Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T22:16:49.917Z Has data issue: false hasContentIssue false
  • English
  • Français

Zinc cobalt bimetallic nanoparticles embedded in porous nitrogen-doped carbon frameworks for the reduction of nitro compounds

Published online by Cambridge University Press:  16 May 2017

Xuejuan Xu ,
Hui Li ,
Hongtao Xie ,
Yuhua Ma ,
Tingxiang Chen  and
Jide Wang
Xuejuan Xu*
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Hui Li
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Hongtao Xie
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Yuhua Ma
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Tingxiang Chen
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Jide Wang*
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur, Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
*
b) 270997380@qq.com
a) Address all correspondence to these authors. e-mail: awangjd@sina.cn
Get access

Abstract

The development of highly efficient and stable inexpensive catalysts for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) by NaBH4 in an aqueous solution by utilizing metal-organic frameworks (MOFs) as precursor and template remains a hot topic. Herein, a simple self-template strategy was developed to synthesize a porous nitrogen-doped carbon frameworks embedded with zinc and cobalt nanoparticles (Zn0.3Co2.7@NC) catalyst by thermal annealing of the bimetallic zinc-cobalt zeolitic imidazolate framework (Zn0.3Co2.7-ZIF) as an effective precursor and template. The resulting Zn0.3Co2.7@NC catalysts show an excellent catalytic activity for the reduction of 4-NP and the reduction reaction was completed only in 5 min with nearly 100% conversion. The apparent rate constant for the reaction of 4-NP reduction was estimated to be 0.683 min−1. Moreover, the catalyst was extended to reduce other nitro compounds and exhibited excellent catalytic activity. When compared to other related catalysts in the literature, the catalytic activity of catalyst is superior. Therefore, the resulting Zn0.3Co2.7@NC is expected to get more extensive application in the field of catalysis.

Keywords

ZnCocatalytic
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 9 , 15 May 2017 , pp. 1777 - 1786
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Edson Roberto Leite

