Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-27T06:55:12.789Z Has data issue: false hasContentIssue false
  • English
  • Français

Removal of emerging organic contaminants from aqueous systems: adsorption and location of methyl-tertiary-butylether on synthetic ferrierite

Published online by Cambridge University Press:  05 July 2018

A. Martucci ,
L. Leardini ,
M. Nassi ,
E. Sarti ,
R. Bagatin  and
L. Pasti
A. Martucci*
Affiliation:
Department of Physics and Earth Sciences, University of Ferrara, Via Saragat, 1, I-44100 Ferrara, Italy
L. Leardini
Affiliation:
Department of Physics and Earth Sciences, University of Messina, Viale Ferdinando Stagno d’Alcontres 31, I-98166 Messina S. Agata, Italy
M. Nassi
Affiliation:
Department of Chemistry, University of Ferrara, Via L. Borsari, 46, I-44100 Ferrara, Italy
E. Sarti
Affiliation:
Department of Chemistry, University of Ferrara, Via L. Borsari, 46, I-44100 Ferrara, Italy
R. Bagatin
Affiliation:
Research Center for Non-Conventional Energy – Istituto Eni Donegani Environmental Technologies, via Felice Maritano, 26, San Donato Milanese (MI), I-20097 Milan, Italy
L. Pasti*
Affiliation:
Department of Chemistry, University of Ferrara, Via L. Borsari, 46, I-44100 Ferrara, Italy
*
* E-mail: mrs@unife.it; psu@unife.it
* E-mail: mrs@unife.it; psu@unife.it
Get access Rights & Permissions [Opens in a new window]

Abstract

This study reports on experimental results concerning methyl-tert-butyl-ether (MTBE, C5H12O) adsorption from water into the pores of siliceous zeolite ferrierite (FER) by combining powder X-ray diffraction analyses and chromatography techniques. Rietveld structure refinement (Immm space group) highlighted the presence of two crystallographically independent MTBE sites located in the 10-ring channel parallel to the [001] direction (MTBE1) and in the ferrierite cage (MTBE2), respectively. On the whole, Rietveld refinement revealed clearly the incorporation of ~1.8 MTBE molecules per unit cell, in very good agreement with the weight loss given by thermogravimetric analyses, and saturation capacity as determined by adsorption isotherms. Rapid kinetics combined with good adsorption suggests that FER can be used beneficially as an adsorbent medium in removing this emerging organic contaminant from water.

Keywords

Zeolite ferrieriteX-ray diffractionadsorptionmethyl-tert-butyl-ether
Type
Research Article
Information
Mineralogical Magazine , Volume 78 , Issue 5 , October 2014 , pp. 1161 - 1175
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2014

