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Geochemical barriers to elemental migration in sulfide-rich tailings: three case studies from Western Siberia

Published online by Cambridge University Press:  05 July 2018

A. A. Bogush ,
O. G. Galkova  and
N. V. Ishuk
A. A. Bogush*
Affiliation:
Institute of Geology and Mineralogy of the Siberian Branch of the Russian Academy of Sciences (IGM SB RAS), pr. Koptyuga 3, Novosibirsk 630090, Russia
O. G. Galkova
Affiliation:
Institute of Geology and Mineralogy of the Siberian Branch of the Russian Academy of Sciences (IGM SB RAS), pr. Koptyuga 3, Novosibirsk 630090, Russia
N. V. Ishuk
Affiliation:
Institute of Geology and Mineralogy of the Siberian Branch of the Russian Academy of Sciences (IGM SB RAS), pr. Koptyuga 3, Novosibirsk 630090, Russia
*
*E-mail: annakhol@gmail.com
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Abstract

This study describes geochemical barriers that have developed at three different localities in sulfiderich tailings in the Kemerovo region of Western Siberia, Russia. Iron oxyhydroxides, gypsum, malachite, chalcanthite, goslarite, bianchite, gunningite and copper and zinc chloridescrystallized in the sequence specified at an evaporative barrier around glassy slag produced by the Belovo zinc processing plant. A complex cemented barrier that has developed within the old Salair sulfide tailings contains two well defined layers: an upper layer containing Fe(III) mineralsand gypsum as cements in which Pb, As, Mo, Ni and Co have been deposited; and (2) a lower calcite- and gypsum-bearing layer, in which phases containing Zn, Cd and Cu have been deposited. A complex organic-mineral barrier below the Ursk sulfide tailings consists of peaty organic matter, clayminerals and iron oxyhydroxides cemented by gypsum. Elements that have leached from the tailings are present in this barrier in a variety of different forms: Ca and Mn are present as water-soluble species; Cu, Fe and Zn are present as species produced by interaction with organic matter viaion-exchange, metal humate formation and cation bridging in organic-mineral complexes; Pb and As are co-precipitated with and/or adsorbed onto iron oxyhydroxides; gold has been deposited as minute particles of native metal. The mechanisms for the formation of the different geochemical barriersare discussed.

Keywords

geochemical barriersulfide tailingselement migrationheavy metal species
Type
Research Article
Information
Mineralogical Magazine , Volume 76 , Issue 7 , December 2012 , pp. 2693 - 2707
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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References

