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Assessment of the use of Raman spectroscopy for the determination of amphibole asbestos

Published online by Cambridge University Press:  05 July 2018

C. Rinaudo ,
E. Belluso  and
D. Gastaldi
C. Rinaudo
Affiliation:
Dipartimento di Scienze dell’Ambiente e della Vita, Università del Piemonte Orientale ‘Amedeo Avogadro’, Piazza Ambrosoli 5, 15100 Alessandria, Italy
E. Belluso
Affiliation:
Dipartimento di Scienze Mineralogiche e Petrologiche, Università di Torino, Via Valperga Caluso 35, 10125 Torino, Italy
D. Gastaldi
Affiliation:
Dipartimento di Scienze dell’Ambiente e della Vita, Università del Piemonte Orientale ‘Amedeo Avogadro’, Piazza Ambrosoli 5, 15100 Alessandria, Italy
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Abstract

Raman spectroscopy was assessed for its ability to rapidly identify asbestos phases by submitting the amphiboles anthophyllite, amosite, crocidolite and tremolite to spectroscopic analysis. All the phases were characterized by using XRD, SEM, TEM (CTEM, SAED), AEM and EDS techniques. This study demonstrates that accurate identification of the mineralogical phase can be attained by analysing the position in the Raman spectrum of the bands corresponding to the symmetric stretching modes (vs) and to the antisymmetric stretching modes (vas) of the different Si—O linkages. Raman spectroscopy thus proves to be an effective technique for rapidly distinguishing the different fibrous minerals examined.

Keywords

Raman spectroscopytransmission electron microscopyasbestos
Type
Research Article
Information
Mineralogical Magazine , Volume 68 , Issue 3 , June 2004 , pp. 455 - 465
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

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References

Bard, D., Yarwood, J. and Tylee, B. (1997) Asbestos fibre identification by Raman microspectroscopy. Journal of Raman Spectroscopy, 28, 803–809.3.0.CO;2-7>CrossRefGoogle Scholar
Blaha, J.J. and Rosasco, G.J. (1978) Raman microprobe spectra of individual microcrystals and fibres of talc, tremolite, and related silicate minerals. Analytical Chemistry, 50, 892–896.CrossRefGoogle Scholar
Droop, G.R.T. (1987) A general equation for estimating Fe3+ concentrations in ferromagnesian silicates and oxides from microprobe analysis using stoichiometric criteria. Mineralogical Magazine, 51, 431–435.CrossRefGoogle Scholar
Farmer, V.C. (1974) The Infrared Spectra of Minerals. Monograph 4, Mineralogical Society, London.Google Scholar
Frost, R.L. (1995) Fourier transform Raman spectro- scopy of kaolinite, dickite and halloysite. Clays and Clay Minerals, 43, 191–195.CrossRefGoogle Scholar
Frost, R.L. (1997) The structure of the kaolinite minerals – a FT-Raman study. ClayMinerals, 32, 65–77.CrossRefGoogle Scholar
Frost, R.L. and Kristof, J. (1997) Intercalation of halloysite: a Raman spectroscopic study. Clays and ClayMinerals 45, 551–563.CrossRefGoogle Scholar
Kloprogge, J.T., Frost, R.L. and Rintoul, L. (1999) Single crystal Raman microscopic study of the asbestos mineral chrysotile. Physical Chemistry Chemical Physics, 1, 2559–2564.CrossRefGoogle Scholar
Kloprogge, J.T., Case, M.H. and Frost, R.L. (2001) Raman microscopic study of the Li amphibole holmquistite, from the Mertin Marietta Quarry, Bessemer City, NC, USA. Mineralogical Magazine, 65, 775–785.CrossRefGoogle Scholar
Lazarev, A.N. (1972) Vibrational Spectra and Structure of Silicates. Consultants Bureau, New York and London, p. 1.Google Scholar
Leake, B.E., Woolley, A.R., Arps, C.E.S., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, F.C., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J.A., Maresch, W.V., Nickel, E.H., Rock, N.M.S., Schumacher, J.C., Smith, D.C., Stephenson, N.C.N., Ungaretti, L., Whittaker, E.J.W. and Youzhi, G. (1997) Nomenclature of amphiboles: report of the subcommittee on amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Mineralogical Magazine, 61, 295–321.CrossRefGoogle Scholar
Lewis, I.R., Chaffin, N.C., Gunter, M.E. and Griffiths, P.R. (1996) Vibrational spectroscopic studies of asbestos and comparison of suitability for remote analysis. Spectrochimica Acta A, 52, 315–328.CrossRefGoogle Scholar
Rinaudo, C., Gastaldi, D. and Belluso, E. (2003) Characterization of chrysotile, antigorite and lizardite by FT-Raman Spectroscopy. The Canadian Mineralogist, 41, 883–890.CrossRefGoogle Scholar
Yavuz, F. (1999) A revised program for microprobederived amphibole analyses using the IMA rules. Computers & Geosciences, 25, 909–927.CrossRefGoogle Scholar