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Pseudomeisserite-(NH4), a new mineral with a novel uranyl-sulfate linkage from the Blue Lizard mine, San Juan County, Utah, USA

Published online by Cambridge University Press:  17 March 2020

Anthony R. Kampf Open the ORCID record for Anthony R. Kampf [Opens in a new window] ,
Travis A. Olds ,
Jakub Plášil ,
Barbara P. Nash  and
Joe Marty
Anthony R. Kampf*
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA90007, USA
Travis A. Olds
Affiliation:
Section of Minerals and Earth Sciences, Carnegie Museum of Natural History, 4400 Forbes Avenue, Pittsburgh, Pennsylvania15213, USA
Jakub Plášil
Affiliation:
Institute of Physics ASCR, v.v.i., Na Slovance 1999/2, 18221Prague 8, Czech Republic
Barbara P. Nash
Affiliation:
Department of Geology and Geophysics, University of Utah, Salt Lake City, UT84112, USA
Joe Marty
Affiliation:
5199 East Silver Oak Road, Salt Lake City, UT84108, USA
*
*Author for correspondence: Anthony R. Kampf, Email: akampf@nhm.org
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Abstract

The new mineral pseudomeisserite-(NH4) (IMA2018-166), (NH4,K)2Na4[(UO2)2(SO4)5]⋅4H2O, was found in the Blue Lizard mine, San Juan County, Utah, USA, where it occurs as light yellow prisms in a secondary assemblage with belakovskiite, blödite, changoite, ferrinatrite, gypsum, ivsite, metavoltine and tamarugite. The streak is very pale yellow and the fluorescence is bright lime green under 405 nm ultraviolet light. Crystals are transparent with vitreous lustre. The tenacity is brittle, the Mohs hardness is 2½, the fracture is curved or conchoidal and there is one perfect cleavage on {100}. The mineral is easily soluble in H2O and has a measured density of 3.22(2) g⋅cm–3. Pseudomeisserite-(NH4) is optically biaxial (–) with α = 1.536(2), β = 1.559(2) and γ = 1.565(2) (white light); 2Vmeas. = 53(1)°; dispersion is r > v, distinct; pleochroism: X colourless, Y light yellow and Z pale yellow (X < Z < Y); optical orientation: Z = b, Y ∧ c = 33° in obtuse β). Electron microprobe analyses (WDS mode) provided (NH4)1.49K0.60Na3.87U2.00S5.04O28H7.78. The five strongest X-ray powder diffraction lines are [dobs, Å(I)(hkl)]: 12.69(76)(100), 6.83(84)(012,102), 6.01(100)($\bar{2}$02), 3.959(67)($\bar{2}$21,$\bar{2}$14,$\bar{1}$23) and 3.135(76)($\bar{2}$06,223,$\bar{1}$16). Pseudomeisserite-(NH4) is monoclinic, P21/c, a = 13.1010(3), b = 10.0948(2), c = 19.4945(14) Å, β = 104.285(7)°, V = 2498.5(2) Å3 and Z = 4. The structural unit in the structure (R1 = 0.0254 for 3837 I > 2σI reflections) is a novel [(UO2)2(SO4)5]6– uranyl-sulfate band.

Keywords

pseudomeisserite-(NH4)new mineraluranyl sulfatecrystal structureBlue Lizard mineRed CanyonUtahUSA
Type
Article
Information
Mineralogical Magazine , Volume 84 , Issue 3 , June 2020 , pp. 435 - 443
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2020

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Footnotes

Associate Editor: Daniel Atencio

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