Alekseenko, V.A. (2000) Ecological Geochemistry. LOGOS, Moscow, 627 pp., [in Russian]. Alekseenko, V.A. and Alekseenko, L.P. (2003) Geochemical Barriers. LOGOS, Moscow, 144 pp., [in Russian].Google Scholar
Ball, J.W. and Nordstrom, D.K. (1991) User’s manual for WATERQ4F, with a revised thermodynamic data base and test cases for calculating the speciation of major, trace, and redox elements in natural waters. Menlo Park, California, USA, 189 pp.Google Scholar
Benedetti, M. and Boulegue, J. (1991) Mechanism of gold transfer and deposition in a supergene environment. Geochimica et Cosmochimica Acta, 55, 1539–1547.CrossRefGoogle Scholar
Blair, R.D., Cherry, J.A., Lim, T.P. and Vivyurka, A.J. (1980) Groundwater monitoring and contaminant occurrence at an abandoned tailings area, Eliot Lake, Ontario. Pp. 911–944.in: First International Conference on Uranium Mine Waste Disposal (C.O. Brawner, editor). Society of Mining Engineers of Aime, British Columbia, Canada.Google Scholar
Blowes, D.W. and Jambor, J.L. (1990a) The pore-water geochemistry and the mineralogy of the vadose zone of sulfide tailings, Waite Amulet, Quebec, Canada. Applied Geochemistry, 5, 327–346.CrossRefGoogle Scholar
Blowes, D.W. and Jambor, J.L. (1990b) The importance of cemented layers in inactive sulfide mine tailings. Geochimica et Cosmochimica Acta, 55, 965–978.CrossRefGoogle Scholar
Bogush, A.A. and Androsova, N.V. (2007) Ecogeochemical state of the S. Talmovaya– Talmovaya–S. Bachat-Bachat-Inya river system (Kemerovo region). Ecology of Industrial Production, 1, 8–16.Google Scholar
Bogush, A.A., Kropacheva, M.Yu., Chuguevsky, A.B., Maskenskaya, O.M., Nadelaeva, Yu., Scherbakova, I.N. and Pirogova, A.O. (2007a) Speciation of Heavy Metal and Radionuclides in Natural and Contaminated Systems. Lavrentev Project Report, Novosibirsk, Russia, 78 pp., [in Russian].Google Scholar
Bogush, A.A. and Lazareva, E.V. (2011) Behaviour of heavy metals in sulfide mine tailings and bottom sediment (Salair, Kemerovo region, Russia). Environmental Earth Sciences, 64, 1293–1302.CrossRefGoogle Scholar
Bogush, A.A., Letov, S.V. and Miroshnichenko, L.V. (2007b) Distribution and speciation of heavy metals in drainage water and sludge pond of the Belovo zinc plant (Kemerovo region). Geoecology, 5, 413–420.Google Scholar
Bogush, A.A., Moroz, T.N., Galkova, O.G. and Maskenskaya, O.M. (2007c) Application of natural material for drainage water treatment. Ecology of Industrial Production, 2, 63–69.Google Scholar
Bogush, A.A. and Voronin, V.G. (2011) Application of a peat-humic agent for treatment of acid mine drainage. Mine Water and the Environment, 30, 185–190.CrossRefGoogle Scholar
Bolgov, G.P. (1937) Sulfides of Salair: Urskaya Group of Polymetallic Deposits. Tomsk Industrial Institute, Tomsk, Russia, 51 pp., [in Russian].Google Scholar
Borman, R.S. and Watson, D.M. (1976) Chemical processes in bounded sulfide tailings dumps and environmental implication for Northeastern New Brunswick. Bulletin of the Canadian Institute of Mining and Metallurgy, 69, 86–96.Google Scholar
Da Rosa, C.D., Lyon, J.S. and Hocker, P.M. (1997) Golden Dreams, Poisoned Streams. Mineral Policy Center, Washington DC, 269 pp.Google Scholar
De Vos, K.J., Blowes, D.W., Robertson, W.D. and Greenhouse J.P. (1995) Delineation and evaluation of a plume of tailings derived water, Copper Cliff, Ontario. Pp. 673–682.in: Proceedings of a Conference on Mining and the Environment, Sudbury, Ontario. Volume 2.Google Scholar
Fanfani, L., Zuddas, P. and Chessa, A. (1997) Heavy metals speciation analysis as a tool for studying mine tailings weathering. Journal of Geochemical Exploration, 58, 241–248.CrossRefGoogle Scholar
Hudson-Edwards, K.A., Jamieson, H.E. and Lottermoser, B.G. (2011) Mine wastes: past, present, future. Elements, 7, 375–380.CrossRefGoogle Scholar
Jambor, J.L. and Blowes, D.W. (editors) (1994) Environmental Geochemistry of Sulfide Mine Wastes. Mineral Association of Canada Short Course Series, 22. Mineral Association of Canada, Québec, Canada, 438 pp.Google Scholar
Jambor, J.L., Blowes, D.W. and Ritchie, A.I.M. (editors) (2003) Environmental Aspects of Mine Wastes. Mineral Association of Canada Short Course Series, 31. Mineral Association of Canada, Québec, Canada, 436 pp.Google Scholar
Jamieson, H.E. (2011) Geochemistry and mineralogy of solid mine waste: essential knowledge for predicting environmental impact. Elements, 7, 381–386.CrossRefGoogle Scholar
Jamieson, H.E., Robinson, C., Alpers, C.N., McCleskey, R.B., Nordstrom, D.K. and Peterson, R.C. (2005) Major and trace element composition of copiapitegroup minerals and coexisting water from Richmond mine, Iron Mountain, California. Chemical Geology, 215, 387–405.CrossRefGoogle Scholar
