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Silver nanoparticles produced by laser ablation for a study on the effect of SERS with low laser power on N719 dye and Rhodamine-B

Published online by Cambridge University Press:  11 March 2019

Nelson Fabian Villegas Borrero ,
José Maria Clemente da Silva Filho Open the ORCID record for José Maria Clemente da Silva Filho [Opens in a new window] ,
Viktor A. Ermakov  and
Francisco Chagas Marques
Nelson Fabian Villegas Borrero*
Affiliation:
State University of Campinas, IFGW, Campinas, SP, 13083-859, Brazil.
José Maria Clemente da Silva Filho
Affiliation:
State University of Campinas, IFGW, Campinas, SP, 13083-859, Brazil.
Viktor A. Ermakov
Affiliation:
State University of Campinas, IFGW, Campinas, SP, 13083-859, Brazil.
Francisco Chagas Marques
Affiliation:
State University of Campinas, IFGW, Campinas, SP, 13083-859, Brazil.
*
*(Email: nelsonfabianvillegas@gmail.com)
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Abstract

The effect of surface-enhanced Raman spectroscopy (SERS) was investigated in N719 dye thin films deposited on silicon wafer with a thin film of silver nanoparticles (Ag-NPs) fabricated by laser ablation in an aqueous solution, using a NdYAG laser (λ = 1064nm). Optical absorption spectroscopy of the Ag-NPs colloidal solution shows an absorption peak at λ = 400nm, associated with a localized surface plasmon resonance in the Ag-NPs. Scanning electron microscopy (SEM) reveals that these NPs have an approximately spherical shape, with their diameter being tunable by laser power intensity. Raman spectroscopy measurements were performed using low laser power to avoid damage to the N719 dye films. Thus, a small Raman signal is obtained. The Raman intensity was greatly increased when the N719 film was deposited on a substrate with a thin film of Ag-NPs due to the SERS effect. The process was also used in Rhodamine-B to clearly demonstrate the SERS effect obtained by the use of these NPs produced by laser ablation.

Keywords

laser ablationsurface enhanced Raman spectroscopy (SERS)AgRaman spectroscopy
Type
Articles
Information
MRS Advances , Volume 4 , Issue 11-12: Electronic, Photonic and Magnetic Materials , 2019 , pp. 723 - 731
Copyright
Copyright © Materials Research Society 2019 

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