthesis of vanadium nitride solid foams

Published online by Cambridge University Press:  31 January 2011

Ted S. Oyama ,
Rajat Kapoor ,
Hideko T. Oyama ,
David J. Hofmann  and
Egon Matijević
Ted S. Oyama
Affiliation:
Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5814
Rajat Kapoor
Affiliation:
Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5814
Hideko T. Oyama
Affiliation:
Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5814
David J. Hofmann
Affiliation:
Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5814
Egon Matijević
Affiliation:
Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5814
Get access

Abstract

Vanadium nitride has been synthesized with a surface area of 120 m2 g−1 by temperature programmed nitridation of a foam-like vanadium oxide (35 m2 g−1), precipitated from vanadate solutions. The nitridation reaction was established to be topotactic and pseudomorphous by x-ray powder diffraction and scanning electron microscopy. The crystallographic relationship between the nitride and oxide was {200}//{001}. The effect of precursor geometry on the product size and shape was investigated by employing vanadium oxide solids of different morphologies.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 6 , June 1993 , pp. 1450 - 1454
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Levy, R.B. and Boudart, M., Science 181, 547 (1973).CrossRefGoogle Scholar
2Oyama, S.T. and Haller, G.L., Catalysis, Specialist Periodical Reports 5, 333 (1981).Google Scholar
3Oyama, S.T., Catalysis Today 15, 179 (1992).CrossRefGoogle Scholar
4Leclerq, L., Surface Properties and Catalysis by Non-Metals, edited by Bonnelle, J.P. (Reidel, New York, 1983).Google Scholar
5Ranhotra, G. S., Hadix, G. W., Bell, A. T., and Reimer, J. A., J. Catal. 108, 24 (1987).CrossRefGoogle Scholar
6Toth, L. E., Transition Metal Carbides and Nitrides (Academic Press, New York, 1971).Google Scholar
7Wilner, G.W. and Berger, J.A., J. Metals 7, 360 (1955).Google Scholar
8Shy, Y. M., Toth, L. E., and Somasundaram, R., J. Appl. Phys. 44, 5539 (1973).CrossRefGoogle Scholar
9Powell, R. M., Skocpol, W., and Tinkham, M., J. Appl. Phys. 48, 788 (1977).CrossRefGoogle Scholar
10Hahn, H., Logas, J., and Averback, R.S., J. Mater. Res. 5, 609 (1990).CrossRefGoogle Scholar
11Herring, C., J. Appl. Phys. 21, 437 (1950).CrossRefGoogle Scholar
12Coble, R. L., J. Appl. Phys. 34, 1679 (1963).CrossRefGoogle Scholar
13Volpe, L. and Boudart, M., Catal. Rev.-Sci. Eng. 27, 515 (1985).CrossRefGoogle Scholar
14Dent-Glasser, L. S., Glasser, F. P., and Taylor, H. F. W., Quart, Rev. Chem. Soc. 16, 343 (1962).CrossRefGoogle Scholar
15Bertrand, O. and Dufour, L.C., Phys. Status Solidi A 60, 507 (1980).CrossRefGoogle Scholar
16Gunter, J.P., J. Solid State Chem. 5, 354 (1972).CrossRefGoogle Scholar
17Volpe, L. and Boudart, M., J. Solid State Chem. 59, 348 (1985).CrossRefGoogle Scholar
18Volpe, L. and Boudart, M., J. Solid State Chem. 59, 332 (1985).CrossRefGoogle Scholar
19Volpe, L., Oyama, S.T., and Boudart, M., Preparation of Catalysts III, edited by Poncelet, G., Garange, P., and Jocobs, P. A. (Elsevier Science Publishers B.V., Amsterdam, The Netherlands, 1983).Google Scholar
20Kapoor, R. and Oyama, S.T., J. Solid State Chem. 99, 303 (1992).CrossRefGoogle Scholar
21Powder Diffraction Data File, Inorganic Phases, JCPDS International Centre for Diffraction Data, Swarthmore, PA, 1981.Google Scholar
22Baes, C. F. and Mesmer, R. E., The Hydrolysis of Cations (John Wiley, New York, 1976).Google Scholar
23Livage, J., Chem. Mater. 3, 578 (1991).CrossRefGoogle Scholar
24Pope, M.T. and Dale, B.W., Quart. Rev. Chem. Soc. 22, 527 (1966).CrossRefGoogle Scholar
25Connors, J.A. and Ebsworth, E.A.V., Adv. Inorg. Chem. Radiochem. 6, 279 (1964).CrossRefGoogle Scholar
26Selbin, J., Chem. Rev. 65, 153 (1965).CrossRefGoogle Scholar
27Clark, R. J. H., Chemistry of Titanium and Vanadium (Elsevier Science Publishers, New York, 1969).Google Scholar
28Orhanovic, M. and Wilkins, R.G., J. Am. Chem. Soc. 89, 278 (1967).CrossRefGoogle Scholar