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Raman spectroscopy of the minerals boléite，cumengéite， diaboléte and phosgenite — implications for the analysis of cosmetics of antiquity

Published online by Cambridge University Press:  05 July 2018

R. L. Frost ,
P. A. Williams  and
W. Martens
R. L. Frost*
Affiliation:
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia
P. A. Williams
Affiliation:
Centre for Industrial and Process Mineralogy, School of Science, Food and Horticulture, University of Western Sydney, Locked Bag 1797, Penrith South DC, NSW 1797, Australia
W. Martens
Affiliation:
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia
*
* E-mail: r.frost@qut.edu.au
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Abstract

The application of Raman spectroscopy to the study of the mixed cationic Pb-Cu and Pb-Cu-Ag minerals: boleite, cumengeite and diaboleite has enabled their molecular structures to be compared. Each of these three minerals shows different hydroxyl-stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl-deformation modes. The low-wavenumber region is characterized by the bands assigned to the cation-chloride stretching and bending modes. Phosgenite is also a mixed chloride-carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems of secondary mineral formation.

Keywords

boléitecumengéitediaboléiteleadchloridephosgeniteRaman spectroscopy.
Type
Research Article
Information
Mineralogical Magazine , Volume 67 , Issue 1 , February 2003 , pp. 103 - 111
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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