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Novograblenovite from Radlin, Upper Silesia, Poland and its relation to ‘redikortsevite’

Published online by Cambridge University Press:  05 January 2021

Jan Parafiniuk ,
Marcin Stachowicz Open the ORCID record for Marcin Stachowicz [Opens in a new window]  and
Krzysztof Woźniak Open the ORCID record for Krzysztof Woźniak [Opens in a new window]
Jan Parafiniuk
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, Faculty of Geology, University of Warsaw, Żwirki i Wigury 93, 02-089Warsaw, Poland
Marcin Stachowicz*
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, Faculty of Geology, University of Warsaw, Żwirki i Wigury 93, 02-089Warsaw, Poland
Krzysztof Woźniak
Affiliation:
Department of Chemistry, University of Warsaw, Pasteura 1, 02-093Warszawa, Poland
*
*Author for correspondence: Marcin Stachowicz, Email: marcin.stachowicz@uw.edu.pl
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Abstract

The paper presents detailed mineralogical and structural characteristics of novograblenovite that occurs abundantly on a burning coal dump at Radlin, Upper Silesia, Poland. Our results indicate that NH4MgCl3⋅6H2O is the proper formula of this mineral. The thermal behaviour of novograblenovite shows a two-step dehydration at 155 and 193°C and sublimation of NH4Cl at 341°C. A Raman spectrum, obtained for the first time, reveals the normal modes of H2O and NH4+ vibrations. The crystal structure of novograblenovite was refined on the basis of high quality X-ray diffraction data. The final discrepancy factor wR2 was 0.0567 for 94 parameters and 1464 independent reflections. The structure has a monoclinic C2/c space group symmetry with the following unit cell parameters: a = 9.2709(3) Å, b = 9.5361(2) Å, c = 13.2741(4) Å and β = 90.054(3)°. We were able to specify the architecture of the disordered NH4+ cation located at the symmetry centre. This led to reasonable parameters for the H-bonding formed by this cation. In carnallite the K+ cations occupy an identical space to the ammonium ion in novograblenovite, but when embedded into the latter crystal structure it is bound less tightly. Voids occupy 14% of the space in the novograblenovite crystal structure. Novograblenovite is exactly the same phase as the ‘redikortsevite’ described previously from Chelabinsk coal dumps and this informally introduced name should be abandoned.

Keywords

burning coal dumpsammonium mineralcrystal structuredifferential thermal analysisRaman spectroscopynovograblenovite
Type
Article
Information
Mineralogical Magazine , Volume 85 , Issue 2 , April 2021 , pp. 132 - 141
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Mihoko Hoshino

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