Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-10T12:41:49.292Z Has data issue: false hasContentIssue false
  • English
  • Français

Carbonatitic melts in cuboid diamonds from Udachnaya kimberlite pipe (Yakutia): evidence from vibrational spectroscopy

Published online by Cambridge University Press:  05 July 2018

D. A. Zedgenizov ,
H. Kagi ,
V. S. Shatsky  and
N. V. Sobolev
D. A. Zedgenizov*
Affiliation:
Institute of Mineralogy and Petrography of SBRAS, pr. Koptyuga 3, 630090, Novosibirsk, Russia
H. Kagi
Affiliation:
Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo, Tokyo 113-0033, Japan
V. S. Shatsky
Affiliation:
Institute of Mineralogy and Petrography of SBRAS, pr. Koptyuga 3, 630090, Novosibirsk, Russia
N. V. Sobolev
Affiliation:
Institute of Mineralogy and Petrography of SBRAS, pr. Koptyuga 3, 630090, Novosibirsk, Russia
*
*E-mail: zed@uiggm.nsc.ru
Get access Rights & Permissions [Opens in a new window]

Abstract

Micro-inclusions (1 –10 μm) in 55 diamonds of cubic habit from the Udachnaya kimberlite pipe have been studied using vibrational spectroscopy. This has revealed a multiphase assemblage in cuboid diamonds from the Udachnaya kimberlite pipe. This assemblage includes carbonates, olivine, apatite, graphite, water and silicate glasses. The micro-inclusions preserve the high internal pressure and give confidence that the original materials were trapped during growth of the host diamond. The internal pressures, extrapolated to mantle temperatures, lie within the stability field of diamond and the relatively low temperatures are typical for the formation of cuboid diamonds. In contrast to previously reported data for African diamonds, the micro-inclusions in the cuboids from Udachnaya are extremely carbonatitic in composition (H2O/(H2O+CO2) ≈5 –20%) with the observed assemblage of microinclusions similar to some types of carbonatites. The low water and silica content testify that the material in the micro-inclusions of the Udachnaya diamonds was near-solidus carbonatitic melt. Vibrational spectroscopy has provided the evidence of carbonatitic melts in cuboid diamonds.

