Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-10T07:07:15.443Z Has data issue: false hasContentIssue false
  • English
  • Français

Slip systems and critical resolved shear stress in pyrite: an electron backscatter diffraction (EBSD) investigation

Published online by Cambridge University Press:  05 July 2018

C. D. Barrie ,
A. P. Boyle ,
S. F. Cox  and
D. J. Prior
C. D. Barrie*
Affiliation:
Department of Earth and Ocean Sciences, University of Liverpool, Liverpool L69 3GP, UK School of Geography and Geosciences, Irvine Building, University of St Andrews, Fife KY16 9AL, UK
A. P. Boyle
Affiliation:
Department of Earth and Ocean Sciences, University of Liverpool, Liverpool L69 3GP, UK
S. F. Cox
Affiliation:
Research School of EarthSciences, Australian National University, ACT 0200, Australia
D. J. Prior
Affiliation:
Department of Earth and Ocean Sciences, University of Liverpool, Liverpool L69 3GP, UK
*
*E-mail: cdb21@st-andrews.ac.uk
Get access Rights & Permissions [Opens in a new window]

Abstract

A suite of experimentally deformed single-crystal pyrite samples has been investigated using electron backscatter diffraction (EBSD). Single crystals were loaded parallel to <100> or <110> and deformed at a strain rate of 10-5 s-1, confining pressure of 300 MPa and temperatures of 600°C and 700°C. Although geometrically (Schmid factor) the {001}<100> slip system should not be activated in <100> loaded samples, lattice rotation and boundary trace analyses of the distorted crystals indicate this slip system is easier to justify. Determination of 75 MPa as the critical resolved shear stress (CRSS) for {001}<100> activation, in the <110> loaded crystals, suggests a crystal misalignment of ~5—15° in the <100> loaded crystals would be sufficient to activate the {001}<100> slip system. Therefore, {001}<100> is considered the dominant slip system in all of the single-crystal pyrite samples studied. Slip-system analysis of the experimentally deformed polycrystalline pyrite aggregates is consistent with the single-crystal findings, with the exception that {001}<11̄> also appears to be important, although less common than the {001}<100> slip system. The lack of crystal preferred orientation (CPO) development in the polycrystalline pyrite aggregates can be accounted for by the presence of two independent symmetrically equivalent slip systems more than satisfying the von Mises criterion.