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Achten, C., Kolb, A. and Puttman, W. (2002) Occurrence of methyl tert-butyl ether (MTBE) in riverbank filtered water and drinking water produced by riverbank filtration. 2. Environmental Science & Technology, 36, 3663–3670.CrossRefGoogle ScholarPubMed
Alberti, A. and Martucci, A. (2010) Proton transfer mediated by water: experimental evidence by neutron diffraction. The Journal of Physical Chemistry C, 114, 7767–7773.CrossRefGoogle Scholar
Alberti, A. and Sabelli, C. (1987) Statistical and true symmetry of ferrierite: possible absence of straight T–O–T bridging bonds. Zeitschrift für Kristallographie, 178, 249–256.CrossRefGoogle Scholar
Amberg, A., Rosner, E. and Dekant, W. (2001) Toxicokinetics of methyl tert-butyl ether and its metabolites in humans after oral exposure. Toxicological Sciences, 61, 62–67.CrossRefGoogle ScholarPubMed
Anderson, M.A., (2000) Removal of MTBE and other organic contaminants from water by sorption to high silica zeolites. Environmental Science & Technology, 34, 725–727.CrossRefGoogle Scholar
Arletti, R., Martucci, A., Alberti, A., Pasti, L., Nassi, M. and Bagatin, R. (2012) Location of MTBE and toluene in the channel system of the zeolite mordenite: Adsorption and host-guest interactions. Journal of Solid State Chemistry, 194, 135–142.CrossRefGoogle Scholar
Baerlocher, Ch., McCusker, L.B., and Olson, D.H., (2007) Atlas of Zeolite Framework Types, 6th edition. Elsevier, Amsterdam.Google Scholar
Braschi, I., Blasioli, S., Gigli, L., Gessa, C.E., Alberti, A. and Martucci, A. (2010) Removal of sulfonamide antibiotics from water: Evidence of adsorption into an organophilic zeolite Y by its structural modifications. Journal of Hazardous Materials, 178, 218–225.CrossRefGoogle Scholar
Braschi, I., Gatti, G., Bisio, C., Berlier, G., Sacchetto, V., Cossi, M. and Marchese, L. (2012) The role of silanols in the interactions between methyl tert-butyl ether and high-silica faujasite Y: an infrared spectroscopy and computational model study. The Journal of Physical Chemistry C, 116, 6943–6952.CrossRefGoogle Scholar
Centi, G., Grande, A. and Perathoner, S. (2002) Catalytic conversion of MTBE to biodegradable chemicals in contaminated water. Catalysis Today, 75, 69–76.CrossRefGoogle Scholar
Chang, P. and Young, T. (2000) Kinetics of methyl tertbutyl ether degradation and by-product formation during UV/hydrogen peroxide water treatment, Water Research, 34, 2233–2240.CrossRefGoogle Scholar
Ciambelli, P., Sannino, D., Palo, E., Balboni, E., Martucci, A., Dalconi, M.C., and Alberti, A. (2008a) The effect of cation siting in Co,Agferrierite on CH4-NOx-SCR, Studies in Surface Science and Catalysis, 174, 1039–1044.CrossRefGoogle Scholar
Ciambelli, P., Sannino, D., Palo, E., Gargano, G., Balboni, E., Martucci, A., Dalconi, M.C., and Alberti, A. (2008b) Relevance of Co, Ag-ferrierite catalysts acidity and cation siting to CH4-NOx-SCR activity I. Nuovo Cimento, 123, 1583–1595.Google Scholar
Cruciani, G., Alberti, A., Martucci, A., Knudsen, K.D., Ciambelli, P. and Rapacciuolo, M. (1999) Crystal structure of zeolite ferrierite in as-synthesized, NH4- and H-forms. Pp. 2361–2369 in: Proceedings of the 12th International Zeolite Conference (M.M.J. Treacy, B.K., Marcus, M.E., Bisher and J.B. Higgins, editors). Materials Research Society, Warrendale, Pennsylvania, USA.Google Scholar
Fowler, R.H., and Guggenheim, E.A., (1965) Statistical Thermodynamics, Theory of the Properties of Matter in Equilibrium. Cambridge University Press, New York.Google Scholar
Giles, C.H., MacEwan, T.H., Nakhwa, S.N., and Smith, D. (1960) Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. Journal of the Chemical Society, 1960, 3973–3993.CrossRefGoogle Scholar
Gramlich-Meier, R., Gramlich, V., Meier, W.M., and Smith, B.K., (1984) On faults in the framework structure of the zeolite ferrierite. Zeitschrift für Kristallographie, 169, 201–210.CrossRefGoogle Scholar
