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Tailoring the structural and magnetic property of nanocrystalline MnxZn1-xFe2O4 synthesized by citrate route method

Published online by Cambridge University Press:  04 September 2017

D. K. Tiwari ,
S. E. Almanza-Morales ,
L. M. Morales-Villagómez ,
M.O. Alonso-Pérez ,
Prakhar Sengar ,
J. Estudillo-Ayala  and
D. Homero Galván
D. K. Tiwari*
Affiliation:
Cátedratico Conacyt-El Colegio de Michoacán, La Piedad, C. P.59370, Michoacán, México. Laboratorio de Análisis y Diagnóstico del Patrimonio, El Colegio de Michoacán, La Piedad, C. P.59370, Michoacán, México
S. E. Almanza-Morales
Affiliation:
Ingeniería en Biotecnología, Universidad Politécnica de Pénjamo, Pénjamo, Guanajuato, México.
L. M. Morales-Villagómez
Affiliation:
División de Ingenierías, Universidad de Guanajuato, Salamanca, Guanajuato, México.
M.O. Alonso-Pérez
Affiliation:
Laboratorio de Análisis y Diagnóstico del Patrimonio, El Colegio de Michoacán, La Piedad, C. P.59370, Michoacán, México
Prakhar Sengar
Affiliation:
Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Ensenada, Baja California, México.
J. Estudillo-Ayala
Affiliation:
División de Ingenierías, Universidad de Guanajuato, Salamanca, Guanajuato, México.
D. Homero Galván
Affiliation:
Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Ensenada, Baja California, México.
*
*Author for correspondence: Dhirendra K. Tiwari, E-mail: dkt.phy@gmail.com, dkumarti@conacyt.mx
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Abstract

Nanocrystalline MnxZn1-xFe2O4 with the varying concentration of Mn (x= 0.25, 0.50) have been synthesized by citrate route method. The effect of annealing temperature on structural and magnetic properties of as-synthesized materials was studied. The X-ray diffraction (XRD) analysis revealed the improved crystallinity and purity of the samples at high temperature annealing. Also, the increase in the annealing temperature yielded nanocrystals with bigger crystallite size. The samples annealed at higher temperature were analyzed by TEM which showed the formation of irregular polycrystalline particles with average size in the range of 150-180 nm. The magnetic measurements were taken using vibrating sample magnetometer and displayed the superparamagnetic behavior of the prepared materials. Also, the increase in magnetization was observed with Mn substitution.

Keywords

NanostructureChemical synthesisMagnetic properties
Type
Articles
Information
MRS Advances , Volume 2 , Issue 49: International Materials Research Congress XXV , 2017 , pp. 2763 - 2768
Copyright
Copyright © Materials Research Society 2017 

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