Keywords

pyritedislocationsslip systemsEBSDdeformationcritical resolved shear stress
Type
Research Article
Information
Mineralogical Magazine , Volume 72 , Issue 6 , December 2008 , pp. 1181 - 1199
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Arnold, M. (1978) Cristallogenese et geochimie isotopique de la pyrite et leurs apports a la metallogenese des amas sulfures associes a un volcanisme sous-marin. PhD Thesis, Universite de Nancy, France.Google Scholar
Auten, T.A., Radcliffe, S.V. and Gordon, R.B. (1976) Flow stress of MgO single crystals compressed along [100] at high hydrostatic pressures. Journal of the American Ceramic Society, 59, 40–42.CrossRefGoogle Scholar
Barrie, CD., Boyle, A.P. and Prior, DJ. (2007) An analysis of the microstructures developed in experimentally deformed polycrystalline pyrite and minor sulphide phases using electron backscatter diffraction. Journal of Structural Geology, 29, 1494–1511.CrossRefGoogle Scholar
Barrie, CD. (2008) An electron backscatter diffraction (ebsd) approach to understanding pyrite from its genesis to its near destruction. PhD thesis, Department of Earth and Ocean Sciences, University of Liverpool, UK.Google Scholar
Bestmann, M. and Prior, DJ. (2003) Intragranular dynamic recrystallization in naturally deformed calcite marble: Diffusion accomodated grain boundary sliding as a result of subgrain rotation recrystallization. Journal of Structural Geology, 25, 1597–1613.CrossRefGoogle Scholar
Bestmann, M., Piazolo, S., Spiers, CJ. and Prior, DJ. (2005) Mierostruetural evolution during initial stages of static recovery and recrystallization: New insights from in-situ heating experiments combined with electron backscatter diffraction analysis. Journal of Structural Geology, 27, 447–457.CrossRefGoogle Scholar
Bestmann, M., Prior, DJ. and Grasemann, B. (2006) Characterisation of deformation and flow mechanics around porphyroclasts in a calcite marble ultra-mylonite by means of EBSD analysis. Tectonophysics, 413, 185.CrossRefGoogle Scholar
Boyle, A.P., Prior, DJ., Banham, M.H. and Timms, N.E. (1998) Plastic deformation of metamorphic pyrite: New evidence from electron-backscatter diffraction and forescatter orientation-contrast imaging. Mineralium Deposita, 34, 71–81.CrossRefGoogle Scholar
Bretheau, T. and Dolin, C (1978) Heterogeneous deformation of Cu2O single crystals during high temperature compression creep. Journal of Materials Science, 13, 587–593.CrossRefGoogle Scholar
Carrez, P., Cordier, P., Devincre, B. and Kublin, L.P. (2005) Dislocation reactions and junctions in MgO. Materials Science and Engineering A, 400—401, 325–328.CrossRefGoogle Scholar
Couderc, J.J., Bras, J., Fagot, M. and Levade, C (1980) Etude par microscopie electronique en transmission d'echantillons de blende de diverses provenances. Bulletin de Mineralogie, 103, 547–557.CrossRefGoogle Scholar
Cox, S.F. (1987) Flow mechanisms in sulphide minerals. Ore Geology Reviews, 2, 133–171.CrossRefGoogle Scholar
Cox, S.F., Etheridge, M.A. and Hobbs, B.E. (1981) The experimental ductile deformation of polycrystalline and single-crystal pyrite. Economic Geology, 76, 2105–2117.CrossRefGoogle Scholar
Deer, W.A., Howie, R.A. and Zussman, J. (1992) An Introduction to the Rock Forming Minerals, Longman, London, pp. 583—89. 676–677.Google Scholar
Gehlen, K. (1971) X-ray analysis of preferred orientation of ore minerals — in particular with the pole-figure goniometer. Siemens Reviews, 38, 45–64.Google Scholar
Graf, J.L., Skinner, B.J., Bras, J., Fagot, M., Levade, C and Couderc, JJ. (1981) Transmission electron-microscopic observation of plastic-deformation in experimentally deformed pyrite. Economic Geology, 76, 738–742.CrossRefGoogle Scholar
Hennig-Michaeli, C (1985) Slip along <3̄11> and <3̄1̄1> on {112}; in experimentally deformed chalcopyrite. Fortschritte der Mineralogie, 63, 93.Google Scholar
Hirth, G. and Lothe, J. (1982) Theory of Dislocations. Wiley, New York.Google Scholar
Hobbs, B.E., Means, W.D. and Williams, P.F. (1976) An Outline of Structural Geology. Wiley, New York.Google Scholar
Jansen, E.M., Siemes, H. and Brokmeier, H.G. (1998) Crystallographic preferred orientation and micro-structure of experimentally deformed braubach galena ore with emphasis on the relation to diffusional processes. Mineralium Deposita, 34, 57–70.CrossRefGoogle Scholar