Gramlich-Meier, R., Gramlich, V. and Meier, W.M., (1985) The crystal structure of the monoclinic variety of ferrierite. American Mineralogist, 70, 619–623.Google Scholar
Gritti, F., Piatkowski, W. and Guiochon, G. (2002) Comparison of the adsorption equilibrium of a few low-molecular mass compounds on a monolithic and a packed column in reversed-phase liquid chromatography. Journal of Chromatography A, 978(1–2), 81–107.CrossRefGoogle Scholar
Johnson, R., Pankow, J., Bender, D., Price, C. and Zogorski, J. (2000) MTBE – to what extent will past releases contaminate community water supply wells? Environmental Science & Technology, 34, 210A–217A.Google Scholar
Knappe, D.R.U. and Campos, A.A.R. (2005) Effectiveness of high-silica zeolites for the adsorption of methyl tertiary-butyl ether from natural water. Water Science and Technology. Water Supply, 5, 83–91.CrossRefGoogle Scholar
Koubaissy, B., Joly, G., Batonneau-Gener, I., and Magnoux, P. (2011) Adsorptive removal of aromatic compounds present in wastewater by using dealuminated Faujasite zeolite. Industrial & Engineering Chemistry Research, 50, 5705–5713.CrossRefGoogle Scholar
Kuster, M., Alda, M.J.L., Hernando, M.D., Petrovic, M., Martín-Alonso, J., and Barceló , D. (2008) Analysis and occurrence of pharmaceuticals, estrogens, progestogens and polar pesticides in sewage treatment plant effluents, river water and drinking water in the Llobregat river basin (Barcelona, Spain). Journal of Hydrology, 358, 112–123.CrossRefGoogle Scholar
Larson, A.C., and Von Dreele, R.B., (2000) General Structure Analysis System (GSAS). Los Alamos National Laboratory Report No. LAUR 86–748. Los Alamos National Laboratory, New Mexico, USA.Google Scholar
Lewis, J.E., Freyhardt, C.C., and Davis, M.E., (1996) Location of pyridine guest molecules in an electroneutral {3 ?}[SiO4/2] host framework: singlecrystal structures of the as-synthesized and calcined forms of high-silica ferrierite. The Journal of Physical Chemistry, 100, 5039–5049.CrossRefGoogle Scholar
Lindsey, M.E., Meyer, M. and Thurman, E.M., (2001) Analysis of trace levels of sulfinamide and tetracycline antimicrobials in groundwater and surface water using solid-phase extraction and liquid chromatography/mass spectroscopy. Analytical Chemistry, 73, 4640–4646.CrossRefGoogle Scholar
Mackay, D., Shiu, W.Y., Ma, K.C., and Lee, S.C., (2006) Illustrated handbook of physical-chemical properties and environmental fate for organic chemicals, Vol. III. Taylor & Francis Group, LLC books, Boca Raton, Florida, US.CrossRefGoogle Scholar
Martucci, A., Alberti, A., Cruciani, G., Radaelli, P., Ciambelli, P. and Rapacciuolo, M (1999) Location of Brønsted sites in D-ferrierite by neutron powder diffraction. Microporous and Mesoporous Materials, 30, 955–101.CrossRefGoogle Scholar
Martucci, A., Pasti, L., Marchetti, N., Cavazzini, A., Dondi, F. and Alberti, A. (2012a) Adsorption of pharmaceuticals from aqueous solutions on synthetic zeolites. Microporous and Mesoporous Materials, 148, 174–183.CrossRefGoogle Scholar
Martucci, A., Pasti, L., Nassi, M., Alberti, A., Arletti, R., Bagatin, R., Vignola, R. and Sticca, R. (2012b) Adsorption mechanism of 1,2-dichloroethane into an organophilic zeolite mordenite: A combined diffractometric and gas chromatographic study. Microporous and Mesoporous Materials, 151, 358–367.CrossRefGoogle Scholar
Martucci, A., Cremonini, M.A., Blasioli, S., Gigli, L., Gatti, G., Marchese, L. and Braschi, I. (2013) Adsorption and reaction of sulfachloropyridazine sulfonamide antibiotic on a high silica mordenite: A structural and spectroscopic combined study. Microporous and Mesoporous Materials, 170, 274–286.CrossRefGoogle Scholar
Morris, R.E., Weigel, S.J., Henson, N.J., Bull, L.M., Janicke, M.T., Chmelka, B.F., and Cheetham, A.K., (1994) A synchrotron X-ray diffraction, neutron diffraction, 29Si MAS-NMR, and computational study of the siliceous form of zeolite ferrierite. Journal of the American Chemical Society, 116, 11849–11855.CrossRefGoogle Scholar
Moulijn, J.A., Makkee, M. and Van Dipen, A. (2001) Chemical Process Technology, 1st Edition. John Wiley and Sons Ltd., Chichester, UK.Google Scholar
