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Applications industrielles des technologies supercritiques :état de l'art et perspectives

Published online by Cambridge University Press:  19 November 2004

Gérard Charbit ,
Elisabeth Badens  and
Olivier Boutin
Gérard Charbit
Affiliation:
Laboratoire de Procédés Propres et Environnement, Europôle de l'Arbois, Bâtiment Laennec, BP 80, 13545 Aix-en-Provence Cedex 4, France
Elisabeth Badens
Affiliation:
Laboratoire de Procédés Propres et Environnement, Europôle de l'Arbois, Bâtiment Laennec, BP 80, 13545 Aix-en-Provence Cedex 4, France
Olivier Boutin
Affiliation:
Laboratoire de Procédés Propres et Environnement, Europôle de l'Arbois, Bâtiment Laennec, BP 80, 13545 Aix-en-Provence Cedex 4, France
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Abstract

Les propriétés des fluides supercritiques sont à mi-chemin entre celles des gaz et celles des liquides ; ces propriétés peuvent en outre être considérablement modifiées par simple variation de la pression et/ou de la température. Cette spécificité est à l'origine de nombreuses applications dans lesquelles les fluides supercritiques se présentent comme des substituts de choix aux solvants organiques traditionnels. L'extraction et la purification sont les premières applications à avoir été développées ; la facilité de séparation du solvant et des solutés extraits par simple dépressurisation constitue l'atout majeur de cette méthode. Plus récemment d'autres applications très prometteuses ont émergé. Elles concernent les domaines de la réaction chimique, de la chromatographie et du traitement du solide.Initialement freinées dans leur développement par des coûts d'investissement supérieurs à ceux des procédés traditionnels, ces techniques supercritiques connaissent depuis peu un net regain d'intérêt, lié entre autres aux contraintes environnementales de plus en plus fortes pesant sur l'utilisation des solvants traditionnels.

Keywords

Supercritical fluidsindustrial applicationsmicronizationcomposite particlesFluides supercritiquesapplications industriellesmicronisationparticules composites
Type
Research Article
Information
Mechanics & Industry , Volume 5 , Issue 5 , September 2004 , pp. 541 - 551
Copyright
© AFM, EDP Sciences, 2004