Keywords

carbonatitic meltdiamondsUdachnaya kimberlite pipevibrational spectroscopyinclusions
Type
Research Article
Information
Mineralogical Magazine , Volume 68 , Issue 1 , February 2004 , pp. 61 - 73
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aines, R.D. and Rossman, G.R. (1984) Water in minerals? A peak in the infrared. Journal of Geophysical Research, 89, 4059–4071.CrossRefGoogle Scholar
Akaishi, M., Kanda, H. and Yamaoka, S. (1990) Synthesis of diamond from graphite-carbonate system under very high temperature and pressure. Journal of Crystal Growth, 104, 578–581.CrossRefGoogle Scholar
Anthony, T.R. (1999) Inclusions in diamonds with solubility changes and phase transformations. Diamond and Related Materials, 8, 78–88.CrossRefGoogle Scholar
Arima, M., Kozai, Yu. and Akaishi, M. (2002) Diamond nucleation and growth by reduction of carbonate melts under high-pressure and high-temperature conditions. Geology, 30, 691–694.2.0.CO;2>CrossRefGoogle Scholar
Baker, M.B. and Wyllie, P.J. (1992) High-pressure apatite solubility in carbonate-rich liquids: Implication for mantle metosomatism. Geochimica et Cosmochimica Acta, 565, 3409–3422.CrossRefGoogle Scholar
Besson, J.M., Pinceaux, J.P. and Anastopoulus, C. (1982) Raman spectra of olivines up to 65 kilobars. Journal of Geophysical Research, 87, 773–775.CrossRefGoogle Scholar
Biellmann, C. and Gillet, Ph. (1992) High-pressure and high-temperature behaviour of calcite, aragonite and dolomite: a Raman spectroscopic study. European Journal of Mineralogy, 4, 389–393.CrossRefGoogle Scholar
Chrenko, R.M., McDonald, R.S. and Darrow, K.A. (1967) Infra-red spectrum of diamond coat. Nature, 214, 474–476.CrossRefGoogle Scholar
Dalton, J.A. and Presnall, D.C. (1998) The continuum of primary carbonatitic-kimberlitic melt compositions in equilibrium with lherzolite: data from the system CaO-MgO-Al2O 3 -SiO2-CO2 at 6 GPa. Journal of Petrology, 39, 1953–1964.Google Scholar
Galimov, E.M. (1991) Isotope fractionation related to kimberlite magmatism and diamond formation. Geochimica et Cosmochimica Acta, 55, 1697–1708.CrossRefGoogle Scholar
Green, D.H. and Wallace, M.E. (1988) Mantle metasomatism by ephemeral carbonatite melts. Nature, 336, 459–462.CrossRefGoogle Scholar
Guthrie, G.D., Veblen, D.R., Navon, O. and Rossman, G.R. (1991) Submicrometer fluid inclusions in turbid-diamond coats. Earth and Planetary Science Letters, 105, 1–12.CrossRefGoogle Scholar
Haggerty, S.E. (1986) Diamond genesis in a multiplyconstrained model. Nature, 320, 34–38.CrossRefGoogle Scholar
Izraeli, E.S., Harris, J.W. and Navon, O. (1999) Raman barometry of diamond formation. Earth and Planetary Science Letters, 173, 351–360.CrossRefGoogle Scholar
Izraeli, E.S., Harris, J.W. and Navon, O. (2001) Brine inclusions in diamonds: a new upper mantle flfluid. Earth and Planetary Science Letters, 187, 323–332.CrossRefGoogle Scholar
Johnson, L.H., Burgess, R. and Turner, G. (1999) Argon and halogen systematics of fluids within coated diamond from Canada. Proceedings of the 7th International Kimberlite Conference, 2, 391–396.Google Scholar
Kagi, H., Takahashi, K. and Masuda, A. (1994) Raman frequencies of graphitic carbon in antarctic ureilites. Proceedings of the NIPR Symposium on Antarctic Meteorites, 7, 252–261.Google Scholar
Kagi, H., Lu, R., Davidson, P., Goncharov, A.F., Mao, H.K. and Hemley, R.J. (2000) Evidence for ice VI as an inclusion in cuboid diamonds from high P-T near infrared spectroscopy. Mineralogical Magazine, 64, 1089–1097.CrossRefGoogle Scholar
Lang, A.R. and Walmsley, J.C. (1983) Apatite inclusions in natural diamond coat. Physics and Chemistry of Minerals, 9, 6–8.CrossRefGoogle Scholar
Lespade, P., Marchand, A., Couzi, M. and Cruege, F. (1984) Characterization de materiaux carbones per microspectrometrie Raman. Carbon, 20, 427–431.CrossRefGoogle Scholar
Litvin, Yu.A. and Zharikov, V.A. (2000) Experimental modeling of diamond genesis: diamond crystallization in multicomponent carbonate-silicate melts at 5–7 GPa and 1200–1570°C. Doklady Earth Sciences, 372, 808–811.Google Scholar
