Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-10T17:18:18.485Z Has data issue: false hasContentIssue false
  • English
  • Français

The role of argillic alteration in the zeolitization of volcanic glass

Published online by Cambridge University Press:  05 July 2018

P. J. Leggo ,
J.-J. Cochemé ,
A. Demant  and
W. T. Lee
P. J. Leggo*
Affiliation:
Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK
J.-J. Cochemé
Affiliation:
Laboratoire de Pétrologie Magmatique, Université Aix-Marseille III, 13397 Marseille Cedex 20, France
A. Demant
Affiliation:
Laboratoire de Pétrologie Magmatique, Université Aix-Marseille III, 13397 Marseille Cedex 20, France
W. T. Lee
Affiliation:
Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK
*
*E-mail: leggo@esc.cam.ac.uk
Get access Rights & Permissions [Opens in a new window]

Abstract

The pseudomorphic replacement of glass shards by zeolite minerals is a common feature of volcanoclastic sediments. In the majority of cases the initial stage of this reaction is the alteration of the glass surface to a clay mineral or celadonite after which the bulk of the glass is altered to zeolite. This replacement feature is seen particularly well in glass of rhyolitic composition; the zeolite mineral usually being clinoptilolite. Volcanoclastic rocks of Oligocene age exposed in the Rhodope Massif, Bulgaria offered an opportunity to study this reaction experimentally as rocks containing unaltered glass shards are known to be close stratigraphic equivalents of zeolitized tuffs and in this respect are considered to be precursor rocks. Low-temperature hydrothermal reactions conducted on the unaltered glass, which had been clay coated in the laboratory, demonstrates the importance of the clay-glass interface. An hypothesis is put forward to explain this type of zeolitization process and a distinction is drawn between these rocks and other sediments in which zeolite minerals form from volcanic glass without the presence of a clay interface.