References

REFERENCES

Raula, M., Rashid, M.H., Lai, S., Roy, M., and Mandal, T.K.: Solvent-adoptable polymer Ni/NiCo alloy nanochains: Highly active and versatile catalysts for various organic reactions in both aqueous and nonaqueous media. ACS Appl. Mater. Interfaces 4, 878 (2012).Google Scholar
Torres Galvis, H.M., Bitter, J.H., Khare, C.B., Ruitenbeek, M., Dugulan, A.I., and de Jong, K.P.: Supported iron nanoparticles as catalysts for sustainable production of lower olefins. Science 335, 835 (2012).Google Scholar
van Speybroeck, V., Gani, R., and Meier, R.J.: The calculation of thermodynamic properties of molecules. Chem. Soc. Rev. 39, 1764 (2010).Google Scholar
Lin, Y., Qiao, Y., Wang, Y., Yan, Y., and Huang, J.: Self-assembled laminated nanoribbon-directed synthesis of noble metallic nanoparticle-decorated silica nanotubes and their catalytic applications. J. Mater. Chem. 22, 18314 (2012).Google Scholar
Yan, N., Zhao, Z., Li, Y., Wang, F., Zhong, H., and Chen, Q.: Synthesis of novel two-phase Co@SiO2 nanorattles with high catalytic activity. Inorg. Chem. 53, 9073 (2014).Google Scholar
Zhao, M., Deng, K., He, L., Liu, Y., Li, G., Zhao, H., and Tang, Z.: Core–shell palladium nanoparticle@metal-organic frameworks as multifunctional catalysts for cascade reactions. J. Am. Chem. Soc. 136, 1738 (2014).Google Scholar
Chughtai, A.H., Ahmad, N., Younus, H.A., Laypkov, A., and Verpoort, F.: Metal-organic frameworks: Versatile heterogeneous catalysts for efficient catalytic organic transformations. Chem. Soc. Rev. 44, 6804 (2015).Google Scholar
Stock, N. and Biswas, S.: Synthesis of metal-organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites. Chem. Rev. 112, 933 (2012).Google Scholar
Aijaz, A., Fujiwara, N., and Xu, Q.: From metal-organic framework to nitrogen-decorated nanoporous carbons: High CO2 uptake and efficient catalytic oxygen reduction. J. Am. Chem. Soc. 136, 6790 (2014).Google Scholar
Bak, W., Kim, H.S., Chun, H., and Yoo, W.C.: Facile synthesis of metal/metal oxide nanoparticles inside a nanoporous carbon matrix (M/MO@C) through the morphology-preserved transformation of metal-organic framework. Chem. Commun. 51, 7238 (2015).Google Scholar
Chen, Y-Z., Wang, C., Wu, Z-Y., Xiong, Y., Xu, Q., Yu, S-H., and Jiang, H-L.: From bimetallic metal-organic framework to porous carbon: High surface area and multicomponent active dopants for excellent electrocatalysis. Adv. Mater. 27, 5010 (2015).Google Scholar
Bai, C., Yao, X., and Li, Y.: Easy access to amides through aldehydic C–H bond functionalization catalyzed by heterogeneous Co-based catalysts. ACS Catal. 5, 884 (2015).Google Scholar
Kim, M., Nam, D-H., Park, H-Y., Kwon, C., Eom, K., Yoo, S., Jang, J., Kim, H-J., Cho, E., and Kwon, H.: Cobalt-carbon nanofibers as an efficient support-free catalyst for oxygen reduction reaction with a systematic study of active site formation. J. Mater. Chem. A 3, 14284 (2015).Google Scholar
Zhong, W., Liu, H., Bai, C., Liao, S., and Li, Y.: Base-free oxidation of alcohols to esters at room temperature and atmospheric conditions using nanoscale Co-based catalysts. ACS Catal. 5, 1850 (2015).Google Scholar
Bai, S., Shen, X., Zhu, G., Li, M., Xi, H. and Chen, K.: In situ growth of Ni(x)Co(100-x) nanoparticles on reduced graphene oxide nanosheets and their magnetic and catalytic properties. Appl. Mater. and Interfaces 4, 2378–2386 (2012).Google Scholar
Hu, L., Zhang, R., Wei, L., Zhang, F., and Chen, Q.: Synthesis of FeCo nanocrystals encapsulated in nitrogen-doped graphene layers for use as highly efficient catalysts for reduction reactions. Nanoscale 7, 450–454 (2014).Google Scholar
Su, P., Xiao, H., Zhao, J., Yao, Y., Shao, Z., Li, C., and Yang, Q.: Nitrogen-doped carbon nanotubes derived from Zn–Fe–ZIF nanospheres and their application as efficient oxygen reduction electrocatalysts with in situ generated iron species. Chem. Sci. 4, 2941 (2013).Google Scholar
Aguirre-Díaz, L.M., Gándara, F., Iglesias, M., Snejko, N., Gutiérrez-puebla, E., and Monge, M.Á.: Tunable catalytic activity of solid solution metal-organic frameworks in one-pot multicomponent reactions. J. Am. Chem. Soc. 137, 6132 (2015).Google Scholar
