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Ag nanocluster synthesis by laser ablation in Ar atmosphere: A plume dynamics analysis

Published online by Cambridge University Press:  12 March 2009

E. Fazio ,
F. Neri ,
P.M. Ossi ,
N. Santo  and
S. Trusso
E. Fazio
Affiliation:
Dipartimento di Fisica della Materia e Ingegneria Elettronica, Università di Messina, Messina, Italy
F. Neri
Affiliation:
Dipartimento di Fisica della Materia e Ingegneria Elettronica, Università di Messina, Messina, Italy
P.M. Ossi
Affiliation:
Dipartimento Energia & Centre for NanoEngineered MAterials and Surfaces, NEMAS, Politecnico di Milano, Milano, Italy
N. Santo
Affiliation:
Centro Interdipartimentale Microscopia Avanzata, Università degli Studi di Milano, Milano, Italy
S. Trusso*
Affiliation:
CNR-Istituto per i Processi Chimico-Fisici Sezione di Messina, Salita Sperone, Messina, Italy
*
Address correspondence and reprint requests to: S. Trusso, CNR-Istituto per i Processi Chimico-Fisici Sezione di Messina, Salita Sperone, C.da Papardo, Faro Superiore, 98158 Messina, Italy. E-mail: trusso@me.cnr.it
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Abstract

Ag thin films were deposited by pulsed laser ablation in a controlled Ar atmosphere. The deposition process was performed at different Ar pressure values in the range between 10 and 100 Pa to investigate the influence of ambient gas pressure on the plasma expansion dynamics and on the film structural properties. Position, velocity and volume of the laser generated plasma as functions of time were obtained by time resolved fast photography. The morphological properties of the films were investigated by transmission electron microscopy which shows that film growth proceeds via aggregation on the substrates of nanoclusters formed in the expanding plume. The formation of nanoparticles takes place as a consequence of plasma confinement induced by the interaction with ambient gas species. Data from fast photography analysis were used as input parameters to calculate the size of the nanoparticles using a model that takes into account the collisional nature of the laser generated silver plasma.

Keywords

Laser ablationPlasma expansionSilver clusters
Type
Research Article
Information
Laser and Particle Beams , Volume 27 , Issue 2 , June 2009 , pp. 281 - 290
Copyright
Copyright © Cambridge University Press 2009