Kaneno, Y., Takahashi, A. and Takasugi, T. (2006) Microstructure and texture evolution during cold rolling and annealing of Ni3Fe alloy. Materials Science and Engineering, A, 431, 328–338.CrossRefGoogle Scholar
Levade, C, Couderc, JJ., Bras, J. and Fagot, M. (1979) Electron-microscopy study of dislocations in pyrite (FeS2). Philosophical Magazine, A, 40, 111–120.CrossRefGoogle Scholar
Levade, C, Couderc, JJ., Bras, J. and Fagot, M. (1982) Transmission electron-microscopy study of experimentally deformed pyrite. Philosophical Magazine A, 46, 307–325.CrossRefGoogle Scholar
Lloyd, G.E., Farmer, A.B. and Mainprice, D. (1997) Misorientation analysis and the formation and orientation of subgrain and grain boundaries. Tectonophysics, 279, 55–78.CrossRefGoogle Scholar
Mainprice, D. (1990) An efficent Fortran program to calculate seismic anisotropy from the lattice preferred orientations of minerals. Computers and Geosdences, 16, 385–393.CrossRefGoogle Scholar
McClay, K.R. and Ellis, P.G. (1983) Deformation and recrystallization of pyrite. Mineralogical Magazine, 47, 527–538.CrossRefGoogle Scholar
Miralles, L., Sans, M., Gali, S. and Santanach, P. (2001) 3-D rock salt fabrics in a shear zone (Suria Anticline, South-Pyrenees). Journal of Structural Geology, 23, 675–691.CrossRefGoogle Scholar
Passchier, C.W. and Trouw, R.A.J. (2005) Microtectonics, Springer-Verlag, Berlin, Heidelberg, pp. 40–51.Google Scholar
Poirier, J.P. (1985) Creep of Crystals: High-temperature Deformation Processes in Metals, Ceramics and Minerals. Cambridge University Press, Cambridge, UK.CrossRefGoogle Scholar
Prior, D.J., Trimby, P.W., Weber, U.D. and Dingley, DJ. (1996) Orientation contrast imaging of micro-structures in rocks using forescatter detectors in the scanning electron microscope. Mineralogical Magazine, 60, 859–869.CrossRefGoogle Scholar
Prior, D.J., Boyle, A.P., Brenker, F., Cheadle, M.C., Austin, D., Lopez, G., Peruzzo, L., Potts, G.J., Reddy, S., Spiess, R., Timms, N.E., Trimby, P., Wheeler, J. and Zetterstrom, L. (1999) The application of electron backscatter diffraction and orientation contrast imaging in the SEM to textural problems in rocks. American Mineralogist, 84, 1741–1759.CrossRefGoogle Scholar
Prior, D.J., Wheeler, J., Peruzzo, L., Spiess, R. and Storey, C. (2002) Some garnet micro structures: an illustration of the potential of orientation maps and misorientation analysis in micro structural studies. Journal of Structural Geology, 24, 999–1011.CrossRefGoogle Scholar
Reddy, S.M., Timms, N.E., Pantleon, W. and Trimby, P. (2007) Quantitative characterization of plastic deformation of zircon and geological implications. Contributions to Mineralogy and Petrology, 153, 625–645.CrossRefGoogle Scholar
Siemes, H., Zilles, D., Cox, S.F., Merz, P., Schafer, W., Will, G., Schaeben, H. and Kunze, K. (1993) Preferred orientation of experimentally deformed pyrite measured by means of neutron-diffraction. Mineralogical Magazine, 57, 29–43.CrossRefGoogle Scholar
Siemes, H., Klingenberg, B., Rybacki, E., Naumann, M., Schafer, W., Jansen, E. and Kunze, K (2008) Glide systems of hematite single crystals in deformation experiments. Ore Geology Reviews, 33, 255–279.CrossRefGoogle Scholar
Sprackling, M.T. (1976) The Plastic Deformation of Simple Ionic Crystals. Academic Press, New York.Google Scholar
Strotzki, W. (1994) Defect structure and deformation mechanisms in naturally deformed augite and enstatite. Tectonophysics, 229, 43–68.CrossRefGoogle Scholar
van Goethem, L., van Landuyt, J. and Amelinckx, S. (1978) Study of the glide elements in pyrite by means of electron microscopy and electron diffraction. American Mineralogist, 63, 548–550.Google Scholar
Vernooij, M.G.C., Brok, B.D. and Kunze, K. (2006) Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals. Tectonophysics, 427, 35–53.CrossRefGoogle Scholar
Wenk, H.-R. and Christie, J.M. (1991) Comments on the interpretation of deformation textures in rocks. Journal of Structural Geology, 13, 1091–1110.CrossRefGoogle Scholar
Wyckoff, R.W.G. (1965) Crystal Structures, Volume 1. Wiley, New York, 467 pp.Google Scholar
Zhang, Y. and Wilson, C.J.L. (1997) Lattice rotation in polycrystalline aggregates and single crystals with one slip system: a numerical and experimental approach. Journal of Structural Geology, 6, 875–885.CrossRefGoogle Scholar