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Scapolite pegmatite from the Minas fault, Nova Scotia: tangible manifestation of Carboniferous, evaporite-derived hydrothermal fluids in the western Cobequid highlands?

Published online by Cambridge University Press:  05 July 2018

J. V. Owen
Affiliation:
Department of Geology, Saint Mary's University, Halifax, N.S. Canada B3H 3C3
J. D. Greenough
Affiliation:
Department of Geological Sciences, Okanagan University College, 3333 College Way, Kelowna, B.C., Canada V1V 1V7

Abstract

Pegmatite cutting chlorite schist in the Minas fault at McKay Head, Nova Scotia, consists of Cl-rich (2.7–3.8 wt.% Cl) marialitic scapolite (EqAn21–32) with interstitial, apparently primary analcite, hematite and rutile, and later (including vug-lining) analcite, pyrite, chlorite, titanite and calcite, and cross-cutting epidote veins. Some of the latter phases might have crystallized from residual pegmatitic fluids. Unlike many other primary scapolite-bearing igneous rocks, the McKay Head occurrence has compositional affinities with mafic (rather than felsic) systems: it is enriched in transition metals (e.g. Cr≤53 ppm), and has very low LILE concentrations (e.g. Rb<10 ppm; U<1 ppm; Th<2 ppm; Ba<20 ppm) and Rb/Sr ratios (~0.05). The presence of interstitial rutile and hematite rather than ilmenite indicates that the pegmatitic fluid was oxygenated late (T~400°C) in its crystallization history.

The pegmatite is interpreted to be related to highly sodic hydrothermal solutions derived from (or affected by) early Carboniferous evaporites of the Windsor or Horton groups. Compositionally-similar fluids, perhaps also related to an evaporite source, may be responsible for a regional, early Carboniferous Na-metasomatic event that altered a suite of alkaline granitoid intrusions shortly after their emplacement.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1999

