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Relation between oxidation/crystallization and degassing upon reheating of basalt glass from Kilauea, Hawaii

Published online by Cambridge University Press:  05 July 2018

D. J. M. Burkhard
D. J. M. Burkhard*
Affiliation:
Institute for Mineralogy and Geochemistry, University of Karlsruhe, D-76128 Karlsruhe, Germany Forschungszentrum Karlsruhe, Institute for Technical Chemistry, Water- and Geotechnology (ITC-WGT), D-76021 Karlsruhe, Germany
*
*E-mail: dorothee.burkhard@itc-wgt.fzk.de
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Abstract

Basalt glass from Kilauea, Hawaii (SBG) starts to crystallize upon heat treatment in air at ∽840°C. In addition, oxidation takes place. The kinetics of both processes may be readily quantified though the mechanism is difficult to access. This work investigates the relationship between these processes, crystallization and oxidation, and the escape of volatiles from the glass/liquid upon reheating. Evolved gas analyses and differential scanning calorimetry are the techniques used. In addition, isothermal heat treatment in argon is carried out in order to eliminate the external reason for oxidation, the oxygen gradient, and to focus on intrinsic oxidation. Products are examined with 57Fe Mössbauer spectroscopy. As expected, degassing temperatures of SBG, and of two MORB samples, considered for comparison, are above the glass transition temperature. We find no convincing evidence of intrinsic oxidation. Degassing is likely to induce interface-controlled crystallization.

Keywords

oxidationcrystallizationdegassingreheatingbasalt glassKilaueaHawaiiDEGASDSC
Type
Research Article
Information
Mineralogical Magazine , Volume 69 , Issue 2 , April 2005 , pp. 103 - 117
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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