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References

J.B. Hannay, J. Hogarth, On the solubility of solids in gases, Proceedings of the Royal Society of London, 29, 1879, p. 324
K. Zosel, Process for recovering caffeine, U.S. Patent 3 806 619, Avril 1974
K. Zosel, Process for the direct decaffeination of aqueous coffee extract solutions, U.S. Patent 4 348 422 (Sep. 7, 1982)
E.B. Auerbach, Process for treating, separating, and purifying oils, U.S. Patent 1 805 751 (1931)
V. Krukonis, G. Brunner, M. Perrut, Industrial operations with supercritical fluids : current processes and perspectives of the future. Proceedings of the 3rd Intenational Symposium on Supercritical Fluids, Strasbourg, 1994, vol. 1, p. l
P. Pellerin, Comparing extraction by traditional solvents with supercritical extraction: An economic and environmental standpoint, Proceedings of the 6th International Symposium on Supercritical fluids, Versailles, 2003, pp. 11–15
M. Perrut, Supercritical fluid applications: Industrial developments and economic issues, in Eng. Chem. Res. 39 (2000) 4531–4535
Gamse, T., Rogler, I., Marr, R., Use of supercritical fluids for different processes including new developments: A review, Chem. Eng. and Proc. 39 (2000) 19–28
K. Udaya Sankar, Supercritical fluid carbon dioxide technology for extraction of spices and other high value bio-active compounds, dans Supercritical Fluid Processing of Food and Biomaterials, Chapman and Hall, 1994, pp. 155–167
A. Castera, Production of low-fat and low-cholesterol foodstuffs or biological products by supercritical CO2 extraction: processes and applications, dans Supercritical Fluid Processing of Food and Biomaterials, Chapman and Hall, 1994, pp. 187–201
S. Vijayan, D.P. Byskal, L.P. Buckley, Separation of oil from fried chips by a supercritical extraction process: An overview of bench-scale experience and process economics, dans Supercritical Fluid Processing of Food and Biomaterials, Chapman and Hall, 1994, pp. 75–92
U. Nguyen, D.A. Evans, G. Frakman, Natural antioxidants produced by supercritical extraction, dans Supercritical Fluid Processing of Food and Biomaterials, Chapman and Hall, 1994, pp. 103–113
G.B. Guarise, A. Bertucco, P. Pallado, Carbon dioxide as a supercritical solvent in fatty acid refining: Theory and practice, dans Supercritical Fluid Processing of Food and Biomaterials, Chapman and Hall, 1994, pp. 27–43
Brunner, G., Peter, S., On the solubility of glycerides and fatty acids in compressed gases in presence of an entrainer, Sep. Sci. and Tech. 17 (1982) 199–214 CrossRef
Gearhart, J.A., Garwin, L., ROSE process improves resid feed, Hydrocarbon Process. 55 (1976) 125–128
Wilson, R.E., Keith, P.C., Haylett, R.E., 1936. Liquid propane: Use in dewaxing, deasphalting, and refining heavy oils, Ind. Eng. Chem. 28 (1936) 1065 CrossRef
M. Mc Hugh, V. Krukonis, Supercritical extraction, Butterworth–Heinemann, 1994, pp. 189–284
L. van Ginneken, R. van de Leest, L. Willems, K. Elst, H. Weyten, Synthesis, characterisation and applications of silica aerogels, Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 2003, pp. 1971–1976
Fages, J., Marty, A., Delga, C., Condoret, J.S., Combes, D., Frayssinet, P., Biomaterials 15 (1994) 650–656 CrossRef
Fages, J., Jean, E., Frayssinet, P., Mathon, D., Poirier, B., Autefage, A., Larzul, D., Bone allografts and supercritical Processing$;$ effects on osteointegration and viral safety, J. Supercritical Fluids 13 (1998) 351–356 CrossRef
Chartier, T., Bordet, F., Delhomme, E., Baumard, J.F., Extraction of binders from green ceramic bodies by supercritical fluids: Influence of porosity, J. Europ. Ceramic Soc. 22 (2002) 1403–1409 CrossRef
Lansberry, D., Council, T.G., Supercritical recirculating system for a precision inertial instrument cleaner, J. Cleaner Production 4 (1996) 133–134
H. Wang, M. Hirahara, M. Goto, T. Tsutomu Hirose, Extraction of flame retardants from electronic printed circuit board by supercritical carbon dioxide, J. Supercritical Fluids (2003), sous presse
Hawthorne, S.B., Yang, Y., Miller, D.J.,, Extraction of organic pollutants from environmental solids with sub and supercritical, Water. Anal. Chem. 66 (1994) 2912–2920 CrossRef
Ken Li, K., Michael La, M.ndriault, M. Merv Fingas, M. Maria Ljompart, Accelerated solvent extraction (ASE) of environmental organic compounds in soils using a modified supercritical fluid extractor, J. Hazardous Materials 102 (2003) 93–104
John, R., Dean, J.R., Guohua Xiong, G., Extraction of organic pollutants from environmental matrices: Selection of extraction technique, Trends in Analytical Chemistry 19 (2000) 553–564
E. Lack, T. Gamse, R. Marre, Separation operations and equipment, dans High Pressure Process Technology: Fundamentals and Applications, Elsevier, 2001, pp. 351–402
K.W. Hutchenson, Organic chemical reactions and catalysis in supercritical fluid media, dans Supercritical Fluid Technology in Materials Science and Engineering, M. Dekker (ed.), 2002, 87–188
