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Mauriziodiniite, NH4(As2O3)2I, the ammonium and iodine analogue of lucabindiite from the Torrecillas mine, Iquique Province, Chile

Published online by Cambridge University Press:  26 November 2019

Anthony R. Kampf Open the ORCID record for Anthony R. Kampf [Opens in a new window] ,
Barbara P. Nash  and
Arturo A. Molina Donoso
Anthony R. Kampf*
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA90007, USA
Barbara P. Nash
Affiliation:
Department of Geology and Geophysics, University of Utah, Salt Lake City, Utah84112, USA
Arturo A. Molina Donoso
Affiliation:
Los Algarrobos 2986, Iquique, Chile
*
*Author for correspondence: Anthony R. Kampf, Email: akampf@nhm.org
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Abstract

The new mineral mauriziodiniite (IMA2019-036), NH4(As2O3)2I, was found at the Torrecillas mine, Iquique Province, Chile, where it is a secondary alteration phase associated with calcite, cuatrocapaite-(NH4), lavendulan, magnesiokoritnigite and torrecillasite on matrix consisting of native arsenic, arsenolite and pyrite. Mauriziodiniite occurs as hexagonal tablets up to ~300 μm in diameter. Crystals are colourless and transparent, with pearly to adamantine lustre and white streak. The Mohs hardness is ~1. Tablets are sectile and easily flexible, but not elastic. Fracture is curved, irregular and stepped. Cleavage is perfect on {001}. The calculated density is 3.916 g/cm3. Optically, mauriziodiniite is uniaxial (–) with ω = 2.07(calc) and ɛ = 1.770(5) (white light). The empirical formula, determined from electron microprobe analyses, is (NH4)0.94K0.03(As2O3)2I0.92Cl0.03. Mauriziodiniite is hexagonal, P6/mmm, a = 5.289(2), c = 9.317(2) Å, V = 225.68(18) Å3 and Z = 1. The structure, refined to R1 = 4.16% for 135 Io > 2σI reflections, contains three types of layers: (1) a planar neutral As2O3 (arsenite) sheet; (2) an NH4+ layer that links adjacent arsenite sheets via bonds to their O atoms; and (3) an I– layer that links adjacent arsenite sheets via bonds to their As atoms. The layer sequence is I–As2O3–NH4–As2O3–I. Mauriziodiniite is isostructural with lucabindiite and is structurally related to gajardoite, cuatrocapaite-(NH4), cuatrocapaite-(K) and torrecillasite.

Keywords

mauriziodiniitenew mineralarsenitecrystal structureRaman spectroscopylucabindiiteTorrecillas mineChile
Type
Article
Information
Mineralogical Magazine , Volume 84 , Issue 2 , April 2020 , pp. 267 - 273
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

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Footnotes

Associate Editor: Ian T. Graham

References

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