Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-28T14:43:15.080Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Layered Nano-Composite by the Reaction of Ca(OH)2 with Carboxylic Acid as the Molecular Recognition Host

Published online by Cambridge University Press:  09 January 2018

Yusuke Edamatsu ,
Junichi Kobayashi  and
Hideyuki Tagaya
Yusuke Edamatsu*
Affiliation:
Graduate School of Science and Engineering, Yamagata University, Yonezawa, Yamagata, Japan
Junichi Kobayashi
Affiliation:
Graduate School of Science and Engineering, Yamagata University, Yonezawa, Yamagata, Japan
Hideyuki Tagaya
Affiliation:
Graduate School of Science and Engineering, Yamagata University, Yonezawa, Yamagata, Japan
*
*(Email: ter50833@st.yamagata-u.ac.jp)
Get access

Abstract

Calcium hydroxide was reacted with aliphatic calboxylic acids having the different number of carbons, and the precipitated products were characterized by TG, SEM, TEM and XRD. Layered structure was confirmed by TEM images and XRD patterns. From the results of XRD patterns, the interlayer spacing d increased with an increase of the number of carbons of carboxylic acids from 30 Å to 60 Å, and it was proportional to the carbon number of the materials. Calculated angles of the long chain fatty acids in the crystal structures of the reaction products was about sixty degrees. The adsorption ability of the nanocomposite prepared with stearic acid was carried out by using the mixture of three organic compounds at room temperature. For the adsorption experiment, only one kind of organic matters was selectively adsorbed.

Keywords

absorptionself-assemblylayered
Type
Articles
Information
MRS Advances , Volume 3 , Issue 26: Biomaterials and Soft Materials , 2018 , pp. 1485 - 1490
Check for updates
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Tagaya, H., “Preparation and Application of Organic-Inorganic Nanohybrids” Bottom-up Nanofabrication Supramolecules, Self-assemblies, and Organized Films Volume 6, ed. Ariga, Katsuhiko and Nalwa, Hari Singh (American Scientific Publishers, 2009) pp. 283–300.Google Scholar
Gu, Qingyang, Liu, Xia, Hu, Yingxi, Zhang, Lifang and Li, Yanyun, Journal of Photochemistry and Photobiology A: Chemistry 335, 268–275 (2017).CrossRefGoogle Scholar
O’Hare, D., “Inorganic Intercalation Compounds,” Inorganic Materials 2nd Edition, ed. Bruce, D. W. and O’Hare, D. (John Wiley & Sons Ltd, 1996), pp.172–179.Google Scholar
Ogata, Sumikazu, Kadokawa, Jun-ichi and Tagaya, Hideyuki, Journal of Nanoscience and Nanotechnology 6, 1826–1829 (2006).CrossRefGoogle Scholar
Shishito, Kazuya, Fukuda, Hajime and Tagaya, Hideyuki, Trans. Mat. Res. Soc. Japan, 39 (2), 207–210 (2014).CrossRefGoogle Scholar
Tagaya, H., Ogata, S., Morioka, H., Kadokawa, J., Karasu, M. and Chiba, K., J. Mater. Chem. 6, 1235 (1996).CrossRefGoogle Scholar
Tagaya, H., Morioka, H., Ogata, S., Karasu, M., Kadokawa, J. and Chiba, K., Apllied Surface Science 121-122 (1997).Google Scholar
Ogata, S., Tagaya, H., Karasu, M. and Kadokawa, J., J. Mater. Chem. 10, 321 (1999).CrossRefGoogle Scholar
Fukuda, H. and Tagaya, H., presented at 6th International Conference on Green and Sustainable chemistry, P36, Nottingham, United Kingdom, 2013 (unpublished).Google Scholar
Ahmad, Rozita, Hussein, Mohd Zobir, Wan Abdul Kadir, Wan Rasidah, Halimah Sarijo, Siti, and Hin, Taufiq-Yap Yun, J. Agric. Food Chem., 63 (51), 10893–10902 (2015).CrossRefGoogle Scholar
Liu, Jiexiang, Zhang, Xiaoguang and Zhang, Yongqing, ACS Appl. Mater. Interfaces, 7 (21), 11180–11188 (2015).CrossRefGoogle Scholar