M. Härröd, S. van den Hark, A. Holmqvist, P. Moller, Hydrogenation at supercritical single phase conditions, Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 2003, pp. 1097–1102
Aymonier, C., Beslin, C., Jolivalt, C., Cansell, F., Hydrothermal oxidation of a nitrogen-containinig compound: The funuron, J. Supercritical Fluids 17 (2000) 45–54 CrossRef
Meyer, J.C., Marone, P.A., Tester, J.W., Acetic acid oxidation and hydrolysis in supercritical water, AIChEJ. 41 (1995) 2108–2121 CrossRef
Shanableh, A., Shinuzu, Y., Treatment of sewage sludge using hydrothermal oxidation technology application challenges, Water Sci. Technol. 41 (2000) 84–92
Fauvel, E., Joussot-Dubien, C., Pomier, E., Guichardon, P., Charbit, G., Charbit, F., Sarrade, S., Modeling of a porous reactor for supercritical water oxidation by a residence time distribution study, Ind. Eng. Chem. Res. 42 (2003) 2122–2130 CrossRef
E. Fauvel, C. Joussot-Dubien, P. Guichardon, G. Charbit, F. Charbit, S. Sarrade, A double-wall reactor for hydrothermal oxidation with supercritical water flow across the inner porous tube, J. Supercritical Fluids (2003), sous presse
F. Graser, G. Wickenhaeuser, Conditioning of finely divided crude organic pigments. US Patent 4 451 654 (1982)
Gallagher, P.M., Coffey, M.P., Krukonis, V.J., Klasutis, N., Gas antisolvent recrystallization: New process to recrystallize compounds insoluble in supercritical fluids dans Supercritical Fluid Science and Technology, ACS Symp. Ser. 406 (1989) 334–354 CrossRef
S. Iversen, T. Tommy Larsen, O. Ole Henriksen, K. Felsvang, The world's first commercial supercritical wood treatment plant, Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 2003, pp. 445–450
Guneya, O., Akgerman, A., Synthesis of controlled-release products in supercritical medium AIChE J. 48 (2002) 856–866
P. Alessi, A. Cortesi, I. Kikic, Effect of operating parameters on the impregnation of polymers with drugs, Proceedings of the 5th Meeting on Supercritical Fluids, Nice, 1998, pp. 373–378
C. Magnan, C. Bazan, F. Charbit, J. Joachim, G. Charbit, Impregnation of porous supports with active substances by means of supercritical fluids, dans High Pressure Chemical Engineering, P.R. Von Rohr, C. Trepp (ed.), 1996, pp. 509–514
W. Majewski, M. Perrut, On-line direct impregnation of natural extracts, Proceedings of the 7th Meeting on Supercritical Fluids, Antibes, 2000, pp. 779–780
De Giorgi, M.R., Cadoni, E., Maricca, D., Piras, A., Dyeing polyester fibres with disperse dyes in supercritical CO2, Dyes and Pigments 45 (2000) 75–79 CrossRef
Ngo, T., Liotta, C.L., Eckert, C.A., Kazarian, S.G., Supercritical fluid impregnation of different azo-dyes into polymer: in situ UV/Vis spectroscopic study, J. Supercritical Fluids 27 (2003) 215–222 CrossRef
E. Bach, E. Cleve, E. Schollmeyer, Treatment of textiles in supercritical CO2: New results, Proceedings of the 7th Meeting on Supercritical Fluids, Antibes, 2000, pp. 385–388
J.J. Shim, J.H. Choi, J.H. Ju, B.K. Son, J.M. Ahn, B.H. Kim, K.S. Kim, Dyeing of polyester, aramid, and polypropylene fibers in supercritical CO2, Proceedings of the 6th International Symposium on Supercritical fluids, Versailles, 2003, pp. 2101–2106
Tavana, A., Randolph, A.D., Manipulating solids CSD in a supercritical fluid crystallizer: CO2 – benzoïc acid, AIChE J. 35 (1989) 1625–1630 CrossRef
C.J. Chang, A.D. Randolph, Precipitation of micronsize organic particles from supercritical fluids, AIChE J. 35 (989) 1876–1882
Helfegen, B., Türk, M., Schaber, K., Theoretical and experimental investigation of the micronization of organic solids by rapid expansion of supercritical solutions, Powder Technology 110 (2000) 22–28 CrossRef
G. Pace, K. Mishra, B. Henriksen, V.J. Krukonis, A. Godinas, Processes to generate submicron particles of water – insoluble compounds, International Patent WO 99/65469, 1999
Reverchon, E., Della Porta, G., Taddeo, R., Pallado, P., Stassi, A., Solubility and micronization of griseofulvin in supercritical CHF3, Industrial and Engineering Chemistry Research 34 (1995) 4087–4091 CrossRef
Larson, K.A., King, M.L., Evaluation of Supercritical Fluid Extraction in the Pharmaceutical Industry, Biotechnology Progress 2 (1986) 73–82 CrossRef
Kim, J., Paxton, T., Tomasko, D., Microencapsulation of naproxen using rapid expansion of supercritical solutions, Biotechnology Progress 12 (1996) 650–661 CrossRef
M.P. Coffey, V. Krukonis, Supercritical Fluid Nucleation, An improved Ultrafine Particle Formation Process, Phasex Corp., Final report to NSF, 1988
Reverchon, E., Donsi, G., Gorgoglione, D., Salicylic acid solubilization in supercritical CO2 and its micronization by RESS, J. Supercritical Fluids 6 (1993) 241–248 CrossRef
F.E. Wubbolts, C. Kerach, G.M. Van Rosmalen, Semi batch precipitation of acetaminophen from ethanol with liquid carbon dioxide at a constant pressure, Proceedings of the 5th Meeting on Supercritical Fluids, Nice, 1, 1998, pp. 249–255
