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Galuskinite, Ca7(SiO4)3(CO3), a new skarn mineral from the Birkhin gabbro massif, Eastern Siberia, Russia

Published online by Cambridge University Press:  05 July 2018

B. Lazic ,
T. Armbruster ,
V. B. Savelyeva ,
A. E. Zadov ,
N. N. Pertsev  and
P. Dzierżanowski
B. Lazic
Affiliation:
Institute of Geological Sciences, University of Bern, Freiestr. 3, CH-3012 Bern, Switzerland
T. Armbruster*
Affiliation:
Institute of Geological Sciences, University of Bern, Freiestr. 3, CH-3012 Bern, Switzerland
V. B. Savelyeva
Affiliation:
Institute of the Earth Crust SB RAS, Lermontov St. 128, 664033 Irkutsk, Russia
A. E. Zadov
Affiliation:
OOO Science Research Centre ‘NEOCHEM’, Altuf’evskoye Highway 43, Moscow, Russia
N. N. Pertsev
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry (IGEM) RAS, Staromonetny 35, Moscow, Russia
P. Dzierżanowski
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, University of Warsaw, al. Żwirki i Wigury 93, 02-089 Warszawa, Poland
*
*E-mail: thomas.ambruster@krist.unibe.ch
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Abstract

In addition to spurrite, Ca5(SiO4)2(CO3), and tilleyite, Ca5(Si2O7)(CO3)2, galuskinite, C is the third mineral in the CaO—SiO2—CO2 ternary system. Galuskinite, monoclinic, space group P21/c (a = 18.79, b = 6.72, c = 10.47 Å, β = 90.79°, V = 1322 Å3, Z = 4), occurs in thin veins which cut calcio-olivine, γ-Ca2SiO4, skarn with larnite, β-Ca2SiO4, relics. Pavlovskyite, Ca8(SiO4)2(Si3O10), and dellaite, Ca6(Si2O7)(SiO4)(OH)2, form a margin between the veins and the calcio-olivine skarn. The sanidinite facies high-temperature skarn formed ∼500 Ma ago when gabbroid rocks of the Birkhin complex (Baikal area, Eastern Siberia, Russia) intruded and contact-metamorphosed limestone xenoliths. Galuskinite is a retrograde product of skarn alteration and has neither been described from cement clinker production processes nor from studies of the CaO—SiO2—CO2 system. The crystal structure of galuskinite, refined from single crystal X-ray data to Ri = 3.1%, has a modular character. One may define a polysomatic series with spurrite and larnite as endmembers and galuskinite as a 1:1 polysome built from regular alternating spurrite and larnite modules. Differences between the X-ray powder patterns of galuskinite and spurrite are most obvious in the low 8 region. Galuskinite is named after the Russian mineralogists Irina O. Galuskina and Evgeny V. Galuskin, Faculty of Earth Sciences. University of Silesia, Poland, for their outstanding contributions to skarn mineralogy.

Keywords

galuskinitecalcium silicate carbonateskarnnew mineralcrystal structurepolysomatismmodularityBaikalRussia
Type
Research Article
Information
Mineralogical Magazine , Volume 75 , Issue 5 , October 2011 , pp. 2631 - 2648
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

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