Hou, Y-L., Sun, R.W-Y., Zhou, X-P., Wang, J-H., and Li, D.: A copper(i)/copper(ii)-salen coordination polymer as a bimetallic catalyst for three-component Strecker reactions and degradation of organic dyes. Chem. Commun. 50, 2295 (2014).Google Scholar
Long, J., Shen, K., Chen, L., and Li, Y.: Multimetal-MOF-derived transition metal alloy NPs embedded in an N-doped carbon matrix: Highly active catalysts for hydrogenation reactions. J. Mater. Chem. A 4, 10254 (2016).Google Scholar
Naeem, S., Ribes, A., White, A.J.P., Haque, M.N., Holt, K.B., and Wilton-Ely, J.D.E.T.: Multimetallic complexes and functionalized nanoparticles based on oxygen- and nitrogen-donor combinations. Inorg. Chem. 52, 4700 (2013).Google Scholar
Liao, Y., Zhang, D., Wang, Q., Wen, T., Jia, L., Zhong, Z., Bai, F., Tang, L., Que, W., and Zhang, H.: Open-top TiO2 nanotube arrays with enhanced photovoltaic and photochemical performances via a micromechanical cleavage approach. J. Mater. Chem. A 3, 14279 (2015).Google Scholar
Shi, Z-Q., Jiao, L-X., Sun, J., Chen, Z-B., Chen, Y-Z., Zhu, X-H., Zhou, J-H., Zhou, X-C., Li, X-Z., and Li, R.: Cobalt nanoparticles in hollow mesoporous spheres as a highly efficient and rapid magnetically separable catalyst for selective epoxidation of styrene with molecular oxygen. RSC Adv. 4, 47 (2014).Google Scholar
Liu, Y., Liu, B., Liu, Y., Wang, Q., Hu, W., Jing, P., Liu, L., Yu, S., and Zhang, J.: Improvement of catalytic performance of preferential oxidation of CO in H2-rich gases on three-dimensionally ordered macro- and meso-porous Pt–Au/CeO2 catalysts. Appl. Catal., B 142–143, 615 (2013).Google Scholar
Rong, F., Zhao, J., Su, P., Yao, Y., Li, M., Yang, Q., and Li, C.: Zinc-cobalt oxides as efficient water oxidation catalysts: The promotion effect of ZnO. J. Mater. Chem. A 3, 4010–4017 (2015).Google Scholar
Huang, Z-F., Song, J., Li, K., Tahir, M., Wang, Y-T., Pan, L., Wang, L., Zhang, X., and Zou, J-J.: Hollow cobalt-based bimetallic sulfide polyhedra for efficient all-pH-value electrochemical and photocatalytic hydrogen evolution. J. Am. Chem. Soc. 138, 1359 (2016).Google Scholar
Li, X., Zeng, C., Jiang, J., and Ai, L.: Magnetic cobalt nanoparticles embedded in hierarchically porous nitrogen-doped carbon frameworks for highly efficient and well-recyclable catalysis. J. Mater. Chem. A 4, 7476–7482 (2016).Google Scholar
Rakap, M. and Özkar, S.: Intrazeolite cobalt(0) nanoclusters as low-cost and reusable catalyst for hydrogen generation from the hydrolysis of sodium borohydride. Appl. Catal., B 91, 21 (2009).Google Scholar
Rakap, M. and Özkar, S.: Hydroxyapatite-supported cobalt(0) nanoclusters as efficient and cost-effective catalyst for hydrogen generation from the hydrolysis of both sodium borohydride and ammonia-borane. Catal. Today 183, 17 (2012).Google Scholar
Li, X., Gao, X., Ai, L., and Jiang, J.: Mechanistic insight into the interaction and adsorption of Cr(VI) with zeolitic imidazolate framework-67 microcrystals from aqueous solution. Chem. Eng. J. 274, 238–246 (2015).Google Scholar
Wu, R., Qian, X., Zhou, K., Wei, J., Lou, J., and Ajayan, P.M.: Porous spinel Zn x Co3−x O4 hollow polyhedra templated for high-rate lithium-ion batteries. ACS Nano 8, 6297 (2014).Google Scholar
Peng, S., Li, L., Tan, H., Cai, R., Shi, W., Li, C., Mhaisalkar, S.G., Srinivasan, M., Ramakrishna, S., and Yan, Q.: MS2 (M = Co and Ni) hollow spheres with tunable interiors for high-performance supercapacitors and photovoltaics. Adv. Funct. Mater. 24, 2155 (2014).Google Scholar
Xiao, Y., Liu, S., Li, F., Zhang, A., Zhao, J., Fang, S., and Jia, D.: 3D hierarchical Co3O4 twin-spheres with an urchin-like structure: Large-scale synthesis, multistep-splitting growth, and electrochemical pseudocapacitors. Adv. Funct. Mater. 22, 4052 (2012).Google Scholar
Kong, A., Mao, C., Lin, Q., Wei, X., Bu, X., and Feng, P.: From cage-in-cage MOF to N-doped and Co-nanoparticle-embedded carbon for oxygen reduction reaction. Dalton Trans. 44, 6748 (2015).Google Scholar
