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Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals

Published online by Cambridge University Press:  21 May 2019

C. L. Saiz Open the ORCID record for C. L. Saiz [Opens in a new window] ,
M. A. McGuire ,
S. R. J. Hennadige ,
J. van Tol  and
S. R. Singamaneni
C. L. Saiz
Affiliation:
Department of Physics, The University of Texas at El Paso, El Paso, Texas79968, USA
M. A. McGuire
Affiliation:
Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee37831, USA
S. R. J. Hennadige
Affiliation:
Department of Chemistry, The University of Texas at El Paso, El Paso, Texas79968, USA
J. van Tol
Affiliation:
National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida32310, USA
S. R. Singamaneni*
Affiliation:
Department of Physics, The University of Texas at El Paso, El Paso, Texas79968, USA
*
*(Email: srao@utep.edu)
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Abstract

Developing functional, cleavable two-dimensional materials for use in next generation devices has recently become a topic of considerable interest due to their unique properties. Of particular interest, transition metal halides CrI3 and CrCl3 have shown to be good contenders for tunable and cleavable magnetic materials due to their unique magnetic properties in the monolayer. Here, electron spin resonance spectroscopy is used to pinpoint the atomic origins and underlying mechanisms of magnetic interactions as a function of temperature (5-500 K) and microwave frequency (9.43, 120 GHz) on CrI3 and CrCl3 bulk single crystals. ESR signals from CrI3 due to Cr3+ were observed to decay at 460 K, while ESR signals from CrCl3 remain up to 500 K. In the case of CrCl3, the temperature dependences of signal behavior, line width and g-value show characteristic signatures of ferromagnetic fluctuations at around 40 K, near to the antiferromagnetic phase transition at 17 K.

Keywords

2D materialsCrelectron spin resonance
Type
Articles
Information
MRS Advances , Volume 4 , Issue 40: Quantum and Nanomaterials , 2019 , pp. 2169 - 2175
Copyright
Copyright © Materials Research Society 2019 

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