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Compositional variation in the chevkinite group: new data from igneous and metamorphic rocks

Published online by Cambridge University Press:  05 July 2018

R. Macdonald*
Affiliation:
IGMiP Faculty of Geology, University of Warsaw, al. Žwirki i Wigury 93, 02-089 Warszawa, Poland Environment Centre, Lancaster University, Lancaster LA1 4YQ, UK
H. E. Belkin
Affiliation:
U.S. Geological Survey, 956 National Center, Reston, VA 20192, USA
F. Wall
Affiliation:
Camborne School of Mines, School of Geography, Archaeology and Earth Resources, University of Exeter, Cornwall Campus, Penryn TR10 9EZ, UK
B. Baginski
Affiliation:
IGMiP Faculty of Geology, University of Warsaw, al. Žwirki i Wigury 93, 02-089 Warszawa, Poland

Abstract

Electron microprobe analyses are presented of chevkinite-group minerals from Canada, USA, Guatemala, Norway, Scotland, Italy and India. The host rocks are metacarbonates, alkaline and subalkaline granitoids, quartz-bearing pegmatites, carbonatite and an inferred K-rich tuff. The analyses extend slightly the range of compositions in the chevkinite group, e.g. the most MgO-rich phases yet recorded, and we report two further examples where La is the dominant cation in the A site. Patchily- zoned crystals from Virginia and Guatemala contain both perrierite and chevkinite compositions. The new and published analyses are used to review compositional variation in minerals of the perrierite subgroup, which can form in a wide range of host rock compositions and over a substantial pressure- temperature range. The dominant substitutions in the various cation sites and a generalized substitution scheme are described.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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