Wei, J., Hu, Y., Wu, Z., Liang, Y., Leong, S., Kong, B., Zhang, X., Zhao, D., Simon, G.P., and Wang, H.: A graphene-directed assembly route to hierarchically porous Co–N x /C catalysts for high-performance oxygen reduction. J. Mater. Chem. A 3, 16867 (2015).Google Scholar
Zhang, Z., Hao, J., Yang, W., and Tang, J.: Defect-rich CoP/nitrogen-doped carbon composites derived from a metal-organic framework: High-performance electrocatalysts for the hydrogen evolution reaction. ChemCatChem 7, 1920 (2015).Google Scholar
Lü, Y., Wang, Y., Li, H., Lin, Y., Jiang, Z., Xie, Z., Kuang, Q., and Zheng, L.: Mof-derived porous Co/C nanocomposites with excellent electromagnetic wave absorption properties. ACS Appl. Mater. Interfaces 7, 13604 (2015).Google Scholar
Torad, N.L., Hu, M., Ishihara, S., Sukegawa, H., Belik, A.A., Imura, M., Ariga, K., Sakka, Y., and Yamauchi, Y.: Direct synthesis of MOF-derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment. Small 10, 2096 (2014).Google Scholar
Khemasiri, N., Chananonnawathorn, C., Klamchuen, A., Jessadaluk, S., Pankiew, A., Vuttivong, S., Eiamchai, P., Horprathum, M., Pornthreeraphat, S., Kasamechonchung, P., Tantisantisom, K., Boonkoom, T., Songsiririthigul, P., Nakajima, H., and Nukeaw, J.: Crucial role of reactive pulse-gas on a sputtered Zn3N2 thin film formation. RSC Adv. 6, 94905 (2016).Google Scholar
Jiang, N., Georgiev, D.G., Jayatissa, A.H., Collins, R.W., Chen, J., and McCullen, E.: Zinc nitride films prepared by reactive RF magnetron sputtering of zinc in nitrogen containing atmosphere. J. Phys. D: Appl. Phys. 45, 135101 (2012).Google Scholar
Kong, X-K., Sun, Z-Y., Chen, M., Chen, C-L., and Chen, Q-W.: Metal-free catalytic reduction of 4-nitrophenol to 4-aminophenol by N-doped graphene. Energy Environ. Sci. 6, 3260 (2013).Google Scholar
Yang, Y., Zhang, W., Ma, X., Zhao, H., and Zhang, X.: Facile construction of mesoporous N-Doped carbons as highly efficient 4-nitrophenol reduction catalysts. ChemCatChem 7, 3454 (2015).Google Scholar
Ma, L., Shen, X., Zhu, G., Ji, Z., and Zhou, H.: CoP nanoparticles deposited on reduced graphene oxide sheets as an active electrocatalyst for the hydrogen evolution reaction. Carbon 77, 255–265 (2015).Google Scholar
Wu, K-L., Wei, X-W., Zhou, X-M., Wu, D-H., Liu, X-W., Ye, Y., and Wang, Q.: NiCo2 alloys: Controllable synthesis, magnetic properties, and catalytic applications in reduction of 4-nitrophenol. J. Phys. Chem. C 115, 16268–16274 (2011).Google Scholar
Yang, Y., Zhang, Y., Sun, C.J., Li, X., Zhang, W., Ma, X., Ren, Y., and Zhang, X.: Heterobimetallic metal-organic framework as a precursor to prepare a nickel/nanoporous carbon composite catalyst for 4-nitrophenol reduction. ChemCatChem 6, 3084–3090 (2014).Google Scholar
Bai, S., Shen, X., Zhu, G., Li, M., Xi, H., and Chen, K.: In situ growth of Ni x Co100−x nanoparticles on reduced graphene oxide nanosheets and their magnetic and catalytic properties. ACS Appl. Mater. Interfaces 4, 2378–2386 (2012).Google Scholar
Wang, X., Liu, D., Song, S., and Zhang, H.: Heterobimetallic metal-organic framework as a precursor to prepare a nickel/nanoporous carbon composite catalyst for 4-nitrophenol reduction. J. Am. Chem. Soc. 135, 15864–15872 (2013).Google Scholar
Li, J., Liu, C.Y., and Liu, Y.: Au/graphene hydrogel: Synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. J. Mater. Chem. 22, 8426–8430 (2012).Google Scholar
Ai, L., Yue, H., and Jiang, J.: Environmentally friendly light-driven synthesis of Ag nanoparticles in situ grown on magnetically separable biohydrogels as highly active and recyclable catalysts for 4-nitrophenol reduction. J. Mater. Chem. 22, 23447–23453 (2012).Google Scholar
Tang, S.C., Vongehr, S., and Meng, X.K.: Environmentally friendly light-driven synthesis of Ag nanoparticles in situ grown on magnetically separable biohydrogels as highly active and recyclable catalysts for 4-nitrophenol reduction. J. Phys. Chem. C 114, 977–982 (2010).Google Scholar
Supplementary material: File

Xu supplementary material

Xu supplementary material

Download Xu supplementary material(File)
File 4.6 MB