Moneghini, M., Kikic, I., Voinovich, D., Perissutti, B., Filipovic-Grcic J., Processing of carbamazepine-PEG 4000 solid dispersions with supercritical carbon dioxide: preparation, characterization, and in vitro dissolution, Int. J. Pharmaceutics 222 (2001) 129–138 CrossRef
Yeo, S.D., Kim, M.S., Lee, J.C., Recrystallization of sulfothiazole and chlorpropamide using the supercritical fluid antisolvent process, J. Supercritical Fluids 25 (2003) 143–154 CrossRef
Yeo, S.D., Lim, G., Debenedetti P.G., Bernstein H., Formation of microparticulate protein powders using a supercritical fluid antisolvent, Biotechnology and Bioengineering 41 (1993) 341–346 CrossRef
Thiering, R., Dehghani, D., Dillow, A., Foster, N.R., The influence of operating conditions on the dense gas precipitation of model proteins, J. Chem. Tech. Biotech. 75 (2000) 29–41 3.0.CO;2-E>CrossRef
Kitamura, M., Yamamoto, M., Yoshinaga, Y., Masuoka, H., Crystal size control of sulfathiazole using high pressure carbon dioxide, J. Crystal Growth 178 (1997) 378–386 CrossRef
Reverchon, E., De Marco, I., Caputo, C., Della Porta, G., Pilot scale micronization of amoxicillin by supercritical antisolvent precipitation, J. Supercritical Fluids 26 (2003) 1–7 CrossRef
Reverchon, E., Della Porta, G., Production of antibiotic micro- and nano-particles by supercritical antisolvent precipitation, Powder Technology 106 (1999) 23–29 CrossRef
S. Said, R.A. Rajewski, V. Stella, B. Subramanian, World Patent WO 9 731 691, 1997
Sze Tu, L., Dehghani, F., Foster, N.R., Micronisation and microencapsulation of pharmaceuticals using a carbon dioxide antisolvent, Powder Technology 126 (2002) 134–149
Badens, E., Magnan, C., Charbit, G., Microparticles of soy lecithin formed by supercritical processes, Biotechnology and Bioengineering 72 (2001) 194–204 3.0.CO;2-L>CrossRef
Magnan, C., Badens, E., Commenges, N., Charbit, G., Soy lecithin micronization by precipitation with a compressed fluid antisolvent influence of process parameters, J. Supercritical Fluids 19 (2000) 69–77 CrossRef
Reverchon, E., De Marco, I., Della Porta, G., Rifampicin microparticles production by supercritical antisolvent precipitation, Int. J. Pharmaceutics 243 (2002) 83–91. CrossRef
M. Hanna, P. York, Particle formation method and their products, US Patent 2002/0073511 A1, 2002
M. Hanna, P. York, Method and apparatus for the formation of particles. European Patent WO 99/59710, 1999
Ghaderi, R., Artursson, P., Carlfors, J., A new method for preparing biodegradable microparticles and entrapment of hydrocortisone in DL-PLG microparticles using supercritical fluid, Europ. J. Pharmaceutical Sciences 10 (2000) 1–9 CrossRef
R. Sloan, M.E. Hollowood, G.O. Humphreys, W. Ashraf, P. York, Supercritical Fluid Processing: preparation of stable protein particles. Proceedings of the 5th Meeting on Supercritical Fluids, Nice, 1998, pp. 301–306
M.H. Hanna, P. York, Method and apparatus for the formulation of particles. WO 96/00 610, 1996
M.H. Hanna, P. York, Method and apparatus for the formation of particles, European Patent WO 98/36825, 1998
Jung, J., Perrut, M., Particle design using supercritical fluids: Literature and patent survey, J. Supercritical Fluids 20 (2001) 179–219 CrossRef
G. Charbit, E. Badens, O. Boutin, Methods of particle production, dans Drug Delivery and Supercritical Fluid Technology, Marcel Dekker (ed.), sous presse
A. Bertucco, P. Pallado, L. Benedetti, Formation of biocompatible polymer microspheres for controlled drug delivery by a supercritical antisolvent technique, Proceedings of the 3rd Symposium on High Pressure Chemical Engineering, Zürich, 1996, pp. 217–222
P. Pallado, P.L. Benedetti, L. Callegaro, Nanospheres comprising a biocompatible polysaccharide, US Patent 6 214 384, 2001
Elvassore, N., Bertucco, A., Caliceti, P., Production of insulin-Ioaded poly(ethylene gIycol)/poly(lactide) (PEG/PLA) nanoparticles by gas antisolvent techniques, J. Pharmaceutical Sciences 90 (2001) 1628–1636 CrossRef
Corrigan, O.I., Crean, A.M., Comparative physicochemical properties of hydrocorisone-PVP composites prepared using supercritical carbon dioxide by the GAS anti-solvent recrystallization process, by coprecipitation and spray drying, Int. J. Pharmaceutics 245 (2002) 75–82 CrossRef
Bitz, C., Doelker, E., Influence of the preparation method on residual solvents in biodegradable microspheres, Int. J. Pharmaceutics 131 (1996) 171–181 CrossRef
Taki, S., Badens, E., Charbit, G., Controlled release system formed by supercritical anti-solvent coprecipitation of a herbicide and a biodegradable polymer, J. Supercritical Fluids 21 (2001) 61–70 CrossRef
H. Lochard, E. Rodier, M. Sauceau, J.J. Letourneau, B. Freiss, C. Joussot-Dubien, J. Fages, A three step supercritical process to improve the dissolution rate of Eflucimibe, Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 2003, pp. 1659–1664
Perrut, M., Supercritical fluids applications: Industrial developments and economic issues, Ind. Eng. Chem. 39 (2000) 4531–4535 CrossRef