Keywords

zeoliteclinoptiloliteargillic alterationrhyolitic glassvolcanic glass
Type
Research Article
Information
Mineralogical Magazine , Volume 65 , Issue 5 , October 2001 , pp. 653 - 663
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aleksiev, B.S. and Djourova, E.G. (1974) Zeolite rocks: classification and nomenclature. Comptes Rend. Acad. bulgare des Sci., 27, 373–4.Google Scholar
Barth-Wirsching, U. and Holler, H. (1989) Experimental studies on zeolite formation conditions. Eur. J. Mineral., 1, 489–506.CrossRefGoogle Scholar
Boles, J.R. (1988) Occurrences of natural zeolites – Present status and future research. Pp. 3–18 in: Occurrence, Properties and Utilization of Natural Zeolites (Kallo, D. and Sherry, H.S., editors). Akademiai Kiado, Budapest.Google Scholar
Bray, H.J. (1999) Kinetics of high-temperature transformation of cay minerals. PhD thesis, Univ. Cambridge, UK.Google Scholar
Breck, D. (1984) Zeolite Molecular Seives (revised edition). Krieger, Florida, USA.Google Scholar
Burlet, E. (1997) Les tufs volcaniques zéolitisés des Rhodopes (Bulgarie) caractérization, propriétés physico-chimiques, origine. MSc thesis, Univ. Aix- Marseille 111, France.Google Scholar
Decarreau, A. (1983) Etude expérimentale de la cristallogenèse des smectites. Mesure des cofficients de partage smectite trioctaédrique – solution aqueuse pour les métaux M 2+de la première série de transition. Memoire ULP, 74, 185.Google Scholar
Deer, W.A., Howie, R.A. and Zussman, J. (1992) An Introduction to the Rock Forming Minerals, 2nd edition. Longmans, Harlow, Essex, UK.Google Scholar
de’Gennaro, M. and Colella, C. (1992) Experimental clay formation through the action of hot saline waters on volcanic glass. Mineral. Petrogr. Acta, 35A, 275–82.Google Scholar
Djourova, E.G. and Aleksiev, B.S. (1990) Zeolitic rocks related to the second acid Paleogene volcanism to the east of the town of Kurdjali. Geologica Rhodopica, 2nd Hellenic Bulgarian Symposium, 202–17.Google Scholar
Djourova, E.G. and Milakovska, Z.I. (1987) Oligocene volcanic glass genetic types at the village of Kralevo, District of Haskovo. Comptes Rend. Acad. bulgare des Sci., 40, 103–6.Google Scholar
Furness, H. and El-Anbaawy, M. (1980) Chemical changes and authigenic mineral formation during palagonitization of a basaltic hyaloclastite, Gran Canaria, Canary Islands. Neues Jahrb. Mineral. Abh., 139, 279–302.Google Scholar
Ghiara, M.R. and Petti, C. (1996) Chemical alteration of volcanic glasses and related control by secondary minerals: experimental studies. Aquatic Geochem., 1, 329–54.CrossRefGoogle Scholar
Hall, A. (1998) Zeolitization of volcaniclastic sediments: The role of temperature and pH. J. Sed. Res., 68, 739–45.CrossRefGoogle Scholar
Hay, R.L. (1978) Geologic occurrence of zeolites. Pp. 135–45 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. and Mumpton, F.A., editors). Pergamon Press, Elmsford, New York.Google Scholar
Hay, R.L. (1993) New developments in the geology of natural zeolites. Pp. 3–13 in: Natural Zeolites ‘93 (Ming, D.W. and Mumpton, F. A., editors). International Committee on Natural Zeolites, Brockport, New York.Google Scholar
Hay, R.L. and Guldman, S.G. (1987) Diagenetic alteration of silicic ash in Searles Lake California. Clays Clay Miner., 35, 449–57.CrossRefGoogle Scholar
Hawkins, D.B. (1981) Kinetics of glass dissolution and zeolite formation under hydrothermal conditions. Clays Clay Miner., 29, 331–40.CrossRefGoogle Scholar
Honnorez, J. (1978) Generation of phillipsite by palagonitization of basaltic glass in seawater and the origin of K-rich deep sea sediments. Pp. 245–57 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. and Mumpton, F.A., editors). Pergamon Press, Elmsford, New York.Google Scholar
Iijima, A. (1978) Occurrence of natural zeolites in marine environments. Pp. 175–98 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. and Mumpton, F.A., editors). Pergamon Press, Elmsford, New York.Google Scholar
Karaboni, S., Smit, B., Urah, J. and Oort, E. (1996) The swelling of clays: molecular simulations of the hydration of montmorillonite. Science, 271, 1102–4.CrossRefGoogle Scholar
Mariner, R.H. and Surdam, R.C. (1970) Alkalinity and formation of zeolites in saline alkaline lakes. Science, 170, 977–80.CrossRefGoogle ScholarPubMed
Minato, H. (1994) Observation under the polarizing microscope. Pp. 285–7 in: Natural Zeolite and its Utilization (No. 111 Committee, editor). Japan Society for the Promotion of Science, Tokyo University Press, Tokyo.Google Scholar
Murat, M., Amokrane, A., Bastide, J.P. and Montanaro, L. (1992) Synthesis of zeolites from thermally activated kaolinite. Some observations on nucleation and growth. Clay Miner., 27, 119–30.CrossRefGoogle Scholar
Murray, J. and Renard, A.F. (1891) Deep-sea Deposits: Vol. 5, Report on the Scientific Results of the Voyage of “HMS Challenger” during the years 1873-76. Eyre and Spottiswoode, London.Google Scholar
Ogihara, S. (1996) Diagenetic transformati on of clinopti lolite to analcime in silicic tuffs of Hokkaido, Japan. Mineral. Deposita. 31, 548–53.CrossRefGoogle Scholar
Petit, J.-C., Della Mea, G., Dran, J.-C., Magonthier, M.-C., Mando, P.A. and Paccagnella, A. (1990) Hydrated- layer formation during dissolution of complex silicate glasses and minerals. Geochim. Cosmochim. Acta, 54, 1941–55.CrossRefGoogle Scholar
Putnis, A. (1992) Introduction to Mineral Sciences. Cambridge University Press, Cambridge, UK.CrossRefGoogle Scholar
Raynov, N., Popov, N., Yanev, Y., Petrova, P., Popova, T., Hristova, V., Atanasova, R. and Zankarska, R. (1997) Geological, mineralogical and technological characteristics of zeolitized tuff in the Eastern Rhodopes, Bulgaria. Pp. 263–75 in: Natural Zeolites, Sofia ‘95 (Kirov, G., Filizova, L. and Petrov, O., editors).Google Scholar
Resing, J.A. and Sansone, F.J. (1999) The chemistry of lava-seawater reactions: the generation of acidity. Geochim. Cosmochim. Acta, 63, 2183–98.CrossRefGoogle Scholar
Sheppard, R.A. (1991) Zeolitic diagenesis of tuffs in the Miocene Chalk Hills Formation, Western Snake River Plain, Idaho. US Geol. Surv. Bull, 1963, 27.Google Scholar
Sudo, T. (1978) An outline of clays and clay minerals in Japan. Pp. 1–103 in: Developments in Sedimentology, Vol. 26 (Sudo, T. and Shimoda, S., editors ). Elsevier Scientific Publishing Co., Amsterdam, The Netherlands.CrossRefGoogle Scholar
Surdam, R.C. and Eugster, H.P. (1976) Mineral reactions in the sedimentary deposits of the Lake Magadi region, Kenya. Bull. Geol. Soc. Amer., 87, 1739–52.2.0.CO;2>CrossRefGoogle Scholar
Surdam, R.C. and Sheppard, R.A. (1978) Zeolites in saline alkaline lake deposits. Pp. 145–74 in: Natural Zeolites: Occurrence, Properties, Use (Sand, L.B. and Mumpton, F.A., editors). Pergamon Press, Elmsford, New York.Google Scholar
Tsirambides, A., Filippidis, A. and Kassoli-Fournaraki, A. (1993) Zeolitic alteration of Eocene volcaniclastic sediments at Metaxades, Thrace, Greece. Appl. Clay Sci., 7, 509–26.CrossRefGoogle Scholar