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Improved Corrosion Resistance and Increased Hardness of Copper Substrates from Cu-Ni/Ni-P Composite Coatings

Published online by Cambridge University Press:  27 April 2020

Wenwen Dou ,
Wen Li ,
Yuchen Cai ,
Mengyao Dong ,
Xiaojing Wang ,
Jincheng Fan ,
Juying Zhou ,
Hua Hou ,
Shidong Zhu  and
Shougang Chen
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Wenwen Dou
Affiliation:
Department of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
Wen Li
Affiliation:
Department of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
Yuchen Cai
Affiliation:
Department of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
Mengyao Dong*
Affiliation:
Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37934, USA
Xiaojing Wang
Affiliation:
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37934, USA
Jincheng Fan
Affiliation:
College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha 410114, China
Juying Zhou
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China School of Materials Science and Engineering, North University of China, Taiyuan 030051, China
Hua Hou
Affiliation:
School of Materials Science and Engineering, North University of China, Taiyuan 030051, China
Shidong Zhu
Affiliation:
School of Materials Science and Engineering, Xi`an Shiyou University, Xi`an 710065, China
Shougang Chen*
Affiliation:
Department of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
Zhanhu Guo*
Affiliation:
Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37934, USA
*
*Corresponding author: sgchen@ouc.edu.cn (S. Chen); dongbinbin@zzu.edu.cn (B. Dong); and zguo10@utk.edu or nanomaterials2000@gmail.com (Z. Guo)
*Corresponding author: sgchen@ouc.edu.cn (S. Chen); dongbinbin@zzu.edu.cn (B. Dong); and zguo10@utk.edu or nanomaterials2000@gmail.com (Z. Guo)
*Corresponding author: sgchen@ouc.edu.cn (S. Chen); dongbinbin@zzu.edu.cn (B. Dong); and zguo10@utk.edu or nanomaterials2000@gmail.com (Z. Guo)
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Abstract

To improve the corrosion resistance and to increase the hardness of copper substrate in marine environment, the Cu-Ni/Ni-P composite coatings were prepared on the copper substrate using the galvanostatic electrolytic deposition method. The deposition current densities were explored to find the optimized deposition conditions for forming the composite coatings. Corrosion resistance properties were analyzed using the polarization curves and electrochemical impedance spectroscopy (EIS). Considering the corrosion resistance and hardness, the −20 mA/cm2 was selected to deposit Cu-Ni coatings on copper substrate and the −30 mA/cm2 was selected to deposit Ni-P coating on the Cu-Ni layer. The Cu-Ni/Ni-P composite coatings not only exhibited superior corrosion resistance compared to single Cu-Ni coating in 3.5 wt.% NaCl solution, but also showed much better mechanical properties than single Cu-Ni coating.

Keywords

coatingcompositecorrosionelectrodepositionhardness
Type
Articles
Information
MRS Advances , Volume 5 , Issue 40-41: Nanoscale and Quantum Materials , 2020 , pp. 2129 - 2137
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Copyright
Copyright © Materials Research Society 2020

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