Office of Environmental Health Hazard Assessment (OEHHA) (1999) Public health goal for methyl tertiary butyl Ether (MTBE) in drinking water. Pesticide and Environmental Toxicology Section, California Environment Protection Agency, USA. [http://oehha.ca.gov/water/phg/pdf/mtbe_f.pdf].Google Scholar
Pasti, L., Martucci, A., Nassi, M., Cavazzini, A., Alberti, A. and Bagatin, R. (2012) The role of water in DCE adsorption from aqueous solutions onto hydrophobic zeolites. Microporous and Mesoporous Materials, 160, 182–193.CrossRefGoogle Scholar
Pasti, L., Sarti, E., Cavazzini, A., Marchetti, N., Dondi, F. and Martucci, A. (2013) Factors affecting drug adsorption on beta zeolites. Journal of Separation Science, 36, 1604–1611.CrossRefGoogle ScholarPubMed
Petrovic, M. and Barceló , D. (2006) Application of liquid chromatography/quadruple time-of-flight mass spectrometry (LC-QqTOF-MS) in the environmental analysis. Journal of Mass Spectrometry, 41, 1259–1267.CrossRefGoogle Scholar
Pickering, I.J., Maddox, P.J., Thomas, J.M., and Cheetham, A.K., (1989) A neutron powder diffraction analysis of potassium-exchanged ferrierite. Journal of Catalysis, 119, 261–265.CrossRefGoogle Scholar
Richardson, S.D., and Ternes, T.A., (2011) Water analysis: emerging contaminants and current issues. Analytical Chemistry, 83, 4614–4648.CrossRefGoogle ScholarPubMed
Sacchetto, V., Gatti, G., Paul, G., Braschi, I., Berlier, G., Cossi, M., Marchese, L., Bagatin, R. and Bisio, C. (2013) The interactions of methyl tert-butyl ether on high silica zeolites: a combined experimental and computational study. Physical Chemistry Chemical Physics, 15, 13275–13287.CrossRefGoogle ScholarPubMed
Shiguang, L., Tuan, V.A., Noble, R.D., and Falconer, J.L., (2003) MTBE Adsorption on all-silica b zeolite. Environmental Science & Technology, 37, 4007–4010.Google Scholar
Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J. and Siemieniewska, T. (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure and Applied Chemistry, 57, 603–619.CrossRefGoogle Scholar
Squillace, P., Pankow, J., Kortes, N. and Zogorski, J. (2009) Review of the environmental behavior and fate of methyl tert-butyl ether. Environmental Toxicology and Chemistry, 16, 1836–1844.CrossRefGoogle Scholar
Toby, B.H., (2001) EXPGUI, a graphical user interface for GSAS. Journal of Applied Crystallography, 34, 210–213.CrossRefGoogle Scholar
United States Environmental Protection Agency (1997) Drinking water advisory: Consumer acceptability advice and health effects analysis on methyl tertiarybutyl ether (MTBE). Report No. EPA-822-F-97-009. US Environmental Protection Agency, Washington, DC. [http://www.epa.gov/action/advisories/drinking/ mtbe.cfm].Google Scholar
Vaughan, P.A., (1966) The crystal structure of the zeolite ferrierite. Acta Crystallographica, 21, 983–990.CrossRefGoogle Scholar
Weigel, S.J., Gabriel, J.C., Gutierrez Puebla, E., Monge Bravo, A., Henson, N.J., Bull, L.M., and Cheetham, A.K., (1996) Structure-directing effects in zeolite synthesis: a single-crystal x-ray diffraction, 29Si MAS NMR, and computational study of the competitive formation of siliceous ferrierite and dodecasil-3C (ZSM-39). Journal of the American Chemical Society, 118, 2427–2435.CrossRefGoogle Scholar
Xu, W.-Q., Yiu, Y.-G., Suib, S.C., Edwards, J.C., and O’Young, C.-L. (1995) N-butene skeletal isomerization to isobutylene on shape-selective catalysts: ferrierite/ZSM-35. Journal of Physical Chemistry, 99, 9443–9451.CrossRefGoogle Scholar
Zhang, H., Guo, O., Ren, L., Yang, C., Zhu, L., Meng, X., Li, C. and Xiao, F.-S. (2011) Organotemplatefree synthesis of high-silica ferrierite zeolite induced by CDO-structure zeolite building units. Journal of Material Chemistry, 21, 9494–9497.CrossRefGoogle Scholar
Zhang, T., Zhang, L., Wang, J., Yuan, T., Hong, X. and Qi, F. (2008) Pyrolysis of methyl tert-butyl ether (MTBE). 2. Theoretical study of decomposition pathways. The Journal of Physical Chemistry A. 112, 10495–10501.CrossRefGoogle ScholarPubMed