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References

REFERENCES

Bailini, A. & Ossi, P.M. (2006 a). Effect of ambient gas ionisation on the morphology of a pulsed laser deposited carbon film. Carbon 44, 3049–3052.Google Scholar
Bailini, A. & Ossi, P.M. (2006 b). How the dynamics of an ablation plume is affected by ambient gas ionisation. Rad. Eff. Def. Sol. 160, 567–573.Google Scholar
Bailini, A., Ossi, P.M. & Rivolta, A. (2007 a). Plume propagation through a buffer gas and cluster size prediction. Appl. Surf. Sci. 253 7682–7685.Google Scholar
Bailini, A. & Ossi, P.M. (2007 b). Expansion of an ablation plume in a buffer gas and cluster growth. Europhys. Lett. 79, 35002/1–6.Google Scholar
Baserga, A., Russo, V., Di Fonzo, F., Bailini, A., Cattaneo, D., Casari, C.S., Li Bassi, A. & Bottani, C.E. (2007). Nanostructured tungsten oxide with controlled properties: Synthesis and Raman characterization. Thin Solid Films 515, 6465–6469.Google Scholar
Bertoni, G., Cepek, C., Romanato, F., Casari, C.S., Li Bassi, A., Bottani, C.E. & Sancrotti, M. (2004). Growth of multi-wall and single-wall carbon nanotubes with in situ high vacuum catalyst deposition. Carbon 42, 440–443.Google Scholar
Bolgiaghi, D., Miotello, A., Mosaner, P., Ossi, P.M. & Radnoczi, G. (2005). Pulsed laser deposition of glass-like cluster assembled carbon films. Carbon 43, 2122–2127.CrossRefGoogle Scholar
Cheung, J.T. (1994). History and fundamentals of pulsed laser deposition. In Pulsed Laser Deposition of Thin Films. (Crisey, D.B. and Hubler, G.K. Eds.), pp. 1. New York: Wiley.Google Scholar
Compagnini, G., Pignataro, B. & Pelligra, B. (1997). Nanomorphology and SERS activity in plasma prepared silver surfaces. Chem. Phys. Lett. 272 453–458.CrossRefGoogle Scholar
Di Fonzo, F., Bailini, A., Russo, V., Baserga, A., Cattaneo, D., Beghi, M.G., Ossi, P.M., Casari, C.S., Li Bassi, A. & Bottani, C.E. (2006). Synthesis and characterization of tungsten and tungsten oxide nanostructured films. Catal. Today 116, 69–73.Google Scholar
Dolbec, R., Irissou, E., Chaker, M., Guay, D., Rosei, F. & El Khakani, M.A. (2004). Growth dynamics of pulsed laser deposited Pt nanoparticles on highly oriented pyrolitic graphite substrates. Phys. Rev. B 70, 201406(R)1/201406(R)4.Google Scholar
Dyer, P.E., Issa, A. & Key, P.H. (1990). Dynamics of excimer laser ablation of superconductors in a oxygen environment. Appl. Phys. Lett. 57, 186–188.Google Scholar
Fazio, B., Trusso, S., Fazio, E., Neri, F., Ossi, P.M. & Santo, N. (2008). Nanostructured silver thin films deposited by pulsed laser ablation. Rad. Eff. Def. Solids 163, 673–683.Google Scholar
Gamaly, E.G., Rode, A.V. & Luther-Davies, B. (2000). Formation of diamond-like carbon films and carbon foam by ultrafast laser ablation. Laser Part. Beams 18, 245–254.Google Scholar
Geohegan, D.B. (1992). Fast intensified-CCD photography of YBa2Cu3O7−x laser ablation in vacuum and ambient oxygen. Appl. Phys. Lett. 60, 2732–2734.Google Scholar
Geohegan, D.B. (1994). Diagnostic and characteristic of laser produced plasma. In Pulsed Laser Deposition of Thin Films. (Crisey, D.B. and Hubler, G.K., Eds.), pp. 115. New York: Wiley.Google Scholar
Gonzalo, J., Afonso, C.N. & Madariaga, I. (1997). Expansion dynamics of the plasma produced by laser ablation of BaTiO3 in a gas environment. J. Appl. Phys. 81, 951–955.Google Scholar
Hafeez, S., Shaikh, N.M. & Baig, M.A. (2008). Spectroscopic studies of Ca plasma generated by the fundamental, second, and third harmonics of a Nd:YAG laser. Laser Part. Beams 26, 41–50.Google Scholar
Irissou, E., Le Drogoff, B., Chaker, M. & Guay, D. (2003). Platinum nanoparticles growth by means of pulsed laser ablation. J. Appl. Phys. 94, 4796–4802.Google Scholar
Jarrold, M.F. (1994). Clusters of Atoms and Molecules. Berlin: Springer.Google Scholar
Jin, R., Cao, Y., Mirkin, C.A., Kelly, K.L., Schatz, G.C. & Zheng, J.G. (2001). Photo induced conversion of Ag nanospheres to nanoprisms. Sci. 294, 1901–1903.CrossRefGoogle Scholar
Kneipp, K., Wang, Y., Kneipp, H., Perelman, L.T., Itzkan, I., Dasari, R.R. & Feld, M.S. (1997). Single molecule detection using surface-enhanced raman scattering. Phys. Rev Lett. 78, 1667–1670.Google Scholar
Nie, S. & Emory, S.R. (1997). Probing single molecules and single nanoparticles by surface-enhanced. Raman scattering. Sci. 275, 1102–1106.Google Scholar
Ossi, P.M., Bailini, A., Geszti, O. & Radnoczi, G. (2008 a). Morphology and growth of WOx films prepared by laser ablation of W in different atmospheres. Europhys. Lett. 83, 68005/1–5.Google Scholar
Ossi, P.M. & Bailini, A. (2008 b). Cluster growth in an ablation plume propagating through a buffer gas. Appl. Phys. A. 93, 645–650.CrossRefGoogle Scholar
Rafique, M.S., Khaleeq-Ur-Rahman, M., Riaz, I., Jalil, R. & Farid, N. (2008). External magnetic field effect on plume images and X-ray emission from a nanosecond laser produced plasma. Laser Part. Beams 26, 217–224.CrossRefGoogle Scholar
Rivolta, A. (2006). A model for cluster synthesis during pulsed laser deposition in an ambient gas. Laurea Thesis (in Italian). Milano: Politecnico di Milano.Google Scholar
Rode, A.V., Gamaly, E.G. & Luther-Davies, B. (2000). Strong paramagnetism and possible ferromagnetism in pure carbon nanofoam produced by laser ablation. Appl. Phys. A 70, 135–144.Google Scholar
Seal, K., Nelson, M.A., Ying, Z.C., Genov, D.A., Sarychev, A.K. & Shalaev, V.M. (2003). Growth, morphology, and optical and electrical properties of semicontinuous metallic films. Phys. Rev. B 67, 035318/1–13.Google Scholar
Schade, W., Bohling, C., Hohmann, K. & Scheel, D. (2006). Laser-induced plasma spectroscopy for mine detection and verification. Laser Part. Beams 24, 241–247.Google Scholar
Thareja, R.K. & Sharma, A.K. (2006). Reactive pulsed laser ablation: Plasma studies. Laser Part. Beams 24, 311–320.Google Scholar
Trusso, S., Barletta, E., Barreca, F. & Neri, F. (2004). Pulsed laser ablation of SiC in a nitrogen atmosphere: formation of CN. Appl. Phys. A 79, 1997–2005.Google Scholar
Trusso, S., Barletta, E., Barreca, F., Fazio, E. & Neri, F. (2005). Time resolved imaging studies of the plasma produced by laser ablation of silicon in O2/Ar atmosphere. Laser Part. Beams 23, 149–153.Google Scholar
Wang, Y.-L, Xu, W., Zhou, Y., Chu, L.-Z. & Fu, G.-S. (2007). Influence of pulse repetition rate on the average size of silicon nanoparticles deposited by laser ablation. Laser Part. Beams 25, 9–13.Google Scholar
Wolowsky, J., Badziak, J., Czarnecka, A., Parys, P., Pisarek, P., Rosinski, M., Turan, R. & Yerci, S. (2007). Application of pulsed laser deposition and laser-induced ion implantation for formation of semiconductor nano-crystallites. Laser Part. Beams 25, 65–69.Google Scholar
Zel'dovich, Y.B. & Raizer, Y.P. (1966). Physics of Shock Waves and High Temperature Hydrodynamic Phenomena. New York: Academic Press.Google Scholar
Zenkevich, A.V., Pushkin, M.A., Tronin, V.N., Troyan, V.I., Nevolin, V.N., Maximov, G.A., Filatov, D.O. & Laegsgaard, E. (2002). Formation of Au fractal nanoclusters during pulsed laser deposition on highly oriented pyrolitic graphite. Phys. Rev. B 65, 073406/1–4.Google Scholar