Karpov, I.K. (1981) Physicochemical Computer Modelling in Geology. Nauka, Novosibirsk, Russia, 247 pp. [in Russian].Google Scholar
Karpov, I.K., Chudnenko, K.V. and Bychinskiy, D.F. (1997) User’s Manual for SELECTOR-C Software. Irkutsk, Russia, 105 pp. [in Russian].Google Scholar
Labazin, G.S. (1940) Structural and morphological features of polymetallic deposits of Salair mines and geological conditions of their finding. Nonferrous Metals, 3, 14–20.Google Scholar
Lapuhov, A.S. (1975) Zoning of Sulfur-Polymetallic Deposits. Nauka, Novosibirsk, Russia, 264 pp.Google Scholar
Ledoux, R.L. and White, J.L. (1966) Infrared studies of hydrogen bonding interaction between kaolinite surfaces and intercalated potassium acetate, hydrazine, formamide and urea. Journal of Colloid and Interface Science, 21, 127–152.CrossRefGoogle Scholar
Lotter moser, B.G. (2007) Mine Wastes : Characterization, Treatment and Environmental Impacts, second Edition. Springer, Berlin, 277 pp.Google Scholar
Lucas, S.N. (2002) Manufacturing of and the performance of an integrally-formed, polypropylene geosynthetic clay barrier. Pp. 227–232.in: Clay Geosynthetic Barriers (H. Zanzinger, R.M. Koerner and E. Gartung, editors). A.A Balkema, The Netherlands.Google Scholar
Lundgren, T. (2001) The dynamics of oxygen transport into soil covered mining waste deposits in Sweden. Journal of Geochemical Exploration, 74, 163–173.CrossRefGoogle Scholar
McGregor, R.G. and Blowes, D.W. (2002) The physical, chemical and mineralogical properties of three cemented layers within sulfide-bearing mine tailings. Journal of Geochemical Exploration, 76, 195–207.CrossRefGoogle Scholar
Nordstrom, D.K. (1982) Aqueous pyrite oxidation and the consequence formation of secondary minerals. Pp. 37–56.in: Acid Sulfate Weathering (J.A. Kittrick, D.S. Fanning and L.R. Hossner, editors). Special Publication, 10. Soil Science Society of America, Madison, Wisconsin, USA.Google Scholar
Nordstrom, D.K. (2011) Mine waters: acidic to circumneutral. Elements, 7, 393–398.CrossRefGoogle Scholar
Orlov, D.S. (1990) Humic Acids of Soil and General Theory of Ulmification. Moscow State University, Moscow, 325 pp., [in Russian].Google Scholar
Orlov, D.S. and Osipova, N.N. (1988) Infra-red spectrums of soil and soil components. Moscow State University, Moscow, 101 pp., [in Russian].Google Scholar
Panin, M.S. (2002) Chemical Ecology. Semipalatinsk, Kazakhstan, 450 pp., [in Russian].Google Scholar
Perel’man, A.I. (1961) Landscape Geochemistry. Geographgiz, Moscow, 495 pp., [in Russian].Google Scholar
Perel’man, A.I. (1979) Geochemistry. Visshaya shkola, Moscow, 380 pp., [in Russian].Google Scholar
Perel’man, A.I. (1986) Geochemical barriers: theory and practical applications. Applied Geochemistry, 1, 669–680.CrossRefGoogle Scholar
Perel’man, A.I. and Kasimov, N.S. (1999) Landscape Geochemistry. Moscow State University, Moscow, 610 pp., [in Russian].Google Scholar
Perminova, I.V. (2008) Humic substances - a challenge to chemists XXI century. Chemistry and Life, 1, 50–56.Google Scholar
Robertson, A.M. and Broughton, L.M. (1992) Reliability of acid rock drainage testing. Pp. 1–21.in: Workshop on U.S. EPA specifications for tests to predict acid generation from non-coal mining wastes. Las Vegas, Nevada, USA.Google Scholar
Scherbakova, I.N., Lazareva, E.V., Gustaytis, M.A. and Zhmodik, S.M. (2011) Re-deposition of Au on peat from acid mine drainage. Pp. 2119–2121.in: Proceedings of the International Conference Modern state of the Earth. MSU, [in Russian].Google Scholar
Sidenko, N.V., Giere, R., Bortnikova, S.B., Cottard, F. and Pal’chik N.A. (2001) Mobility of heavy metals in self-burning waste heaps of the zinc smelting plant in Belovo (Kemerovo region, Russia). Journal of Geochemical Exploration, 74, 109–125.CrossRefGoogle Scholar
Seal, R.R. and Hammarstrom, J.M. (2003) Geoenvironmental models of mineral deposits: examples from massive sulfide. Pp. 11–50.in: Environmental Aspects of Mine Wastes (J.L. Jambor, D.W. Blowes and A.I.M. Ritchie, editors). Mineral Association of Canada Short Course Series, 31. Mineral Association of Canada, Québec, Canada, 436 pp.Google Scholar
Stumm, W. and Morgan, J.J. (1981) Aquatic Chemistry, First Edition. John Wiley & Sons, New York, 780 pp.Google Scholar
Tessier, A., Cambell, P.G. and Bisson, M. (1979) Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry, 51, 844–851.CrossRefGoogle Scholar
Williams, R.E. (1975) Waste Production and Disposal in Mining, Milling and Metallurgical Industries. Miller Freeman Publications, San Francisco, USA, 489 pp.Google Scholar
Zijlstra, J.J., Dess, R., Peretti, R. and Zucca, A. (2010) Treatment of percolate from metal sulfide mine tailings with a permeable reactive barrier of transformed red mud. Water Environment Research, 82, 319–27.CrossRefGoogle ScholarPubMed