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References

Aumento, F. (1966) Zeolite minerals, Nova Scotia. In Geology of Parts of the Atlantic Provinces. Geol. Assoc. Canad./Mineral. Assoc. Canad. Guidebook, 71–7.Google Scholar
Barr, S.M., Grammatikopoulos, A.L. and Dunning, G.R. 1994. Early Carboniferous gabbro and basalt in the St. Peters area, southern Cape Breton Island, Nova Scotia. Atlan. Geol., 30, 247–58.Google Scholar
Berman, R.G. (1991) Thermobarometry using multi-equilibrium calculations: a new technique, with petrological applications. Canad. Mineral., 29, 833–55.Google Scholar
Berman, R.G. and Brown, T.H. (1988) A general method for thermobarometric calculations with a revised garnet solution model and geologic applications. Geol. Soc. Amer., Abstracts with Program, 20, A98.Google Scholar
Boivin, P. and Camus, G. (1981) Igneous scapolite-bearing associations in the Chaine des Puys, Massif Central (France) and Atakor (Hoggar, Algeria). Contrib. Mineral. Petrol., 77, 365–75.CrossRefGoogle Scholar
Brown, T.H., Berman, R.G. and Perkins, E.H. (1988) GE0-CALC Software package for calculation and display of pressure- temperature-composition phase diagrams using an IBM or compatible personal computer. Computers Geosci., 14, 279–89.CrossRefGoogle Scholar
Carter, D.C. and Pickerill, R.K. (1985) Algal swamp, marginal and shallow evaporitic lacustrine lithofacies from the later Devonian-early Carboniferous Albert Formation, southeastern New Brunswick. Maritime Sed. Atlan. Geol., 21, 6986.Google Scholar
Doig, R., Murphy, J.B., Pe-Piper, G. and Piper, D.J.W. (1996) U-Pb geochronology of Late Palaeozoic plutons, Cobequid highlands, Nova Scotia, Canada: evidence for Late Devonian emplacement adjacent to the Meguma-Avalon terrane boundary in the Canadian Appalachians. Geol. J., 31, 179–88.3.0.CO;2-U>CrossRefGoogle Scholar
Dostal, J. and Owen, J.V. (1998) Cretaceous alkaline lamprophyres from northeastern Czech Republic: geochemistry and petrogenesis. Geol. Rund., 87, 6777.CrossRefGoogle Scholar
Gibbons, W. and Murphy, J.B. (1995) Mylonitic mafic granulite in fault megabreccia at Clarke Head, Nova Scotia: A sample of Avalonian lower crust? Geol. Mag., 132, 8190.CrossRefGoogle Scholar
Gibbons, W., Doig, R., Gordon, T., Murphy, B., Reynolds, P., and White, J.C. (1996) Mylonite to megabreccia: Tracing fault events within a transcurrent terrane boundary in Nova Scotia, Canada. Geology, 24, 411–4.2.3.CO;2>CrossRefGoogle Scholar
Goff, F., Arney, B.H. and Eddy, A.C. (1982) Scapolite phenocrysts in a latite dome, northwest Arizona, U.S.A. Earth Planet. Sci. Lett., 60, 8692.CrossRefGoogle Scholar
Hodych, J.P. and Dunning, G.R. (1992) Did the Manicouagan impact trigger end-of-Triassic mass extinction? Geology, 20, 51–4.2.3.CO;2>CrossRefGoogle Scholar
Howie, R.D. (1988) Upper Paleozoic evaporites of southeastern Canada. Geol. Surv. Can. Bull., 380, 120 pp.Google Scholar
Mawer, C.K. and White, J.C. (1987) Sense of displacement on the Cobequid-Chedabucto Fault System, Nova Scotia, Canada. Canad. J. Earth Sci., 24, 217–23.CrossRefGoogle Scholar
Mittwede, S.K. (1994) Primary scapolite in a granitic pegmatite, western Cherokee county, South Carolina. Canad. Mineral., 32, 617–22.Google Scholar
Nearing, J.D., Reynolds, P., and Pe-Piper, G. (1997). Devonian-Carboniferous 40Ar/39Ar thermochronology of the Cobequid Highlands, Nova Scotia. Geol. Assoc. Canad./Mineral. Assoc. Canad., programs with abstracts 22, A108.Google Scholar
Orville, P.M. (1975) Stability of scapolite in the system Ab-An-NaCl-CaCO3 at 4 kb and 750°C. Geochim. Cosmochim. Acta, 39, 1091–105.CrossRefGoogle Scholar
Owen, J.V. and Greenough, J.D. (1997) Migmatites from Grenville, Quebec: metamorphic P-T-X conditions in transitional amphibolite/granulite-facies rocks. Lithos, 39, 195208.CrossRefGoogle Scholar
Ravenhurst, C.E., Reynolds, P.H. and Zentilli, M. (1987) Isotopic constraints on the genesis of Zn-Pb mineralization at Gays River, Nova Scotia, Canada. Econ. Geol., 82, 1294–308.CrossRefGoogle Scholar
Shaw, D.M. (1960 a) The geochemistry of scapolite. Part I. Previous work and general mineralogy. J. Petrol., 1, 218–60.CrossRefGoogle Scholar
Shaw, D.M. (1960 b) The geochemistry of scapolite. Part II. Trace elements, petrology, and general geochemistry. J. Petrol., 1, 261–85.Google Scholar
St.Peter, C. (1992) Lithologic facies, seismic facies, and strike-slip setting of the Lower Carboniferous alluvial/fluvial/lacustrine Albert Formation of New Brunswick. N.B. Dept. of Natural Res. and Energy, Mineral Res. Div., Geosci. Rept. 92-2, 145 pp.Google Scholar
St.Peter, C. (1993) Maritime Basin evolution: key geologic and seismic evidence from the Moncton Subbasin of New Brunswick. Atlan. Geol., 29, 233–70.Google Scholar
Stolz, A.J. (1987) Fluid activity in the lower crust and upper mantle: mineralogical evidence bearing on the origin of amphibole and scapolite in ultramafic and mafic granulite xenoliths. Mineral. Mag., 51, 719–32.CrossRefGoogle Scholar
Vanko, D.A. and Bishop, F.C. (1982) Occurrence and origin of marialitic scapolite in the Humboldt lopolith, N.W. Nevada. Contrib. Mineral. Petrol., 81, 277–89.CrossRefGoogle Scholar
Webb, T.C. (1977) Weldon-Gautreau salt-glauberite deposit. New Brunswick Dept. of Natural Res., Open File Report 77-15, 13 pp.Google Scholar