McMillan, P.F. and Hofmeister, A.M. (1988) Infrared and Raman spe ct rosc opy. Pp. 99–159 in: Spectroscopic Methods in Mineralogy and Geology (Hawthorne, F.C., editor). Reviews in Mineralogy, 18, Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
McMillan, P.F. and Wolf, G.H. (1996) Vibrational spectroscopy of silicate liquids. Pp. 245–315 in: Mineral Spectroscopy: a Tribute to Roger G. Burns. Special Publication No. 5, The Geochemical Society, Washington, D.C.Google Scholar
Meyer, H.O.A. (1987) Inclusions in diamond. Pp. 501–522 in: Mantle Xenoliths. John Wiley & Sons, New York.Google Scholar
Navon, O. (1991) Infrared determination of high internal pressures in diamond fluid inclusions, Nature, 353, 746–748.CrossRefGoogle Scholar
Navon, O. (1999) Diamond formation in the Earth's mantle. Proceedings of the 7th International Kimberlite Conference, 2, 546–554.Google Scholar
Navon, O., Hutcheon, I.D., Rossman, G.R. and Wasserburg, G.J. (1988) Mantle-derived fluids in diamond micro-inclusions. Nature, 335, 784–789.CrossRefGoogle Scholar
Orlov, Yu.L. (1977) The Mineralogy of Diamond. John Wiley & Sons, New York, 235 pp.Google Scholar
Pal’yanov, Yu.N., Sokol, A.G., Borzdov, Yu.M., Khokhryakov, A.F. and Sobolev, N.V. (1999) Diamond formation from mantle carbonate fluids. Nature, 400, 417–418.CrossRefGoogle Scholar
Pal’yanov, Yu.N., Sokol, A.G., Borzdov, Yu.M., Khokhryakov, A.F. and Sobolev, N.V. (2002) Diamond formation through carbonate-silicate interaction. American Mineralogist, 87, 1009–1013.CrossRefGoogle Scholar
Rossman, G.R. (1988) Vibrational spectroscopy of hydrous components. Pp. 193–206 in : Spectroscopic Methods in Mineralogy and Geology (Hawthorne, F.C., editor). Reviews in Mineralogy, 18, Mineralogical Society of America, Washington, D.C.Google Scholar
Schrauder, M. and Navon, O. (1994) Hydrous and carbonatitic mantle fluids in. brous diamonds from Jwaneng, Botswana. Geochimica et Cosmochimica Acta, 52, 761–771.CrossRefGoogle Scholar
Sobolev, N.V. (1974) Deep-seated Inclusions in Kimberlites and the Problem of the Composition of the Upper Mantle. Nauka, Novosibirsk, Russia, 246 pp. (in Russian, English translation (1977) Boyd, F.R., editor, American Geophys ical Union, Washington, D.C., 279 pp.).Google Scholar
Sunagawa, I. (1990) Growth and morphology of diamond crystals under stable and metastable conditi ons. Journal of Crystal Growth, 99, 1156–1161.CrossRefGoogle Scholar
Walmsley, J.C. and Lang, A.R. (1992 a) On submicrometre inclusions in diamond coat: crystallography and composition of ankerites and related rhombohedral carbonates. Mineralogical Magazine, 56, 533–543.CrossRefGoogle Scholar
Walmsley, J.C. and Lang, A.R. (1992 b) Oriented biotite inclusi ons in diamond coat. Mineral ogical Magazine, 56, 108–111.CrossRefGoogle Scholar
Wang, S.Y., Sharma, S.K. and Cooney, T.F. (1993) Micro-Raman and infrared spectral study of forsterite under high pressure. American Mineralogist, 78, 469–476.Google Scholar
Woods, G.S. and Collins, A.T. (1983) Infrared absorption spectra of hydrogen complexes in type I diamonds. Journal of the Physics and Chemistry of Solids, 44, 471–475.CrossRefGoogle Scholar
Woods, G.S., Purser, G.C., Mtimkulu, A.S.S. and Collins, A.T. (1990) The nitrogen content of type Ia natural diamonds. Journal of Physics and Chemistry of Solids, 51, 1191–1197.CrossRefGoogle Scholar
Wyllie, P.J., Baker, M.B. and White, B.S. (1990) Experimental boundaries for the origin and evolution of carbonatites. Lithos, 26, 3–19.CrossRefGoogle Scholar
Zedgenizov, D.A., Rylov, G.M. and Shatsky, V.S. (1999) The internal structure of microdiamonds from Udachnaya kimberlite pipe. Russian Geology and Geophysics, 40, 113–121.Google Scholar
Zedgenizov, D.A., Reutsky, V.N., Shatsky, V.S. and Fedorova, E.N. (2002) A comparison of carbon isotope composition and impurite defects of microdiamonds of octahedral and cubic habit from Udachnaya kimberlite pipe (Yakutia). Geochimica et Cosmochimica Acta, 66N, 15A.Google Scholar
Zhenxian, P. (1990) High-pressure Raman studies of graphite and ferric chloride-graphite. Journal of Physics of Condensed Matter, 2, 8083–8088.CrossRefGoogle Scholar